Effect of the silica content on the physico-chemical and relaxation properties of hybrid polymer/silica nanocomposites of P(EMA-co-HEA)

European Polymer Journal

Volumn 46, Issue 5, 2010, Pages 910-917

  Valles Lluch A ^a,b   Gallego Ferrer, G ^a,b,c   Monleon Pradas M ^a,b,c  

^a UNIVERSITAT POLITÈCNICA DE VALÈNCIA   (Spain)

^b CENTRO DE INVESTIGACIÓN PRÍNCIPE FELIPE   (Spain)

^c BIOMATERIALES Y NANOMEDICINA CIBER BBN   (Spain)

Author keywords

Acrylate; Bioactivity; Nanocomposite; Silica; Sol gel

Indexed keywords

ACRYLATE; BONE SUBSTITUTES; CANDIDATE MATERIALS; COMPRESSION PROPERTIES; COPOLYMER MATRIX; ETHYL METHACRYLATES; HYDROXYETHYL ACRYLATE; INORGANIC NETWORK; MATRIX; NANO SCALE; PHYSICO-CHEMICALS; PHYSICOCHEMICAL PROPERTY; POLYMERIC MATRICES; REINFORCING EFFECTS; RELAXATION PROPERTY; SILANOL GROUPS; SILICA CONTENT; SILICA SOL GELS; SURFACE WETTABILITY;

ANGLE MEASUREMENT; CHEMICAL PROPERTIES; CONTACT ANGLE; COPOLYMERIZATION; GELS; MECHANICAL PROPERTIES; NANOCOMPOSITES; POLYMERS; SOL-GEL PROCESS; SOL-GELS; SOLS; SURFACES;

SILICA;

EID: 77950943595     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2010.02.004     Document Type: Article

References (33)

