Investigation of clinoptilolite rich natural zeolites from Turkey: A combined XRF, TG/DTG, DTA and DSC study

Journal of Thermal Analysis and Calorimetry

Volumn 100, Issue 1, 2010, Pages 19-26

  Alver, Burcu Erdoǧan ^a   Sakizci, Meryem ^a   Yörükoǧullari, Ertuǧrul ^a  

^a ANADOLU UNIVERSITY   (Turkey)

Author keywords

Clinoptilolite; Dehydration; Natural zeolites; Thermal analysis; Turkey

Indexed keywords

CLINOPTILOLITE; CLINOPTILOLITES; DIFFERENTIAL SCANNING CALORIMETERS; DSC STUDIES; DTA CURVES; HIGHER TEMPERATURES; MASS LOSS; NATURAL ZEOLITES; SURFACE AREA; TEMPERATURE RANGE; TG/DTG-DTA; THERMAL ANALYSIS;

CALCIUM; DEHYDRATION; DEWATERING; DIFFERENTIAL SCANNING CALORIMETRY; DIFFERENTIAL THERMAL ANALYSIS; SILICATE MINERALS; SODIUM; WATER CONTENT;

ZEOLITES;

EID: 77951256475     PISSN: 13886150     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10973-009-0118-0     Document Type: Article

References (43)

