메뉴 건너뛰기




Volumn 28, Issue 2, 2010, Pages 184-201

Studies on the use of N,N,N',N'-Tetra(2-ethylhexyl) diglycolamide (TEHDGA) for actinide partitioning. I: Investigation on third-phase formation and extraction behavior

Author keywords

Aactinide partitioning; DHOA; Diglycolamides; TEHDGA; Third Phase Formation

Indexed keywords

ACID CONCENTRATIONS; ACTINIDE-PARTITIONING; BRANCHED ISOMERS; DIGLYCOLAMIDE; DODECANE; EXTRACTANTS; HIGH LEVEL WASTE; LANTHANIDES; MODIFIER CONCENTRATION; N-DECANOL; N-DODECANE; PHASE FORMATIONS; PHASE MODIFIERS; SOLVENT SYSTEM; TETRAOCTYL DIGLYCOLAMIDE; THIRD PHASE;

EID: 77951630053     PISSN: 07366299     EISSN: 15322262     Source Type: Journal    
DOI: 10.1080/07366290903565885     Document Type: Article
Times cited : (85)

References (34)
  • 2
    • 0038391229 scopus 로고    scopus 로고
    • Separation of long-lived radio-nuclides from high active nuclear waste
    • Madic, C.; Lecomte, M.; Baron, P.; Boullis, B. Separation of long-lived radionuclides from high active nuclear waste. C. R. Physique 2002, 3,797-811.
    • (2002) C.R. Physique , vol.3 , pp. 797-811
    • Madic, C.1    Lecomte, M.2    Baron, P.3    Boullis, B.4
  • 3
    • 3543019674 scopus 로고    scopus 로고
    • Recent advances on the chemistry of solvent extraction applied to the reprocessing of spent nuclear fuels and radioactive wastes
    • Paiva A. P.; Malik P. Recent advances on the chemistry of solvent extraction applied to the reprocessing of spent nuclear fuels and radioactive wastes. J. Radioanal. Nucl. Chem. 2004, 261(2), 485-496.
    • (2004) J. Radioanal. Nucl. Chem , vol.261 , Issue.2 , pp. 485-496
    • Paiva, A.P.1    Malik, P.2
  • 4
    • 1342311256 scopus 로고    scopus 로고
    • Amides and diamides as promising extractants in the back end of the nuclear fuel cycle: An overview
    • Manchanda, V. K.; Pathak, P. N. Amides and diamides as promising extractants in the back end of the nuclear fuel cycle: an overview. Sep. Purif. Technol. 2004, 35,85-103.
    • (2004) Sep. Purif. Technol , vol.35 , pp. 85-103
    • Manchanda, V.K.1    Pathak, P.N.2
  • 6
    • 0030553415 scopus 로고    scopus 로고
    • Solvent Extraction of Eu, Th, U, Np and Am With N, N'-dimethyl- N, N'-dihexyl-3-oxapentanediamide and Its Analogous Compounds
    • Sasaki, Y.; Choppin, G. R. Solvent extraction of Eu, Th, U, Np and Am with N, N'-dimethyl- N, N'-dihexyl-3-oxapentanediamide and its analogous compounds. Anal. Sci. 1996, 12, 225-230.
    • (1996) Anal. Sci , vol.12 , pp. 225-230
    • Sasaki, Y.1    Choppin, G.R.2
  • 7
    • 0029868765 scopus 로고    scopus 로고
    • Extraction behaviors of Eu, Th, U and Am With Diamides + Thenoyltrifluoroacetone
    • Sasaki, Y.; Choppin, G. R. Extraction behaviors of Eu, Th, U and Am with diamides + thenoyltrifluoroacetone. J. Radioanal. Nucl. Chem. 1996, 207, 383-394.
    • (1996) J. Radioanal. Nucl. Chem , vol.207 , pp. 383-394
    • Sasaki, Y.1    Choppin, G.R.2
  • 8
    • 0000819757 scopus 로고    scopus 로고
    • Solvent extraction of trivalent lanthanide ions with N, N'-dimethyl - N, N'- diphenyl - 3-oxapentanediamide. Radiochim, Acta
    • Narita, H.; Yaita, T.; Tamura, K.; Tachimori, S. Solvent extraction of trivalent lanthanide ions with N, N' - dimethyl - N, N'- diphenyl - 3-oxapentanediamide. Radiochim. Acta 1998, 81, 223.
