Spectrophotometric determination of thiocyanate in human saliva employing micropumping multicommutation flow system

Spectroscopy Letters

Volumn 43, Issue 3, 2010, Pages 213-219

  Silva Júnior, Joilton J ^a   Farias, Marcelo A ^a   Silva, Valdinete L ^a   Montenegro, Maria C B S M ^b   Araújo, Alberto N ^b   Lavorante, André F ^c   Paim, Ana Paula S ^a  

^a FEDERAL UNIVERSITY OF PERNAMBUCO   (Brazil)

^b UNIVERSITY OF PORTO   (Portugal)

^c UNIVERSIDADE FEDERAL RURAL DE PERNAMBUCO   (Brazil)

Author keywords

Human saliva; Multicommutation flow analysis; Multipumping; Spectrophotometry; Thiocyanate

Indexed keywords

EID: 77951191925     PISSN: 00387010     EISSN: 15322289     Source Type: Journal    
DOI: 10.1080/00387010903287094     Document Type: Article

References (35)

1. Lac, G. Saliva assays in clinical and research biology. Pathol. Biol. 2001,49,660-667.
2. Valdés, M. G.; Díaz-García, M. E. Determination of thiocyanate within physiological fluids and environmental samples: current practice and future trends. Crit. Rev. Anal. Chem. 2004, 34, 9-23.
3. Gay, J.-Y.; Fovet, Y.; Adib-Yadzi, M. About a synthetic saliva for in vitro studies. Talanta 2001, 53, 1103-1115.
4. Butts, W. C.; Kuehneman, M.; Widdowson, G. M. Automated method for determining serum thiocyanate, to distinguish smokers from nonsmokers. Clin. Chem. 1974, 20, 1344-1348.
5. Pinillos, S. C.; Vicente, I. S.; Bemal, J. G.; Asensio, J. S. Determination of thiocyanate by carbonyl sulphide (OCS) generation and gas-phase molecular absorption spectrometry. Anal. Chim. Acta. 1996, 318, 377-383.
6. García, M. S.; Ortuño, J. A.; Sánchez-Pedreño, C.; Albero, M. I.; Fernández, M. J. Flow-through bulk optode for spectrophotometric determination of thiocyanate and its application to water and saliva analysis. Sensors 2006, 6, 1224-1233.
7. Tsuge, K.; Kataoka, M.; Seto, Y. Cyanide and thiocyanate levels in blood and saliva of healthy adult volunteers. J. Health Sci. 2000, 46,343-350.
8. Torano, J. S.; van Kan, H. Simultaneous determination of the tobacco smoke uptake parameters nicotine, cotinine and thiocyanate in urine, saliva and hair, using gas chromatography-mass spectrometry for characterisation of smoking status of recently exposed subjects. Analyst 2003, 128, 838-843.
9. Bashammakh, A. S.; Bahaffi, S. O.; Al-Sibaai, A. A.; Al-Wael, H. O.; El-Shihawi, M. S. Extractive liquid-liquid spectrophotometric J. J. Silva Júnior et al. procedure for the determination of thiocyanate ions employing the ion pair reagent amiloride monohydrochloride. Anal. Chim. Acta. 2007,592,16-23.
10. Demkowska, I.; Polkowska, Z.; Namiesnik, J. Application of ion chromatography for the determination of inorganic ions, especially thiocyanates in human saliva samples as biomarkers of environmental tobacco smoke exposure. J. Chromatogr. B 2008, 875, 419-426.
11. Ardakani, M. M.; Jamshidpour, M.; Naeimi, H.; Moradi, L. Thiocyanate ion-selective PVC membrane electrode based on N,N0-ethylene-bis(4-methylsalicylidineiminato)nickel(II). Anal. Sci. 2006, 22,1221-1226.
12. van Staden, J.; Botha, A. Spectrophotometric determination of thiocyanate by sequential injection analysis. Anal. Chim. Acta. 2000,403,279-286.
13. Sweileh, J. A. Determination of cyanide and thiocyanate by a spectrophotometric flow-injection method. Anal. Chim. Acta. 1989, 220, 65-74.
14. Hassan, S. S. M.; Mohmoud, W. H.; Elgazwy, A. S. S. H.; Badawy, N. M. A novel potentiometric membrane sensor based on aryl palladium complex for selective determination of thiocyanate in the saliva and urine of cigarette smokers. Electroanalysis 2006, 18, 2070-2078.
15. Gong, B.; Gong, G. Fluorimetric melthod for the determination of thiocyanate with 20,70-dichlorofluorescein and iodine. Anal. Chim. Acta. 1999, 394, 171-175.
16. Bjergegaard, C.; Moller, P.; Sorensen, H. Determination of thiocyanate, iodide, nitrate and nitrite in biological samples by micellar electrokinetic capillary chromatography. J. Chromatogr. A 1995,717,409-414.
