Conformation control of oligosilanes by trimethylsilyl groups: Dodecamethyl-, Undecamethyl-2-trimethylsilyl- and Decamethyl-2, 4-bis(trimethylsilyl)-n-pentasilane studied by Raman spectroscopy and quantum chemical calculations

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Volumn 1, Issue 4, 2009, Pages 225-237

  Dzambaski, Ana ^a   Baumgartner, Judith ^a   Flock, Michaela ^a   Hassler, Karl ^a  

^a GRAZ UNIVERSITY OF TECHNOLOGY   (Austria)

Author keywords

Conformations; Pentasilanes; Quantum chemical calculations; Raman spectroscopy

Indexed keywords

CRYSTAL STRUCTURE; NEGATIVE IONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; QUANTUM CHEMISTRY; RAMAN SPECTROSCOPY; SILANES; SINGLE CRYSTALS; STRETCHING; X RAY DIFFRACTION;

1H NMR SPECTROSCOPY; PENTASILANES; QUANTUM CHEMICAL CALCULATIONS; REACTION SEQUENCES; SINGLE CRYSTAL X-RAY DIFFRACTION; SOLID-STATE MOLECULAR STRUCTURE; STRETCHING VIBRATIONS; TRIMETHYLSILYL GROUPS;

CONFORMATIONS;

EID: 77951624610     PISSN: 1876990X     EISSN: 18769918     Source Type: Journal    
DOI: 10.1007/s12633-009-9023-1     Document Type: Article

References (19)

1. Michl J, West R (2000) In: Jones RG, Ando W, Chojnowski J (Eds) Silicon-based polymers: The science and technology of their synthesis and applications. Kluwer Academic Publishers, Dordrecht, The Netherlands, pp 499-529.
2. Haaland A, Rypdal K, Stüger H, Volden HV (1995) Acta Chem. Scand. 48: 46.
3. Smith Z, Almenningen A, Hengge E, Kovar D (1982) J. Am. Chem. Soc. 104: 4362.
4. Teramae H, Michl J (1994) J. Mol. Cryst. Liq. Cryst. 256: 149.
5. Michl J, West R (2000) Acc. Chem. Res. 33: 821.
6. Eliel EL, Wilen SH (1994) Stereochemistry of organic compounds. Wiley, New York.
7. Hoffmann RW, Stahl M, Schopfer U, Frenking G (1998) Chem. Eur. J. 4: 559.
8. Chtchian S, Kempe R, Krempner C (2000) J. Organomet. Chem. 613: 208.
9. 2SiMeK is described in: Eur J Inorg Chem 221.
10. Stanislawski DA, West RJ (1980) Organomet. Chem. 204: 295.
11. Frisch MJ, Trucks GW, Schlegel HB, Scuseria GE, Robb MA, Cheeseman JR, Montgomery JA Jr, Vreven T, Kudin KN, Burant JC, Millam JM, Iyengar SS, Tomasi J, Barone V, Mennucci B, Cossi M, Scalmani G, Rega N, Petersson GA, Nakatsuji H, Hada M, Ehara M, Toyota K, Fukuda R, Hasegawa J, Ishida M, Nakajima T, Honda Y, Kitao O, Nakai H, Klene M, Li X, Knox JE, Hratchian HP, Cross JB, Adamo C, Jaramillo J, Gomperts R, Stratmann RE, Yazyev O, Austin AJ, Cammi R, Pomelli C, Ochterski JW, Ayala PY, Morokuma K, Voth GA, Salvador P, Dannenberg JJ, Zakrzewski VG, Dapprich S, Daniels AD, Strain MC, Farkas O, Malick DK, Rabuck AD, Raghavachari K, Foresman JB, Ortiz JV, Cui Q, Baboul AG, Clifford S, Cioslowski J, Stefanov BB, Liu G, Liashenko A, Piskorz P, Komaromi I, Martin RL, Fox DJ, Keith T, Al-Laham MA, Peng CY, Nanayakkara A, Challacombe M, Gill PMW, Johnson B, Chen W, Wong MW, Gonzalez C, Pople JA (2004) Gaussian 03, Revision C. 02. Gaussian, Wallingford.
12. Albinsson B, Antic D, Neumann F, Michl J (1999) J. Phys. Chem. A 103: 2184.
13. Fogarty HA, Ottosson H, Michl J (2006) J. Phys. Chem. B 110: 25485.
14. Raymond MK, Michl J (1998) Int. J. Quantum Chem. 72: 361.
15. Hölbling M, Flock MK, Hassler K (2007) ChemPhysChem. 8: 735.
16. Tekautz G, Binter A, Hassler K, Flock M (2006) ChemPhysChem 7: 421.
17. Lambert JB, Pflug JL, Denari JM (1996) Organometallics 15: 615.
18. Weiss S, Buchner M, Dorfmüller Th (1994) J. Phys. Condens. Matter 6: A217.
19. Dzambaski A, Flock M, Hassler K (2007) J. Raman Spectrosc. 38: 1212.