    • (1998) , vol.81 , pp. 223
    • Narita, H.1    Yaita, T.2    Tamura, K.3    Tachimori, S.4
  • 9
    • 0033053925 scopus 로고    scopus 로고
    • Study on the extraction of trivalent lanthanide ions with N, N'- dimethyl - N, N'- diphenyl malonamide and diglycola-mide
    • Narita, H.; Tachimori, S. Study on the extraction of trivalent lanthanide ions with N, N'- dimethyl - N, N'- diphenyl malonamide and diglycola-mide. J. Radioanal. Nucl. Chem. 1999, 239(2), 381-384.
    • (1999) J. Radioanal. Nucl. Chem , vol.239 , Issue.2 , pp. 381-384
    • Narita, H.1    Tachimori, S.2
  • 10
    • 0035087621 scopus 로고    scopus 로고
    • The novel extractants, diglycolamides, for the extraction of lanthanides and actinides in HNO 3-n-dodecane system
    • Sasaki, Y.; Sugo, Y; Suzuki, S.; Tachimori, S. The novel extractants, diglycolamides, for the extraction of lanthanides and actinides in HNO3-n-dodecane system. Solvent Extr. Ion Exch. 2001, 19 (1), 91-103.
    • (2001) Solvent Extr. Ion Exch , vol.19 , Issue.1 , pp. 91-103
    • Sasaki, Y.1    Sugo, Y.2    Suzuki, S.3    Tachimori, S.4
  • 11
    • 0036875997 scopus 로고    scopus 로고
    • Modification of Todga-n-dode-cane Solvent With a Monoamide For High Loading of Lanthanides(iii) And actinides(III)
    • Tachimori, S.; Sasaki, Y.; Suzuki, S. Modification of TODGA-n-dode-cane solvent with a monoamide for high loading of lanthanides(III) and actinides(III). Solvent Extr. Ion Exch. 2002, 20(6), 687-699.
    • (2002) Solvent Extr. Ion Exch , vol.20 , Issue.6 , pp. 687-699
    • Tachimori, S.1    Sasaki, Y.2    Suzuki, S.3
  • 12
    • 3943073682 scopus 로고    scopus 로고
    • Aggregation Properties of N, N, N', N'-tetraoctyl-3-oxapentanediamide (todga) In N-dodecane
    • Nave, S.; Modolo, G.; Madic, C.; Testard, F. Aggregation properties of N, N, N', N'-tetraoctyl-3-oxapentanediamide (TODGA) in n-dodecane. Solvent Extr. Ion Exch. 2004, 22(4), 527- 551.
    • (2004) Solvent Extr. Ion Exch , vol.22 , Issue.4 , pp. 527-551
    • Nave, S.1    Modolo, G.2    Madic, C.3    Testard, F.4
  • 13
    • 35248881948 scopus 로고    scopus 로고
    • Development of a TODGA based process for Partitioning of actinides from a PUREX raffinate Part I: Batch Extraction Optimization Studies and Stability Tests
    • Modolo, G.; Asp, H.; Schreinemachers, C.; Vijgen, H. Development of a TODGA based process for Partitioning of actinides from a PUREX raffinate Part I: Batch Extraction Optimization Studies and Stability Tests. Solvent Extr. Ion Exch. 2007, 25, 703-721.
    • (2007) Solvent Extr. Ion Exch , vol.25 , pp. 703-721
    • Modolo, G.1    Asp, H.2    Schreinemachers, C.3    Vijgen, H.4
  • 14
    • 0036204294 scopus 로고    scopus 로고
    • Studies on hydrolysis and radiolysis of N, N, N', N'-tetraoctyl-3-oxapentane-1, 5-diamide
    • Sugo, Y.; Sasaki, Y; Tachimori, S. Studies on hydrolysis and radiolysis of N, N, N', N'-tetraoctyl-3-oxapentane-1, 5-diamide. Radiochim. Acta 2002, 90, 161-165.
    • (2002) Radiochim. Acta , vol.90 , pp. 161-165
    • Sugo, Y.1    Sasaki, Y.2    Tachimori, S.3
  • 15
    • 9444279075 scopus 로고    scopus 로고
    • Cumulative study on solvent extraction of elements by N, N, N', N'-tetraoctyl-3-oxapentanediamide (TODGA) from nitric acid into n-dodecane
    • Zhu, Z. -X.; Sasaki, Y.; Suzuki, H.; Suzuki, S.; Kimura, T. Cumulative study on solvent extraction of elements by N, N, N', N'-tetraoctyl-3-oxapentanediamide (TODGA) from nitric acid into n-dodecane. Anal. Chim. Acta 2004, 527, 163-168.
