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1
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0010580277
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West, R.; Fink, M. J.; Michl, J. Science 1981, 214, 1343
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West, R.1
Fink, M.J.2
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2
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77956717087
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For recent comprehensive reviews of disilenes, see
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For recent comprehensive reviews of disilenes, see: Okazaki, R.; West, R. Adv. Organomet. Chem. 1996, 39, 231
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Okazaki, R.1
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0000936858
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Eds.; Rappoport Z. Apeloig Y. Wiley: Chichester, U.K.
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Weidenbruch, M. In The Chemistry of Organic Silicon Compounds; Rappoport, Z.; Apeloig, Y., Eds.; Wiley: Chichester, U.K., 2001; Vol. 3, p 391.
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Weidenbruch, M.1
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6
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0001170860
-
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For a recent review on silyl migrations, see:; In,;, Rappoport Z. Apeloig Y. Eds., Wiley, Chichester, U.K., Chapter 16
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For a recent review on silyl migrations, see: Kira, M.; Iwamoto, T. In The Chemistry of Organic Silicon Compounds, Rappoport, Z.; Apeloig, Y., Eds., Wiley, Chichester, U.K., 2001,; Vol. 3, Chapter 16, p 853.
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(2001)
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Kira, M.1
Iwamoto, T.2
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7
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0000154792
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Yokelson, H.; Maxka, J.; Siegel, D. A.; West, R. J. Am. Chem. Soc. 1986, 108, 4239
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Yokelson, H.1
Maxka, J.2
Siegel, D.A.3
West, R.4
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8
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0001371564
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Yokelson, H.; Siegel, D. A.; Millevolte, A. J.; Maxka, J.; West, R. Organometallics 1990, 9, 1005
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Organometallics
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Yokelson, H.1
Siegel, D.A.2
Millevolte, A.J.3
Maxka, J.4
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-
9
-
-
84981903846
-
-
For a review on dyotropic rearrangement
-
Reetz, M. T. Angew. Chem., Int. Ed. Engl. 1972, 11, 129 For a review on dyotropic rearrangement, see
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Angew. Chem., Int. Ed. Engl.
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Reetz, M.T.1
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11
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0001461661
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Kira, M.; Ohya, S.; Iwamoto, T.; Ichinohe, M.; Kabuto, C. Organometallics 2000, 19, 1817
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Kira, M.1
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12
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0142025003
-
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Iwamoto, T.; Okita, J.; Kabuto, C.; Kira, M. J. Organomet. Chem. 2003, 686, 105
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Iwamoto, T.1
Okita, J.2
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13
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27644474674
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Kobayashi, H.; Iwamoto, T.; Kira, M. J. Am. Chem. Soc. 2005, 127, 15376
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Kobayashi, H.1
Iwamoto, T.2
Kira, M.3
-
14
-
-
51349140075
-
-
For examples of base or Lewis acid induced ring expansion reaction of methylenecyclobutane to cyclopentene derivatives, see
-
For examples of base or Lewis acid induced ring expansion reaction of methylenecyclobutane to cyclopentene derivatives, see: Jiang, M.; Shi, M. Org. Lett. 2008, 10, 2239
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(2008)
Org. Lett.
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Jiang, M.1
Shi, M.2
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15
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0000640551
-
-
references cited therein
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Samuel, S. P.; Niu, T.; Erickson, K. L. J. Am. Chem. Soc. 1989, 111, 1429 and references cited therein.
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-
-
Samuel, S.P.1
Niu, T.2
Erickson, K.L.3
-
16
-
-
77951143873
-
-
2Si - Si)
-
2Si - Si).
-
-
-
-
17
-
-
77951112913
-
-
3, R1 = 0.0317 (I > 2- (I)), wR2 = 0.0832 (all data), GOF = 1.082
-
3, R1 = 0.0317 (I > 2- (I)), wR2 = 0.0832 (all data), GOF = 1.082.
-
-
-
-
18
-
-
77951108158
-
-
2O. For details, see the Supporting Information
-
2O. For details, see the Supporting Information.
-
-
-
-
19
-
-
77951131853
-
-
Note
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14 (952.41): C, 47.92; H, 10.79. Found: C, 47.82; H, 10.61.
-
-
-
-
20
-
-
77951117210
-
-
3) angles as viewed along the Si - Si axis
-
3) angles as viewed along the Si - Si axis.
-
-
-
-
21
-
-
33748215890
-
-
Kira, M.; Maruyama, T.; Kabuto, C.; Ebata, K.; Sakurai, H. Angew. Chem., Int. Ed. Engl. 1994, 33, 1489
-
(1994)
Angew. Chem., Int. Ed. Engl.
