Solid particle decomposition and hydrolysis reaction kinetics in Cu-Cl thermochemical hydrogen production

International Journal of Hydrogen Energy

Volumn 35, Issue 10, 2010, Pages 4877-4882

  Daggupati, V N ^a   Naterer, G F ^a   Gabriel, K S ^a   Gravelsins, R J ^a   Wang, Z L ^a  

^a UNIVERSITY OF ONTARIO INSTITUTE OF TECHNOLOGY   (Canada)

Author keywords

Chemical equilibrium constant; Copper chlorine cycle; Hydrogen production; Hydrolysis

Indexed keywords

CHEMICAL EQUILIBRIUM CONSTANT; CHEMICAL EQUILIBRIUMS; COPPER-CHLORINE CYCLE; CUPRIC CHLORIDE; CUPROUS CHLORIDE; DECOMPOSITION REACTION; EQUILIBRIUM CONVERSION; FIRST ORDER KINETICS; HYDROLYSIS REACTION; OPERATING PARAMETERS; REVERSIBLE REACTION; SOLID CONVERSION; SOLID PARTICLES; THERMOCHEMICAL HYDROGEN PRODUCTION;

ASSOCIATION REACTIONS; CHLORINE; CHLORINE COMPOUNDS; COPPER; COPPER COMPOUNDS; EQUILIBRIUM CONSTANTS; GAS PRODUCERS; HYDROLYSIS; PHASE EQUILIBRIA;

HYDROGEN PRODUCTION;

EID: 77951113137     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2009.08.082     Document Type: Article

References (18)

1. Lewis MA, Serban M, Basco JK. Hydrogen production at <550 C using a low temperature thermochemical cycle. In: ANS/ENS Exposition, New Orleans; November 2003.
2. Naterer G.F., Gabriel K.S., Wang Z.L., Daggupati V.N., and Gravelsins R. Thermochemical hydrogen production with a copper-chlorine cycle I: oxygen release from copper oxychloride decomposition. Int J Hydrogen Energy 33 (2008) 5439-5450
3. Naterer G.F., Suppiah S., Lewis M., Gabriel K.S., Dincer I., Rosen M.A., et al. Recent Canadian advances in nuclear-based hydrogen production and the thermochemical Cu-Cl Cycle. Int J Hydrogen Energy 34 (2009) 2901-2917
4. Funk J.E. Thermochemical hydrogen production: past and present. Int J Hydrogen Energy 26 3 (2001) 185-190
5. Yildiz B., and Kazimi M.S. Efficiency of hydrogen production systems using alternative energy technologies. Int J Hydrogen Energy 31 (2006) 77-92
6. Berman A., and Epstein M. The kinetics of hydrogen production in the oxidation of liquid zinc with water vapor. Int J Hydrogen Energy 25 (2000) 957-967
7. 2 production by the 2-step ZnO/Zn water-splitting thermochemical cycle. Int J Hydrogen Energy 31 (2006) 55-61
8. Haseli Y., Naterer G.F., and Dincer I. Fluid-particle mass transport of cupric chloride hydrolysis in a fluidized bed. Int J Heat Mass Transfer 52 (2009) 2507-2515
9. Haseli Y., Dincer I., and Naterer G.F. Hydrodynamic gas-solid model of cupric chloride particles reacting with superheated steam for thermochemical hydrogen production. Chem Eng Sci 63 (2008) 4596-4604
10. Orhan M.F., Dincer I., and Rosen M.A. Energy and exergy analysis of the fluidized bed of a copper-chlorine cycle for nuclear based hydrogen production via thermochemical water decomposition. Chem Eng Res Des 87 5 (2009) 684-694
11. Orhan M.F., Dincer I., and Rosen M.A. Energy and exergy assessments of the hydrogen production step of a copper-chlorine thermochemical water splitting cycle driven by nuclear based heat. Int J Hydrogen Energy 33 (2008) 6456-6466
12. Orhan M.F., Dincer I., and Rosen M.A. Thermodynamic analysis of the copper production step in a copper-chlorine cycle for hydrogen production. Thermochim Acta 480 (2008) 22-29
13. Orhan M.F., Dincer I., and Rosen M.A. The oxygen production step of a copper-chlorine thermochemical water decomposition cycle for hydrogen production: energy and exergy analysis. Chem Eng Sci 64 (2009) 860-869
14. Bade S., and Hoffmann U. Modeling of the simultaneous comminution and chemical reaction in a non-catalytic gas-solid batch reactor. Chem Eng Sci 52 (1997) 2715-2728
15. Udhe G., and Hoffmann U. Noncatalytic gas-solid reactions: modeling of simultaneous reaction and formation of surface with a nonisothermal cracking core model. Chem Eng Sci 52 (1997) 1045-1054
16. Pritzker M.D. Shrinking core model for systems with facile heterogeneous and homogeneous reactions. Chem Eng Sci 51 (1996) 3631-3645
17. Niksiar A., and Rahimi A. A study on deviation of non-catalytic gas-solid reaction models due to heat effects and changing of solid structure. Powder Technol 193 (2009) 101-109
18. Ferrandon MS, Lewis MA, Tatterson DF, Nankani RV, Kumar M, Wedgewood LE, et al. The hybrid Cu-Cl thermochemical cycle. I. Conceptual process design and H2A cost analysis. II. Limiting the formation of CuCl during hydrolysis. In: NHA annual hydrogen conference, Sacramento Convention Center, CA, USA; March 30-April 3, 2008.