    • (2004) Anal. Chim Acta , vol.527 , pp. 163-168
    • Zhu Z., -X.1    Sasaki, Y.2    Suzuki, H.3    Suzuki, S.4    Kimura, T.5
  • 16
    • 0242626636 scopus 로고    scopus 로고
    • Solvent extraction of alkaline earth metal ions by diglycolic amides from nitric acid solutions
    • Tachimori, S.; Suzuki, S.; Sasaki, Y.; Apichaibukol, A. Solvent extraction of alkaline earth metal ions by diglycolic amides from nitric acid solutions. Solvent Extr. Ion Exch. 2003, 21, 707.
    • (2003) Solvent Extr. Ion Exch , vol.21 , pp. 707
    • Tachimori, S.1    Suzuki, S.2    Sasaki, Y.3    Apichaibukol, A.4
  • 17
    • 3543015557 scopus 로고    scopus 로고
    • Separation of actinides from low level liquid wastes (LLLW) by extraction chromatography using novel DMDOHEMA and TODGA impregnated resins
    • Hecke, K. V.; Modolo, G. Separation of actinides from low level liquid wastes (LLLW) by extraction chromatography using novel DMDOHEMA and TODGA impregnated resins. J. Radioanal. Nucl. Chem. 2004, 261(2), 269-275.
    • (2004) J. Radioanal. Nucl. Chem , vol.261 , Issue.2 , pp. 269-275
    • Hecke, K.V.1    Modolo, G.2
  • 18
    • 2942569121 scopus 로고    scopus 로고
    • H.; Wei, Y.-Z.; Kumagai, M.; Asakura, T.; Morita, Y. Group separation of trivalent minor actinides and lanthanides by TODGA extraction chromatography for radioactive waste management. J. Alloys Comp
    • Hoshi, H.; Wei, Y.-Z.; Kumagai, M.; Asakura, T.; Morita, Y. Group separation of trivalent minor actinides and lanthanides by TODGA extraction chromatography for radioactive waste management. J. Alloys Comp. 2004, 374, 451-455.
    • (2004) , vol.374 , pp. 451-455
    • Hoshi, H.1    Wei, Y.-Z.2    Kumagai, M.3    Asakura, T.4    Morita, Y.5
  • 19
    • 27144449610 scopus 로고    scopus 로고
    • Wang, J,; Rao, L. Extraction of Actinides(III, IV, V, VI) ions and TcO4- by N, N, N', N'-tetraisobutyl-3-oxa-glutaramide
    • Tian, G.; Zhang, P.; Wang, J,; Rao, L. Extraction of Actinides(III, IV, V, VI) ions and TcO4- by N, N, N', N'-tetraisobutyl-3-oxa-glutaramide. Solvent Extr. Ion Exch. 2005, 23, 631-643.
    • (2005) Solvent Extr. Ion Exch , vol.23 , pp. 631-643
    • Tian, G.1    Zhang, P.2    Wang, J.3    Rao, L.4
  • 20
    • 20444475418 scopus 로고    scopus 로고
    • Method for the determination of extraction capacity and its application to N, N, N', N'-tetraalkyl derivatives of diglycolamide-monoamide/n-dodecane media
    • Sasaki, Y.; Sugo, Y.; Suzuki, S.; Kimura, T. A method for the determination of extraction capacity and its application to N, N, N', N'-tetraalkyl derivatives of diglycolamide-monoamide/n-dodecane media. Anal. Chim. Acta 2005, 543, 31-37.
    • (2005) Anal. Chim. Acta , vol.543 , pp. 31-37
    • Sasaki, Y.1    Sugo, Y.2    Suzuki, S.3    Kimura, T.A.4
  • 21
    • 33747781133 scopus 로고    scopus 로고
    • Transport of Am(III) through a supported liquid membrane containing N, N, N', N'-tetraoctyl-3-oxapentane diamide (TODGA) in n-dodecane as the carrier
    • Ansari, S.; Mohapatra, P. K.; Prabhu, D. R.; Manchanda, V. K. Transport of Am(III) through a supported liquid membrane containing N, N, N', N'-tetraoctyl-3-oxapentane diamide (TODGA) in n-dodecane as the carrier. J. Membr. Sci. 2006, 282, 133-141.
    • (2006) J. Membr. Sci , vol.282 , pp. 133-141
    • Ansari, S.1    Mohapatra, P.K.2    Prabhu, D.R.3    Manchanda, V.K.4
  • 22
    • 30644479085 scopus 로고    scopus 로고
    • Extraction chromatographic studies of metal ions using N, N, N', N'-tetraoctyl diglycolamide as the stationary phase
    • Ansari, S.; Pathak, P. N.; Husain, M.; Prasad, A. K.; Parmar, V. S.; Manchanda, V. K. Extraction chromatographic studies of metal ions using N, N, N', N'-tetraoctyl diglycolamide as the stationary phase. Talanta 2006, 68, 1273-1280.