1. Gottardi G, Galli E. Natural zeolites. Berlin: Springer; 1985.
2. Breck DW. Zeolite molecular sieves: structure, chemistry, and use. New York: Wiley; 1974.
3. Breck DW. Potential uses of natural and synthetic zeolites in industry. In: Towsand RP, editor. The properties and application of zeolites. London: The Chemical Society; 1980. p. 391-422.
4. Tsitsishvili G, Andronikashvili T, Kirov G, Filizova L. Natural zeolites. New York: Ellis Horwood; 1992.
5. FA Mumpton 1960 Clinoptilolite redefined Am Min 45 351 369 1:CAS:528:DyaF3cXnvFKhtA%3D%3D
6. MW Ackley RF Giese RT Yang 1992 Clinoptilolite: an untapped potential for kinetic gas separations Zeolites 12 780 787 10.1016/0144-2449(92)90050-Y 1:CAS:528:DyaK38XmsFyru70%3D (Pubitemid 23557458)
7. M Joshi V Joshi A Choudhari M Kasture 1997 Structural studies of natural heulandite using infrared spectroscopy Mater Chem Phys 48 160 168 10.1016/S0254-0584(97)80112-5 1:CAS:528:DyaK2sXjvVClt7k%3D
8. K Koyama Y Takeuchi 1977 Clinoptilolite: the distribution of potassium atoms and its role in thermal analysis Z Kristallogr 145 216 239 1:CAS:528:DyaE1cXmvVSltg%3D%3D
9. E Galli G Gottardi H Mayer A Preisinger E Passaglia 1983 The structure of potassium-exchanged heulandite at 293, 373 and 593 K Acta Crystallogr B39 189 197 1:CAS:528:DyaL3sXhvV2nsLk%3D
10. AB Merkle M Slaughter 1968 Determination and refinement of the structure of heulandite Am Min 53 1120 1138 1:CAS:528:DyaF1cXksFGiur8%3D
11. JR Boles 1972 Composition, optical properties, cell dimensions, and thermal stability of some heulandite-group zeolites Am Min 57 1452 1493
12. T Armbruster ME Gunter 1991 Stepwise dehydration of heulandite- clinoptilolite from Succor Creek Oregan, USA: a single crystal X-ray study at 100 K Am Min 76 1872 1883 1:CAS:528:DyaK38XisVOkuw%3D%3D
13. DL Bish 1984 Effects of exchangeable cation composition on the thermal expansion/contraction of clinoptilolite Clays Clay Min 32 444 452 10.1346/CCMN.1984.0320602 1:CAS:528:DyaL2MXjsV2nug%3D%3D
14. Bish DL. Effects of composition on the dehydration behavior of clinoptilolite and heulandite. In: Kallo D, Sherry HS, editors. Occurrence, properties and utilization of natural zeolites. Budapest: Akademiai Kiado; 1988. p. 565-76.
15. Bish DL. Thermal behavior of natural zeolites. In: Ming DW, Mumpton FA, editors. Natural zeolites'93: occurrence, properties, use. New York: Brockport; 1993. p. 259-69.
16. T Armbruster 1993 Dehydration mechanism of clinoptilolite and heulandite; single-crystal X-ray study of Na-poor, Ca-, K-, Mg-rich clinoptilolite at 100 K Am Min 78 260 264 1:CAS:528:DyaK3sXitFKksrY%3D
17. A Alberti 1972 On the crystal structure of the zeolite heulandite Tschermaks Min Petr Mitt 18 129 146 10.1007/BF01081798 1:CAS:528: DyaE2cXnsFamsg%3D%3D
18. Tsitsishvili GV, Andronikashvili TG, Kvernadze TK, Okugava NG. Natural zeolites. England: Ellis Horwoord Limited; 1992.
19. A Arcoya J Gonzalez G Llabre XL Seoane N Travieso 1996 Role of the counteractions on the molecular sieve properties of a clinoptilolite Microporous Mesoporous Mater 7 1 13 1:CAS:528:DyaK28XkvFGit7s%3D
20. Y Kudoh Y Takeuchi 1983 Thermal stability of clinoptilolite: the crystal structure at 350 °C Min J 11 392 406 10.2465/minerj.11.392 1:CAS:528:DyaL2cXkslKisLg%3D
21. Gottardi G. Mineralogy and crystal chemistry of zeolites. In: Sand LB, Mumpton FA, editors. Natural zeolites: occurrence, properties and uses. England: Oxford; 1978. p. 31-44.
22. A Alietti 1972 Polymorphism and crystal-chemistry of heulandites and clinoptilolites Am Min 57 1448 1462 1:CAS:528:DyaE38XlsFCrtL4%3D
23. A Alietti MF Brigatti L Poppi 1977 Natural Ca-rich clinoptilolites (heulandites of group 3) New data and review Neues Jahrb Min H11 493 501
24. F Çakicioǧlu-Özkan S Ülkü 2008 Diffusion Mechanism of Water Vapour in a Zeolitic tuff rich in clinoptilolite J Therm Anal Calorim 94 699 702 10.1007/s10973-008-9357-8
25. Knowlton GD, White TR, McKague HL. Thermal study of types of water associated with clinoptilolite. Clays Clay Min. 1981;29: 403-11.
26. A Araya A Dyer 1981 Studies on natural clinoptilolites. II. Cation mobilities in near homoionic clinoptilolites J Inorg Nucl Chem 43 595 598 10.1016/0022-1902(81)80509-X 1:CAS:528:DyaL3MXitFGiurs%3D
27. ÖÇ Duvarci Y Akdeniz F Özmihçi S Ülkü D Balköse M Çiftçioǧlu 2007 Thermal behaviour of a zeolitic tuff Ceram Int 33 795 801 10.1016/j.ceramint.2006.01.003 1:CAS:528:DC%2BD2sXjtl2isLc%3D (Pubitemid 46463988)
28. TH Perraki G Kakali E Kontori 2005 Characterization and pozzolanic activity of thermally treated zeolite J Therm Anal Calorim 82 109 113 10.1007/s10973-005-0849-5 1:CAS:528:DC%2BD2MXht1KgsbbK (Pubitemid 43073900)
29. TH Perraki A Orfanoudaki 2004 Mineralogical study of zeolites from Pentalofos area, Thrace, Greece Appl Clay Sci 25 9 16 10.1016/S0169-1317(03) 00156-X 1:CAS:528:DC%2BD2cXht1KgtLo%3D (Pubitemid 38300721)
30. A Langella M Pansini G Cerri P Cappelletti M De' Gennaro 2003 Thermal behavior of natural and cation-exchanged clinoptilolite from Sardinia (Italy) Clays Clay Miner 51 625 633 10.1346/CCMN.2003.0510605 1:CAS:528: DC%2BD3sXpvVarurg%3D (Pubitemid 38119238)
31. Y Akdeniz S Ülkü 2008 Thermal stability of Ag-exchanged clinoptilolite rich mineral J Therm Anal Calorim 94 703 710 10.1007/s10973-008- 9358-7 1:CAS:528:DC%2BD1cXhsFWju7jJ
32. E Chmielewská L Sabová K Jesenák 2008 Study of Adsorption Phenomena ongoing onto clinoptilolite with the immobilized interfaces J Therm Anal Calorim 92 567 571 10.1007/s10973-006-8315-6
33. Chamber of Mining Engineers of Turkey, Zeolit, http://www.maden.org.tr/ www/7.BYKP /ekutup96/0480/zeolit/zeolit.htm.
34. Anonymous 2004a. Zeolit. http://www.enlimining.net.
35. G Ataman N Gündoǧdu 1982 Analcimic zones in the Tertiary of Anatolia and their geologic positions Sediment Geol 31 89 99 10.1016/0037-0738(82)90009-4 1:CAS:528:DyaL38XovV2ntQ%3D%3D
36. Gündoǧdu MN. Neojen yasli Bigadiç sedimanter baseninin jeolojik, mineralojik ve jeokimyasal incelenmesi (in Turkish). PhD Thesis, Hacettepe Universitesi, Yerbilimleri Enstitüsü. Ankara, Turkey, 1982.
37. DW Ming JB Dixon 1987 Quantitative determination of clinoptilolite in soils by a cation-exchange capacity method Clays Clay Miner 35 463 468 10.1346/CCMN.1987.0350607 1:CAS:528:DyaL1cXpvVartA%3D%3D
38. S Brunauer LS Deming WE Deming E Teller 1940 On a theory of the van der Waals adsorption of gases J Am Chem Soc 62 1723 1732 10.1021/ja01864a025 1:CAS:528:DyaH3cXjslyqtg%3D%3D
39. Gregg SJ, Sing KSW. Adsorption, surface area and porosity. 2nd ed. London: Academic Press; 1982.
40. KSW Sing DH Everett RAW Haul L Moscou RA Pierotti J Rouquerol T Siemieniewska 1985 Reporting physisorption data for gas/solid systems with specific reference to the determination of surface area and porosity Pure Appl Chem 57 603 619 10.1351/pac198557040603 1:CAS:528:DyaL2MXhvFWrtb4%3D
41. 4-clinoptilolite Thermochim Acta 336 105 110 10.1016/S0040-6031(99)00210-5
42. P Castaldi L Santona C Cozza V Giuliano C Abbruzzese V Nastro P Melis 2005 Thermal and spectroscopic studies of zeolites exchanged with metal cations J Mol Struct 734 99 105 10.1016/j.molstruc.2004.09.009 1:CAS:528: DC%2BD2cXhtFamsr3K (Pubitemid 39647281)
43. Smith WF. Principles of materials science and engineering. 2nd ed. New York: McGraw Hill; 1990.