The effect of OH radicals on Cr-I spectral lines emitted by DC glow discharges

Spectrochimica Acta - Part B Atomic Spectroscopy

Volumn 65, Issue 3, 2010, Pages 218-224

  Mezei, P ^a   Cserfalvi, T ^b   Hartmann, P ^a   Bencs, L ^a  

^a INSTITUTE OF EXPERIMENTAL MEDICINE   (Hungary)

^b Aqua Concorde Water Analysis R and D LLC   (Hungary)

Author keywords

Atmospheric glow discharge; Atomic emission spectroscopy; Electrolyte cathode

Indexed keywords

AMBIENT AIR; ATMOSPHERIC GLOW DISCHARGE; ATMOSPHERIC PRESSURE GLOW DISCHARGE; CATHODE REGION; DC GLOW DISCHARGE; ELECTROLYTE CATHODE; ENERGY TRANSFER PROCESS; GAS ATMOSPHERE; GAS PHASE COMPOSITION; INTENSITY DISTRIBUTION; LOW PRESSURES; METAL CATHODES; NONRESONANT; OH RADICAL; RESONANCE LINE; RESONANT ENERGY TRANSFER; SPECTRAL LINE; VIBRATIONAL LEVELS;

ATMOSPHERIC COMPOSITION; ATMOSPHERIC PRESSURE; ATOMIC EMISSION SPECTROSCOPY; ATOMIC SPECTROSCOPY; ATOMS; ELECTROLYTES; ENERGY TRANSFER; FREE RADICALS; GLOW DISCHARGES; HELIUM; WATER VAPOR;

CHROMIUM;

EID: 77951091682     PISSN: 05848547     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.sab.2010.02.010     Document Type: Article

References (37)