    • (2006) Talanta , vol.68 , pp. 1273-1280
    • Ansari, S.1    Pathak, P.N.2    Husain, M.3    Prasad, A.K.4    Parmar, V.S.5    Manchanda, V.K.6
  • 23
    • 33745432843 scopus 로고    scopus 로고
    • Extraction of actinides using N, N, N', N'-tetraoctyl diglycolamide (TODGA): A thermodynamic study
    • Ansari, S.; Pathak, P. N.; Husain, M.; Prasad, A. K.; Parmar, V. S.; Manchanda, V. K. Extraction of actinides using N, N, N', N'-tetraoctyl diglycolamide (TODGA): a thermodynamic study. Radiochim. Acta 2006, 94, 307-312.
    • (2006) Radiochim. Acta , vol.94 , pp. 307-312
    • Ansari, S.1    Pathak, P.N.2    Husain, M.3    Prasad, A.K.4    Parmar, V.S.5    Manchanda, V.K.6
  • 24
    • 33847688865 scopus 로고    scopus 로고
    • An additional insight into the correlation between the distribution ratios and the aqueous acidity of the TODGA System
    • Sasaki, Y.; Rapold, P.; Arisaka, M.; Hirata, M.; Kimura, T.; Hill, C.; Cote, G. An additional insight into the correlation between the distribution ratios and the aqueous acidity of the TODGA System. Solvent Extr. Ion Exch. 2007, 25, 187-204.
    • (2007) Solvent Extr. Ion Exch , vol.25 , pp. 187-204
    • Sasaki, Y.1    Rapold, P.2    Arisaka, M.3    Hirata, M.4    Kimura, T.5    Hill, C.6    Cote, G.7
  • 25
    • 33847625838 scopus 로고    scopus 로고
    • Synthesis of some N, N, N', N'-Tetraalkyl-3-Oxa-Pentane-1,5-Diamide and their applications in solvent extraction
    • Mowafy, E. A.; Aly, H. F. Synthesis of some N, N, N', N'-Tetraalkyl-3-Oxa-Pentane-1,5-Diamide and their applications in solvent extraction. Solvent Extr. Ion Exch. 2007, 25, 205-224.
    • (2007) Solvent Extr. Ion Exch , vol.25 , pp. 205-224
    • Mowafy, E.A.1    Aly, H.F.2
  • 26
    • 34249329540 scopus 로고    scopus 로고
    • Evaluation of N, N, N', N'-tetraoctyl-3-oxapentane Diamide (todga) As a Mobile Carrier In Remediation of Nuclear Waste Using Supported Liquid Membrane
    • Ansari, S.; Mohapatra, P. K.; Prabhu, D. R.; Manchanda, V. K. Evaluation of N, N, N', N'-tetraoctyl-3-oxapentane diamide (TODGA) as a mobile carrier in remediation of nuclear waste using supported liquid membrane. J. Membr. Sci. 2007, 298, 169-174.
    • (2007) J. Membr. Sci , vol.298 , pp. 169-174
    • Ansari, S.1    Mohapatra, P.K.2    Prabhu, D.R.3    Manchanda, V.K.4
  • 27
    • 37849042566 scopus 로고    scopus 로고
    • Developmentofa TODGA based continuous counter-currentextractionpro-cessforthePartitioningofactinidesfromasimulatedPUREXraffinate, PartII: Centrifugal Contactor Runs
    • Modolo, G.; Asp, H.; Vijgen, H.; Malmbeck, R.; Magnusson, D.; Sorel, C. Developmentofa TODGA based continuous counter-currentextractionpro-cessforthePartitioningofactinidesfromasimulatedPUREXraffinate, PartII: Centrifugal Contactor Runs. Solvent Extr. Ion Exch. 2008, 26, 62-76.
    • (2008) Solvent Extr. Ion Exch , vol.26 , pp. 62-76
    • Modolo, G.1    Asp, H.2    Vijgen, H.3    Malmbeck, R.4    Magnusson, D.5    Sorel, C.6    Developmentofa, T.O.D.G.A.7
  • 28
    • 50449101924 scopus 로고    scopus 로고
    • Separation of Am(III) and trivalent lanthanides from simulated high-level waste using a hollow fiber-supported liquid membrane
    • Ansari, S. A.; Mohapatra, P. K.; Raut, D. R.; Adya, V. C.; Thulasidas, S. K.; Manchanda, V. K. Separation of Am(III) and trivalent lanthanides from simulated high-level waste using a hollow fiber-supported liquid membrane. Sep. Purif. Technol. 2008, 63, 239-242.
