Photochromic Spirooxazines Functionalized with Oligomers: Investigation of Core-Oligomer Interactions and Photomerocyanine Isomer Interconversion Using NMR Spectroscopy and DFT

Journal of Organic Chemistry

Volumn 75, Issue 9, 2010, Pages 2851-2860

  Yee, Lachlan H ^a   Hanley, Tracey ^b   Evans, Richard A ^a,c   Davis, Thomas P ^a   Ball, Graham E ^a  

^a UNIVERSITY OF NEW SOUTH WALES   (Australia)

^b AUSTRALIAN NUCLEAR SCIENCE AND TECHNOLOGY ORGANISATION   (Australia)

^c CSIRO   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

2D NMR SPECTRA; BEFORE AND AFTER; CROSS PEAKS; DFT CALCULATION; EXPERIMENTAL CONDITIONS; FUNCTIONALIZED; IN-SITU; INTERCONVERSIONS; MEROCYANINE ISOMERS; NMR SPECTROSCOPY; POLYDIMETHYLSILOXANE PDMS; PROTONATED MEROCYANINE; ROOM TEMPERATURE; S-TRANS; SIDE CHAINS; SPIROOXAZINES; TIME-SCALES; UV IRRADIATION;

DYES; ELECTRON TRANSITIONS; ETHYLENE; ETHYLENE GLYCOL; ISOMERIZATION; MICROCHANNELS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLIGOMERS; PHOTOCHROMISM; PHOTOLYSIS; POLYETHYLENE GLYCOLS; POLYETHYLENE OXIDES; SILICONES; SULFUR COMPOUNDS; TEMPERATURE CONTROL;

ISOMERS;

ACID; DIMETICONE; MACROGOL; MEROCYANINE; OLIGOMER; OXAZINE DERIVATIVE; PHOTOCHROMIC SPIROOXAZINE DERIVATIVE; PHOTOMEROCYANINE; PROTON; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL INTERACTION; CIS TRANS ISOMERISM; CONTROLLED STUDY; DENSITY FUNCTIONAL THEORY; ISOMER; ISOMERIZATION; MOLECULE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; NUCLEAR OVERHAUSER EFFECT; PHOTOLYSIS; PROTON TRANSPORT; QUANTUM CHEMISTRY; ROOM TEMPERATURE; ROTATIONAL NUCLEAR OVERHAUSER EFFECT; TEMPERATURE; ULTRAVIOLET IRRADIATION;

BENZOPYRANS; DIMETHYLPOLYSILOXANES; FOURIER ANALYSIS; INDOLES; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR STRUCTURE; OXAZINES; PHOTOCHEMICAL PROCESSES; POLYETHYLENE GLYCOLS; SPIRO COMPOUNDS; STEREOISOMERISM;

EID: 77951817325     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo100081g     Document Type: Article

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