, vol.33
, pp. 1489
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-
Kira, M.1
Maruyama, T.2
Kabuto, C.3
Ebata, K.4
Sakurai, H.5
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22
-
-
3843144920
-
-
Sekiguchi, A.; Inoue, S.; Ichinohe, M.; Arai, Y. J. Am. Chem. Soc. 2004, 126, 9626
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(2004)
J. Am. Chem. Soc.
, vol.126
, pp. 9626
-
-
Sekiguchi, A.1
Inoue, S.2
Ichinohe, M.3
Arai, Y.4
-
23
-
-
51149215937
-
-
The model compound 4- shown in Figure 4 is predicted to adopt an almost planar structure at the B3LYP/6-31G(d) level (see the Supporting Information). For examples of theoretical studies on the flat potential energy surface for trans-bending of disilenes, see
-
The model compound 4- shown in Figure 4 is predicted to adopt an almost planar structure at the B3LYP/6-31G(d) level (see the Supporting Information). For examples of theoretical studies on the flat potential energy surface for trans-bending of disilenes, see: Goldberg, D. E.; Hitchcock, P. B.; Lappert, M. F.; Thomas, K. M.; Thorne, A. J.; Haaland, A.; Schilling, B. E. R. J. Chem. Soc., Dalton Trans. 1986, 2387
-
(1986)
J. Chem. Soc., Dalton Trans.
, pp. 2387
-
-
Goldberg, D.E.1
Hitchcock, P.B.2
Lappert, M.F.3
Thomas, K.M.4
Thorne, A.J.5
Haaland, A.6
Schilling, B.E.R.7
-
29
-
-
77951115634
-
-
11 (693.79): C, 45.01; H, 10.46. Found: C, 44.87; H, 10.40
-
11 (693.79): C, 45.01; H, 10.46. Found: C, 44.87; H, 10.40.
-
-
-
-
30
-
-
77951137690
-
-
3, R1 = 0.0192 (I > 2- (I)), wR2 = 0.0524 (all data), GOF = 1.072
-
3, R1 = 0.0192 (I > 2- (I)), wR2 = 0.0524 (all data), GOF = 1.072.
-
-
-
-
31
-
-
77951143347
-
-
An Eyring plot for the isomerization of 4 to 5 is shown in the Supporting Information
-
An Eyring plot for the isomerization of 4 to 5 is shown in the Supporting Information.
-
-
-
-
32
-
-
0000897946
-
-
Silyldisilene-disilanylsilylene rearrangements were observed by Sakurai and co-workers
-
Silyldisilene-disilanylsilylene rearrangements were observed by Sakurai and co-workers: Sakurai, H.; Sakaba, H.; Nakadaira, Y. J. Am. Chem. Soc. 1982, 104, 6156
-
(1982)
J. Am. Chem. Soc.
, vol.104
, pp. 6156
-
-
Sakurai, H.1
Sakaba, H.2
Nakadaira, Y.3
-
33
-
-
0011624193
-
-
Sakurai, H.; Nakadaira, Y.; Sakaba, H. Organometallics 1983, 2, 1484
-
(1983)
Organometallics
, vol.2
, pp. 1484
-
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Sakurai, H.1
Nakadaira, Y.2
Sakaba, H.3
-
34
-
-
32544439205
-
-
See also
-
Sanji, T.; Mori, T.; Sakurai, H. J. Organomet. Chem. 2006, 691, 1169 See also
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(2006)
J. Organomet. Chem.
, vol.691
, pp. 1169
-
-
Sanji, T.1
Mori, T.2
Sakurai, H.3
-
35
-
-
0344584872
-
-
Ichinohe, M.; Kinjo, R.; Sekiguchi, A. Organometallics 2003, 22, 4621
-
(2003)
Organometallics
, vol.22
, pp. 4621
-
-
Ichinohe, M.1
Kinjo, R.2
Sekiguchi, A.3
-
37
-
-
77951134987
-
-
2Si group
-
2Si group.
-
-
-
-
39
-
-
5344232096
-
-
Matsumoto, S.; Tsutsui, S.; Kwon, E.; Sakamoto, K. Angew. Chem., Int. Ed. 2004, 43, 4610
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(2004)
Angew. Chem., Int. Ed.
, vol.43
, pp. 4610
-
-
Matsumoto, S.1
Tsutsui, S.2
Kwon, E.3
Sakamoto, K.4
-
40
-
-
17644388472
-
-
Tanaka, H.; Kwon, E.; Tsutsui, S.; Matsumoto, S.; Sakamoto, K. Eur. J. Inorg. Chem. 2005, 1235
-
(2005)
Eur. J. Inorg. Chem.
, pp. 1235
-
-
Tanaka, H.1
Kwon, E.2
Tsutsui, S.3
Matsumoto, S.4
Sakamoto, K.5
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