Synthesis of thiol-functionalized spent grain as a novel adsorbent for divalent metal ions

Bioresource Technology

Volumn 101, Issue 15, 2010, Pages 6269-6272

  Chai, Liyuan ^a   Li, Qingzhu ^a   Zhu, Yonghua ^a   Zhang, Zhiyuan ^a   Wang, Qingwei ^a   Wang, Yunyan ^a   Yang, Zhihui ^a  

^a CENTRAL SOUTH UNIVERSITY   (China)

Author keywords

Adsorption; Functionalization; Heavy metal ions; Spent grain; Thiol groups

Indexed keywords

ADSORPTION CAPACITIES; ANALYTICAL RESULTS; CONTAMINATED WATER; DIVALENT METAL ION; DOUBLE BONDS; ESTER LINKAGES; FUNCTIONALIZATION; FUNCTIONALIZATIONS; FUNCTIONALIZED; METAL LOADINGS; N ,N-DIMETHYLFORMAMIDE; SODIUM SULFIDES; SPENT GRAINS; THIOGLYCOLLIC ACID; THIOL GROUPS; X RAY FLUORESCENCE ANALYSIS;

ADSORBENTS; ADSORPTION; CHEMICAL BONDS; CHEMICAL MODIFICATION; DENSITY (SPECIFIC GRAVITY); DIMETHYLFORMAMIDE; ESTERS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; GRAFTING (CHEMICAL); HEAVY METALS; HEAVY WATER; METAL IONS; METALS; SODIUM COMPOUNDS; WATER POLLUTION; X RAY PHOTOELECTRON SPECTROSCOPY; ZINC;

CHEMICALS REMOVAL (WATER TREATMENT);

ADSORBENT; METAL ION; N,N DIMETHYLFORMAMIDE; SODIUM SULFIDE; THIOGLYCOLIC ACID; ZINC ION;

ADSORPTION; CATALYST; FTIR SPECTROSCOPY; HEAVY METAL; POLLUTANT REMOVAL; THIOL; WATER POLLUTION; X-RAY FLUORESCENCE; X-RAY SPECTROSCOPY;

ADSORPTION; ARTICLE; BREWING; CHEMICAL MODIFICATION; CONTROLLED STUDY; CULTURE MEDIUM; GRAIN; INFRARED SPECTROSCOPY; PRIORITY JOURNAL; X RAY FLUORESCENCE; X RAY PHOTOELECTRON SPECTROSCOPY;

ADSORPTION; CEREALS; INDUSTRIAL WASTE; IONS; METALS, HEAVY; SULFHYDRYL COMPOUNDS; ULTRAFILTRATION;

EID: 77951094268     PISSN: 09608524     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.biortech.2010.03.009     Document Type: Article

References (19)

1. Balistrieri L.S., and Murray J.W. The surface chemistry of goethite (alpha FeOOH) in major ion seawater. Am. J. Sci. 281 (1981) 788-806
2. Celo V., Ananth R.V., Scott S.L., and Lean D.R.S. Methylmercury artifact formation during solid-phase extraction of water samples using sulfhydryl cotton fiber adsorbent. Anal. Chim. Acta 516 (2004) 171-177
3. Dubey S.P., and Gopal K. Application of natural adsorbent from silver impregnated Arachis hypogaea based thereon in the processes of hexavalent chromium for the purification of water. J. Hazard. Mater. 164 (2009) 968-975
4. Lagadic I.L., Mitchell M.K., and Payne B.D. Highly effective adsorption of heavy metal ions by a thiol-functionalized magnesium phyllosilicate clay. Environ. Sci. Technol. 35 (2001) 984-990
5. Lee Y.H., and Mowrer J. Determination of methylmercury in natural waters at the sub-nanograms per litre level by capillary gas chromatography after adsorbent preconcentration. Anal. Chim. Acta 221 (1989) 259-268
6. Liu J.F., Zhang L.G., Gu N., Ren J.Y., Wu Y.P., Lu Z.H., Mao P.S., and Chen D.Y. Fabrication of colloidal gold micro-patterns using photolithographed self-assembled monolayers as templates. Thin Solid Films 327 (1998) 176-179
7. Low K.S., Lee C.K., and Liew S.C. Sorption of cadmium and lead from aqueous solutions by spent grain. Process Biochem. 36 (2000) 59-64
8. Lu S., and Gibb S.W. Copper removal from wastewater using spent-grain as biosorbent. Bioresour. Technol. 99 (2008) 1509-1517
9. Mao J., Won S.W., Vijayaraghavan K., and Yun Y.S. Surface modification of Corynebacterium glutamicum for enhanced Reactive Red 4 biosorption. Bioresour. Technol. 100 (2009) 1463-1466
10. Mosier N., Wyman C., Dale B., Elander R., Lee Y.Y., Holtzapple M., and Ladisch M. Features of promising technologies for pretreatment of lignocellulosic biomass. Bioresour. Technol. 96 (2005) 673-686
11. Nomanbhay S.M., and Palanisamy K. Removal of heavy metal from industrial wastewater using chitosan coated oil palm shell charcoal. Electron. J. Biotechnol. 8 (2005) 43-53
12. Russ W., Mörtel H., and Meyer-Pittroff R. Application of spent grains to increase porosity in bricks. Constr. Build. Mater. 19 (2005) 117-126
13. Socrates G. Infrared Characteristic Group Frequencies (1980), Wiley, New York
14. Wang S.G., Sun X.F., Liu X.W., Gong W.X., Gao B.Y., and Bao N. Chitosan hydrogel beads for fulvic acid adsorption: behaviors and mechanisms. Chem. Eng. J. 142 (2008) 239-247
15. Xie J.Z., Chang H.L., and Kilbane J.J. Removal and recovery of metal ions from wastewater using biosorbents and chemically modified biosorbents. Bioresour. Technol. 57 (1996) 127-136
16. Xiros C., Topakas E., Katapodis P., and Christakopoulos P. Evaluation of Fusarium oxysporum as an enzyme factory for the hydrolysis of brewer's spent grain with improved biodegradability for ethanol production. Ind. Crops Prod. 28 (2008) 213-224
17. Xue X., and Li F. Removal of Cu(II) from aqueous solution by adsorption onto functionalized SBA-16 mesoporous silica. Micropor. Mesopor. Mater. 116 (2008) 116-122
18. Yu M., Tian W., Sun D., Shen W., Wang G., and Xu N. Systematic studies on adsorption of 11 trace heavy metals on thiol cotton fiber. Anal. Chim. Acta 428 (2001) 209-218
19. Zhu J., Deng B., Yang J., and Gang D. Modifying activated carbon with hybrid ligands for enhancing aqueous mercury removal. Carbon 47 (2009) 2014-2025