1. Mezei P., and Cserfalvi T. Electrolyte cathode atmospheric glow discharges for direct solution analysis. Appl. Spectr. Rev. 42 (2007) 573-603
2. Mezei P., Cserfalvi T., and Csillag L. The spatial distribution of the temperatures and the emitted spectrum in the electrolyte cathode atmospheric glow discharge. J. Phys. D Appl. Phys. 38 (2005) 2804-2811
3. Cserfalvi T., and Mezei P. Investigation on the element dependency of sputtering processes in the electrolyte cathode atmospheric discharge. J. Anal. At. Spectrom. 20 (2005) 939-944
4. Hickling A. Electrochemical processes in glow discharge electrolysis at gas-solution interface. In: Bockris J.M., and Conway B.E. (Eds). Modern aspects in Electrochemistry vol. 6 (1971), Butterworths, London
5. Park Y.S., Ku S.H., Hong S.H., Kim H.J., and Piepmeier E.H. Fundamental studies of electrolyte-as-cathode glow discharge-atomic emission spectroscopy for determination of trace metals in flowing water. Spectrochim. Acta Part B 53 (1998) 1167-1179
6. Gambling W.A., and Edels H. The high pressure glow discharge in air. Brit. J. Appl. Phys. 5 (1954) 36-39
7. Massey T.J. Constricted discharges in the rare gases II. Analysis of the macroscopic properties of the discharges. J. Appl. Phys. 36 (1965) 373-380
8. Mezei P., Cserfalvi T., and Jánossy M. On the pressure dependence of the positive column cross section in a high-pressure glow discharge. J. Phys. D Appl. Phys. 34 (2001) 1914-1918
9. Francis G. The Glow discharge at low pressure. In: Flügge S. (Ed). Encyclopedia of Physics vol. 22 (1956), Spriger, Berlin 53-208
10. Marić D., Hartmann P., Malović G., Donkó Z., and Petrović Z.L. Measurements and modelling of axial emission profile in abnormal glow discharges in argon: heavy-particles processes. J. Phys. D Appl. Phys. 36 (2003) 2639-2648
11. Rózsa K., Gallagher A., and Donkó Z. Excitation of Ar lines in the cathode region of a dc discharge. Phys. Rev. E 52 1 (1995) 913-918
12. NIST (National Institute of Standard and Technology) Atomic Specrtoscopy Database http://physics.nist.gov/phys.ref.data.
13. Willett C.S. Introduction to Gas Leasers: Population Inversion Mechanisms (1974), Pergamon Press, Oxford
14. Mezei P., Cserfalvi T., Jánossy M., Szo{double acute}cs K., and Kim H.J. Similarity laws for glow discharges with cathodes of metal and an electrolyte. J. Phys. D Appl. Phys. 31 (1998) 2818-2825
15. Dolan T.J. Electron and ion collisions with water vapour. J. Phys. D Appl. Phys. 26 (1993) 4-8
16. Raiser Y.P. Gas Discharge Physics (1991), Springer, Berlin
17. Massey H.S.W., and Gilbody W.B. Recombination. In: Massey H.S.W., et al. (Ed). Electronic and Ionic Impact Phenomena vol. IV (1974), Clarendon, Oxford
18. N. Boudesocque, C. Vandensteendam, C. Lafon, C. Girold, Hydrogen production by thermal water splitting using a thermal plasma, in: Proceedings of the 16th World Hydrogen Energy Conference, WHEC 16, 13-16 June Lyon, France, 2006.
19. NIST Chemical Kinetic Database, http://kinetics.nist.gov/kinetics.
20. Cserfalvi T., and Mezei P. Direct solution analysis by glow discharge: electrolyte-cathode discharge spectrometry. J. Anal. At. Spectrom. 9 (1994) 345-349
21. Medovic S., and Locke B.R. Primary chemical reactions in pulsed electrical discharge channels in water. J. Phys. D Appl. Phys. 40 (2007) 7734-7746
22. Ruscic B., Wagner A.F., Harding L.B., Asher R.L., et al. On the enthalpy of formation of hydroxyl radical and gas-phase bond dissociation energies of water and hydroxyl. J. Phys. Chem. A 106 (2002) 2727-2747
23. Soloshenko I.A., Tsiolko V.V., Pogulay S.S., et al. Effect of water adding on kinetics of barrier discharge in air. Plasma Source Sci. Technol. 18 (2009) 045019 (15pp)
24. Dieke G.H., and Crosswhite H.M. The ultraviolet bands of OH. J. Quant. Spectrosc. Radiat. Transfer. 2 (1961) 97-199
25. Herzberg G. The spectra and structures of simple free radicals. An introduction to molecular spectroscopy (1971), Cornell University Press, Ithaca, London
26. Mavrodineanu R., and Boiteux H. L'Analyse Spectrale Quantitative par La Flamme (1954), Masson et Cie, Paris
27. Strelnitskii V.S. Cosmic masers. Sov. Phys. Usp. 17 4 (1975) 507-527
28. www.cfa.harvard.edu/HITRAN.
29. Bochinski J.R., Hudson E.R., Lewanddowski H.J., and Ye J. Cold free-radical molecules in the laboratory frame. Phys. Rev. A 70 (2004) 043410 (18pp)
30. 2Π electronic system of OH. J. Chem. Phys. 109 2 (1998) 439-448
31. Rosen B. Spectroscopic Data relative to Diatomic Molecules, in International Tables of Selected Constants 17 (1970), Pergamon Press, Oxford
32. Mckinley J.D., Garvin J.D., and Boudart M.J. Production of excited hydroxil radicals in the hydrogen atom-ozone reaction. J. Chem. Phys. 23 5 (1955) 784-786
33. 3 atomic flame. J. Chem. Phys. 32 3 (1960) 880-887
34. i state of OH(v = 0-10). J. Mol. Spectrosc. 214 (2002) 225-226
35. Nelson D.D., Schiffmann A., and Nesbit J. Absolute infrared moments for open shell diatomics for J dependence of transition intensities: application to OH. J. Chem. Phys. 90 (1989) 5443-5454
36. Goldman A., Schoenfeld W.G., Goorvitch D., Chackerian C., Dothe H., Mélen F., Abrams M.C., and Selby J.E.A. Updated line parameters for OH Χ2Π-Χ2Π (v″, v′)transitions. J. Quant. Spectrosc. Radiat. Transfer 59 (1998) 453-469
37. Mezei P., and Cserfalvi T. Charge densities in the electrolyte cathode atmospheric glow discharge (ELCAD). Eur. Phys. J. Appl. Phys. 40 (2007) 89-94