1. Hench L.L., Splinter R.J., Allen W.C., and Greenlee T.K. Bonding mechanisms at the interface of ceramic prosthetic materials. J Biomed Mater Res Symp 2 (1972) 117-141
2. Li R., Clark A.E., and Hench L.L. An investigation of bioactive glass powders by sol-gel processing. J Appl Biomat 2 (1991) 231-239
3. Kokubo T. Bioactive glass ceramics: properties and applications. Biomaterials 12 (1991) 155-163
4. 5 glasses in a simulated body fluid. J Non-Cryst Solids 143 (1992) 84-92
5. Zhong J., and Greenspan D.C. Processing and properties of sol-gel bioactive glasses. J Biomed Mater Res Appl Biomater 53 (2000) 694-701
6. Salinas A.J., Vallet-Regi M., and Izquierdo-Barba I. Biomimetic apatite deposition on calcium silicate gel glasses. J Sol-Gel Sci Tech 21 (2001) 13-25
7. Cerruti M., and Morterra C. Carbonate formation on bioactive glasses. Langmuir 20 (2004) 6382-6388
8. 9. J Mater Sci Mater Med 15 (2004) 1285-1289
9. Kokubo T. Design of bioactive bone substitutes based on biomineralization process. Mater Sci Eng C 25 (2005) 97-104
10. Huang W., Day D.D., Kittiratanapiboon K., and Rahaman M.N. Kinetics and mechanisms of the conversion of silicate (45S5), borate, and borosilicate glasses to hydroxyapatite in dilute phosphate solutions. J Mater Sci Mater Med 17 (2006) 583-596
11. Hench L.L. The story of Bioglass®. J Mater Sci Mater Med 17 (2006) 967-978
12. Ben-Nissan B., and Ylänen H.O. Bioactive glasses and glass ceramics. In: Akay M. (Ed). Wiley enciclopedia of biomedical engineering (2006), John Wiley & Sons, New Jersey 354-366
13. Kokubo T., and Takadama H. How useful is SBF in predicting in vivo bone bioactivity?. Biomaterials 27 (2006) 2907-2915
14. Kim H.M., Himeno T., Kokubo T., and Nakamura T. Process and kinetics of bonelike apatite formation on sintered hydroxyapatite in a simulated body fluid. Biomaterials 26 (2005) 4366-4373
15. 2 nanohybrids for mineralized tissue regeneration. Eur Polym J, submitted for publication [EUROPOL D 0901511].
16. In: Neumann A.W., and Spelt J.K. (Eds). Applied surface thermodynamics. surfactant science series vol. 63 (1993), Marcel Dekker, New York
17. Owens D.K., and Wendt R.C. Estimation of surface free energy of polymers. J Appl Polym Sci 13 (1969) 1741
18. Busscher H.J., Vanpelt A.W.J., Deboer P., Dejong H.P., and Arends J. The effect of surface roughening of polymers on measured contact angles of liquids. Colloids Surf 9 (1984) 319-331
19. Birdi K.S. Surface tension of polymers. In: Yildrim Erbil H. (Ed). CRC Handbook of surface and colloid chemistry (1997), CRC Press, Boca Raton 292
20. Privalko V.P., Lipatov Y.S., and Kercha Y.Y. Calorimetric study of the phase boundary effect on oligo-ethylene glycol adipate (OEGA) properties. Polym Sci USSR 12 (1970) 1520-1529
21. Lipatov Y.S., and Privalko V.P. Glass transition in filled polymer systems. Polym Sci USSR 14 (1972) 1843-1848
22. Hajji P., David L., Gerard J.F., Pascault J.P., and Vigier G. Synthesis, structure and morphology of polymer-silica hybrid nanocomposites based on hydroxyethyl methacrylate. J Polym Sci Part B Polym Phys 37 (1999) 3172-3187
23. Rodríguez Hernández J.C., Monleón Pradas M., and Gómez Ribelles J.L. Properties of poly(2-hydroxyethyl acrylate)-silica nanocomposites obtained by the sol-gel process. J Non-Cryst Solids 354 (2008) 1900-1908
24. In: Van Krevelen D.W. (Ed). Properties of polymers (1997), Elsevier, New York 238
25. Olmedilla M.P., García-Giralt N., Pradas M.M., Ruiz P.B., Ribelles J.L.G., Palou E.C., et al. Response of human chondrocytes to a non-uniform distribution of hydrophilic domains on poly(ethyl acrylate-co-hydroxyethyl methacrylate) copolymers. Biomaterials 27 7 (2006) 1012-1033
26. Oliveira A.L., Malafaya P.B., and Reis R.L. Sodium silicate gel as a precursor for the in vitro nucleation and growth of a bone-like apatite coating in compact and porous polymeric structures. Biomaterials 24 (2003) 2575-2584
27. Oyane A., Uchida M., Choong C., Triffitt J., Jones J., and Ito A. Simple surface modification of poly(ε-caprolactone) for apatite deposition from simulated body fluid. Biomaterials 26 (2005) 2407-2413
28. Rhee S.H. Effect of molecular weight of poly(e-caprolactone) on interpenetrating network structure, apatite-forming ability, and degradability of poly(ε-caprolactone)/silica nano-hybrid materials. Biomaterials 24 (2003) 1721-1727
29. Ward I.M., and Hadley D.W. An introduction to the mechanical properties of solid polymers (1993), Wiley, England
30. Costa R.O.R., and Vasconcelos W.L. Structural modification of poly(2-hydroxyethyl methacrylate)-silica hybrids utilizing 3-methacryloxypropyltrimethoxysilane. J Non-Cryst Solids 304 (2002) 84-91
31. Craig R.G., and Peyton F.A. Elastic and mechanical properties of human dentin. J Dent Res 37 4 (1958) 710-718
32. Motomatsu M., Takahashi T., Nie H.Y., Mizutani W., and Tokumoto H. Microstructure study of acrylic polymer-silica nanocomposite surface by scanning force microscopy. Polymer 38 (1997) 177-182
33. Huang S.L., Chin W.K., and Yang W.P. Structural characteristics and properties of silica/poly(2-hydroxyethyl methacrylate) (PHEMA) nanocomposites prepared by mixing colloidal silica or tetraethyloxysilane (TEOS) with PHEMA. Polymer 46 (2005) 1865-1877