17. Gumus, G.; Demirata, B.; Apak, R. Simultaneous spectrophotometric determination of cyanide and thiocyanate after separation on a melamine-formaldehyde resin. Talanta 2000, 53, 305-315.
18. Themelis, D. G.; Tzanavaras, P. D. Solvent extraction flow-injection manifold for the simultaneous spectrophotometric determination of free cyanide and thiocyanateíons based upon on-line masking of cyanides by formaldehyde. Anal. Chim. Acta. 2002, 452, 295-302.
19. Chamjangali, M. A.; Bagherian, G.; Salek-Gilani, N. Determination of trace amounts of thiocyanate by a new kinetic procedure based on an induction period. Spectrochim. Acta. 2007, 67, 1252-1256.
20. Reis, B. F.; Giné, M. F.; Zagatto, E. A. G.; Lima, J. L. F. C.; Lapa, R. Multicommutation in flow analysis. Part 1. Binary sampling: concepts, instrumentation and spectrophotometric determination of iron in plant digests. Anal. Chim. Acta. 1994, 293, 129-138.
21. Lavorante, A. F.; Feres, M. A.; Reis B. F. Multicommutation in flow analysis: A versatile tool for the development of the automatic analytical procedure focused on the reduction of reagent consumption. Spectros. Lett. 2006, 39, 631-650.
22. Lapa, R. A. S.; Lima, J. L. F. C.; Reis, B. F.; Santos, J. L. M.; Zagatto, E. A. G. Multi-pumping in flow analysis: Concepts, instrumentation, potentialities. Anal. Chim. Acta. 2002, 466, 125-132.
23. Carneiro, J. M. T.; Zagatto, E. A. G.; Santos, J. L. M.; Lima, J. L. F. C. Spectrophotometric determination of phytic acid in plant extracts using a multi-pumping flow system. Anal. Chim. Acta. 2002, 474, 161-166.
24. Lima, J. L. F. C.; Sá, S. M. O.; Santos, J. L. M.; Zagatto, E. A. G. Multi-pumping flow system for the spectrophotometric determination of dipyrone in pharmaceutical preparations. J. Pharmaceut. Biomed. Anal. 2003, 32, 1011-1017.
25. Dias, A. C. B.; Santos, J. L. M.; Lima, J. L. F. C.; Zagatto, E. A. G. Multi-pumping flow system for spectrophotometric determination of bromhexine. Anal. Chim. Acta. 2003, 499, 107-113.
26. Prior, J. A. V.; Santos, J. L. M.; Lima, J. L. F. C. Sampling strategies exploiting multi-pumping flow systems. Anal. Bioanal. Chem. 2003, 375,1234-1239.
27. Lavorante, A. F.; Morales-Rubio, A.; de la Guardia, M.; Reis, B. F. Micro-pumping flow system for spectrophotometric determination of anionic surfactants in water. Anal. Bioanal. Chem. 2005, 381, 1305-1309.
28. Rocha, F. R. P.; Cordova, C. M. I.; Melchert, W. R. A multi-purpose flow system based on multi-commutation. Spectros. Lett. 2006, 39, 651-668.
29. Pons, C.; Toóth, I. V.; Rangel, A. O. S. S.; Forteza, R.; Cerdà, V. Multi-pumping flow system for the determination of dissolved orthophosphate and dissolved organic phosphorus in wastewater samples. Anal. Chim. Acta. 2006, 572, 148-154.
30. Ródenas-Torralba, E.; Morales-Rubio, A.; Lavorante, A. F.; Reis, B. F.; de la Guardia, M. Micropumping multicommutation turbidimetric analysis of waters. Talanta 2007, 73, 742-747.
31. Lima, J. L. F. C.; Santos, J. L. M.; Dias, A. C. B.; Ribeiro, M. F. T.; Zagatto, E. A. G. Multi-pumping flow systems: an automation tool. Talanta 2004, 64, 1091-1098.
32. Paim, A. P. S.; Kronka, E. A. M.; Reis, B. F.; Korn, M. Determinação espectrofotométrica de ácido ascórbico em fármacos empregando amostragem binária em fluxo. Quím. Nova. 1998, 21, 47-50.
33. Recalde-Ruiz, D. L.; Andrés-García, E.; Díaz-García, M. E. Development of flow analytical systems for monitoring thiocyanate biodegradation in waste waters. Anal. Lett. 2000, 33, 1603-1614.
34. Ródenas-Torralba, E.; Rocha, F. R. P.; Reis, B. F.; Morales-Rubio, A.; de la Guardia, M. Evaluation of a multicommuted flow system for photometric environmental measurements. J. Automat. Meth. Manag. Chem. 2006, 2006, 1-9.
35. Mendham, J.; Denney, R. C.; Barnes, J. D.; Thomas, M. J. K. Vogel-Análise Química Quantitativa, 6th ed.; LTC: Rio de Janeiro, 2002.