Catalytic copolymerization of ethylene with vinyl sulfones

Macromolecules

Volumn 43, Issue 8, 2010, Pages 3589-3590

  Bouilhac, Cécile ^a   Rünzi, Thomas ^a   Mecking, Stefan ^a  

^a UNIVERSITY OF KONSTANZ   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CHAIN INITIATION; CHAIN TRANSFER; CHAIN-ENDS; CO-MONOMER; END GROUPS; ETHYLENE PRESSURE; HYDRIDE ELIMINATION; LINEAR COPOLYMERS; MONOMER INSERTION; NMR ANALYSIS; POLYMER MAIN CHAIN; VINYL SULFONES;

COPOLYMERIZATION; FABRICS; PALLADIUM;

ETHYLENE;

EID: 77951169508     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma100237s     Document Type: Article

References (25)

1. Weast, R. C., Ed.; CRC Handbook of Chemistry and Physics, 60th ed.; CRC Press: Cleveland, OH, 1979; p E64.
2. (a) Schroeder, J. P.; Schroeder, D. C. In Vinyl and Diene Monomers, Part 3; Leonard, E. C., Ed.; Wiley-Interscience: New York, 1971; p 1487.
3. (b) Choe, H. S.; Giaccai, J.; Alamgir, M.; Abraham, K. M. Electrochim, Acta, 1995 40 (13-14), 2289-2293.
4. (c) Fujimori, K. J. Macromol. Sci. Chem. 1976, A10 (6), 1005-1015.
5. -1: (a) Schroeder, J. P.; Schroeder, D. C.; Jotikasthira, S. J. Polym. Sci., Part A-1 1972, 10, 2189-2195.
6. (b) Boor, J., Jr.; Finch, A. M. T J. Polym. Sci. Part A-1 1971, 9, 249-252.
7. Berkefeld, A.; Drexler, M.; Möller, H.; Mecking, S. J. Am. Chem. Soc. 2009, 131, 12613-12622.
8. (a) Boffa, L. S.; Novak, B. M. Chem. Rev. 2000, 100, 1479-1493.
9. (b) Chen, E. Y.-X. Chem. Rev. 2009, 109, 5157-5214.
10. (a) Johnson, L. K.; Mecking, S.; Brookhart, M. J. Am, Chem, Soc. 1996, 118, 267-268.
11. (b) Mecking, S.; Johnson, L. K.; Wang, L.; Brookhart, M. J. Am. Chem. Soc. 1998, 120, 888-899.
12. (c) Popeney, C. S.; Camacho, D. H.; Guan, Z. J. Am. Chem. Soc. 2007, 129,10062-10063.
13. Johnson, L.; Wang, L.; McLain, S.; Bennett, A.; Dobbs, K.; Hauptman, E.; Ionkin, A.; Ittel, S.; Kunitsky, K.; Marshall, W.; McCord, E.; Radzewich, C.; Rinehart, A.; Sweetman, K. J.; Wang, Y.; Yin, Z.; Brookhart, M. ACS Symp. Ser. 2003, 857, 131-142.
14. Drent, E.; van Dijk, R.; van Ginkel, R.; van Oort, B.; Pugh, R. I. Chem, Commun. 2002, 744-745.
15. Skupov, K. M.; Marella, P. R.; Simard, M.; Yap, G. P. A.; Allen, N.; Conner, D.; Goodall, B. L.; Claverie, J. P. Macromol. Rapid Commun. 2007, 28, 2033-2038.
16. Skupov, K. M.; Piche, L.; Claverie, J. P. Macromolecules 2008, 41, 2309-2310.
17. Liu, S.; Borkar, S.; Newsham, D.; Yennawar, H.; Sen, A. Organometallics 2007, 26, 210-216.
18. Luo, S.; Vela, J.; Lief, G. R.; Jordan, R. F. J. Am. Chem. Soc. 2007, 129, 8946-8947.
19. (a) Domski, G. J.; Rose, J. M.; Coates, G. W.; Bolig. A. D.; Brookhart, M. Prog. Polvm. Sci. 2007, 32, 30-92.
20. (b) Berkefeld, A.; Mecking, S. Angew. Chem. Int. Ed. 2008, 47, 2538-2542.
21. (c) Nakamura, A.; Ito, S.; Nozaki, K. Chem. Rev. 2009, 109, 5215-5244.
22. Kochi, T.; Noda, S.; Yoshimura, K.; Nozaki, K. J. Am. Chem, Soc. 2007, 129, 8948-8949.
23. Ito, S.; Munakata, K.; Nakamura, A.; Nozaki, K. J. Am. Chem. Soc. 2009, 131, 14606-14607.
24. Guironnet, D.; Roesle, P.; Rünzi, T.; Göttker-Schnetmann, I.; Mecking, S. J. Am, Chem. Soc. 2009, 131, 422-423.
25. The extent of chain transfer after an MVS insertion (4:1 MVS vs ethylene-based end groups; 13.9 mol % MVS incorporation) is similar to the behaviour observed in methyl acrylate (MA) copolymerization affording a copolymer of comparative composition (3:1 MA vs ethylene-based end groups; 12.7 mol % MA incorporation).