    • (2008) Sep. Purif. Technol , vol.63 , pp. 239-242
    • Ansari, S.A.1    Mohapatra, P.K.2    Raut, D.R.3    Adya, V.C.4    Thulasidas, S.K.5    Manchanda, V.K.6
  • 29
    • 62149131458 scopus 로고    scopus 로고
    • Counter-current Extraction of Uranium and Lanthanides From Simulated High-level Waste Using N, N, N', N'-tetraoctyl Diglycola-mide
    • Ansari S. A. Et Al
    • Ansari, S. A. et al. Counter-current extraction of uranium and lanthanides from simulated high-level waste using N, N, N', N'-tetraoctyl diglycola-mide. Sep. Purif. Technol. 2009, 66,118- 124.
    • (2009) Sep. Purif. Technol , vol.66 , pp. 118-124
  • 30
    • 18144395128 scopus 로고    scopus 로고
    • Novel extraction of Chromatographic Resins Based on Tetraalkyldiglycolamides: Characterization and Potential Applications
    • Horwitz, E. P.; McAlister, D. R.; Bond, A. H.; Barrans, R. E. Novel extraction of chromatographic resins based on tetraalkyldiglycolamides: Characterization and Potential Applications. Solvent Extr. Ion Exch. 2005, 23, 319-344.
    • (2005) Solvent Extr. Ion Exch , vol.23 , pp. 319-344
    • Horwitz, E.P.1    McAlister, D.R.2    Bond, A.H.3    Barrans, R.E.4
  • 31
    • 34248213141 scopus 로고    scopus 로고
    • Process development for bulk separation of trivalent actinides and lanthanides from radioactive high-level liquid waste
    • Manohar, S.; Sharma, J. N.; Shah, B. V.; Wattal, P. K. Process development for bulk separation of trivalent actinides and lanthanides from radioactive high-level liquid waste. Nucl. Sci. Eng. 2007, 156,96-102.
    • (2007) Nucl. Sci. Eng , vol.156 , pp. 96-102
    • Manohar, S.1    Sharma, J.N.2    Shah, B.V.3    Wattal, P.K.4
  • 32
    • 53249140318 scopus 로고    scopus 로고
    • Facilitated Transport of Am(iii) Through a Flat-sheet Supported Liquid Membrane (fsslm) Containing Tetra (2-ethyl Hexyl) Diglycolamide (tehdga) As Carrier
    • Panja, S.; Ruhela, R.; Misra, S. K; Sharma, J. N; Tripathi, S. C.; Dakshinamoorthy. A. Facilitated transport of Am(III) through a flat-sheet supported liquid membrane (FSSLM) containing tetra (2-ethyl hexyl) diglycolamide (TEHDGA) as carrier. J. Membr. Sci. 2008, 325, 158-165.
    • (2008) J. Membr. Sci , vol.325 , pp. 158-165
    • Panja, S.1    Ruhela, R.2    Misra, S.K.3    Sharma, J.N.4    Tripathi, S.C.5    Dakshinamoorthy, A.6
  • 33
    • 53249119893 scopus 로고    scopus 로고
    • Separation studies of uranium and thorium using tetra (2-ethyl hexyl) diglycolamide (TEHDGA) as extractant
    • Sharma, J. N.; Ruhela, R.; Harindaran, K. N.; Mishra, S. L.; Tangri, S. K.; Suri, A. K. Separation studies of uranium and thorium using tetra (2-ethyl hexyl) diglycolamide (TEHDGA) as extractant. J. Radioanal. Nucl. Chem. 2008, 278(1), 173-177.
    • (2008) J. Radioanal. Nucl. Chem , vol.278 , Issue.1 , pp. 173-177
    • Sharma, J.N.1    Ruhela, R.2    Harindaran, K.N.3    Mishra, S.L.4    Tangri, S.K.5    Suri, A.K.6
  • 34
    • 0001985577 scopus 로고
    • The chemistry of the formation and elimination of a third phase in organophosphorus and amine extraction systems
    • McKay, H. A. C.; Healy, T. V.; Jenkins, I. L., Eds.; Macmillan: London
    • Kertes, A. S. The chemistry of the formation and elimination of a third phase in organophosphorus and amine extraction systems. In Solvent Extraction Chemistry of Metals; McKay, H. A. C.; Healy, T. V.; Jenkins, I. L., Eds.; Macmillan: London, 1965; 377-399.
    • (1965) In Solvent Extraction Chemistry of Metals , pp. 377-399
    • Kertes, A.S.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.