Synthetic design of heterometallic cluster compounds with site-selective and stepwise substitution of bridging carboxylates

Chemistry - A European Journal

Volumn 16, Issue 15, 2010, Pages 4438-4441

  Ikegami, Atsushi ^a   Abe, Masaaki ^a   Inatomi, Atsushi ^a   Hisaeda, Yoshio ^a  

^a KYUSHU UNIVERSITY   (Japan)

Author keywords

Carboxylates; Cluster compounds; Coordination chemistry; Ruthenium; Substitution reactions

Indexed keywords

CLUSTER COMPOUNDS; COORDINATION CHEMISTRY; HETEROMETALLIC CLUSTERS; HETEROMETALLICS; METAL CENTERS; OXO-CENTERED; SITE SELECTIVE; SYNTHETIC DESIGN;

CARBOXYLATION; EXCITONS; METALLIC COMPOUNDS; RUTHENIUM; SUBSTITUTION REACTIONS;

COORDINATION REACTIONS;

CARBOXYLIC ACID; ORGANOMETALLIC COMPOUND; PYRIDINE DERIVATIVE; RUTHENIUM;

ARTICLE; CARBOXYLATES; CHEMICAL STRUCTURE; CHEMISTRY; CLUSTER COMPOUNDS; CONFORMATION; COORDINATION CHEMISTRY; SUBSTITUTION REACTIONS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

CARBOXYLATES; CLUSTER COMPOUNDS; COORDINATION CHEMISTRY; RUTHENIUM; SUBSTITUTION REACTIONS;

CARBOXYLIC ACIDS; CRYSTALLOGRAPHY, X-RAY; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; PYRIDINES; RUTHENIUM;

EID: 77950841015     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201000387     Document Type: Article

References (45)

1. a) A. Volbeda, E. Garcin, C. Piras, A. L. de Lacey, V. M. Fernandez, E. C. Hatchikian. M. Frey, J. C. Fontecilla-Camps. J. Am. Chem. Soc. 1996, 118, 12989-12996:
2. b) J.C. Fontecilla-Camps. P. Amara, C. Cavazza, Y. Nicolet. A. Volbeda, Nature 2009, 460. 814-822;
3. c) D. J. Evans, C. J. Pickett, Chem. Soc. Rev. 2003, 32, 268-275:
4. d) B. E. Barton, C. M. Whaley, T. B. Rauchfuss, D. L. Gray, J. Am. Chem. Soc. 2009, 131, 6942-6943:
5. e) C. Tard, C. J. Pickett, Chem. Rev. 2009, 109, 2245-2274;
6. f) S. E. McGlynn, D. W. Mulder, E. Spepard, J. B. Broderick, J. W. Peters, J. Chem. Soc. Dalton Trans. 2009, 4274-4285
7. a) R. D. Cannon, R. P. White, Prog. Inorg. Chem. 1988, 36, 195-298
8. b) J. A. Stride, S. K. Bollen, N. Chai Sa-Ard, G. J. Kearley, U. A. Jayasooriya, R. D. Cannon, J. Am. Chem. Soc. 1993, 115, 7778-7782
9. c) M. Abe, Y. Sasaki, Y. Yamada, K. Tsukahara, S. Yano, T. Yamaguchi, M. Tominaga, I. Taniguchi, T. lto. lnorg. Chem. 1996, 35, 6724-6734
10. d) A. B. Blake, E. Sinn, A. Yavari, K. S. Murray, B. Moubaraki, J. Chem. Soc. Dalton Trans. 1998. 45-49
11. e) B. Singh, J. R. Long, F. F. de Biani, D. Gatteschi, P. Stavropoulos, J. Am. Chem. Soc. 1997, 119, 7030-7047
12. f) R. D. Adams, B. Captain, Angew. Chem. 2008, 120, 258-263
13. Angew. Chem. Int. Ed. 2008, 47, 252-257
14. G. Novitchi, F. Riblet, R. Scopelliti, L. Helm, A. Gulea, A. E. Merbach, lnorg. Chem. 2008, 47, 10587-10599
15. a) K. Nakata, A. Nagasawa, N. Soyama, Y. Sasaki. T. lto, lnorg. Chem. 1991. 30, 1575-1579
16. b) Y. Sasaki, A. Tokiwa, T. lto, J. Am. Chem. Soc. 1987. 109, 6341-6347
17. c) Y. Sasaki, A. Nagasawa, A. Tokiwa-Yamamoto. T. lto. lnorg. Chim. Acta 1993, 212, 175-182
18. A. Ohto,Y. Sasaki,T. lto, lnorg. Chem. 1994, 33, 1245-1246
19. M. Abe, M. Tanaka, K. Umakoshi, Y. Sasaki, lnorg. Chem. 1999, 38. 4146-4148
20. a) Y. Sasaki, M. Suzuki, A. Nagasawa, A. Tokiwa, M. Ebihara, T. Yamaguchi, C. Kabuto, T. Ochi, T. lto, lnorg. Chem. 1991, 30, 4903-4908
21. b) M. Abe, A. Mitani, A. Ohsawa, M. Herai, M. Tanaka, Y. Sasaki, lnorg. Chim. Acta 2002, 331, 158-167
22. M. Tanaka, N. Kariya, M. Abe, Y. Sasaki, Bull. Chem. Soc. Jpn. 2007, 80, 192-194
23. See the Supporting Information for details.
24. 2: = 0.l747, GOF= 1.124 [l>2σ(/)]. For more details, see the Supporting Information. CCDC-754952 contains the supplementary crystallography data for this paper. These data can be obtained free of charge from The Cambridge Crystallography Data Centre via www.ccdc.cam.ac.uk/data- request/cif.
25. T. Yamaguchi, Y. Sasaki, A. Nagasawa, T. lto. N. Koga. K. Morokuma, lnorg. Chem. 1989, 28, 4311-4312
26. a) M. Ohashi, A. Yagyu, Q. Xu, K. Mashima, Chem. Lett. 2006, 35, 954-955
27. b)M. Ohashi, A. Yagyu, T. Yamagala, K. Mashima, Chem. Commun. 2007, 3103-3105
28. A. lnatomi, M. Abe, Y. Hisaeda, Eur. J. lnorg. Chem. 2009, 4830-4836
29. a) N. Prokopuk, D. F. Shriver, lnorg. Chem. 1997, 36, 5609-5613
30. b) J. H. K. Yip, J. Wu, K.-Y. Wong, K. P. Ho, C. S.-N. Pun, J. J. Vittal, Organometaltics 2002, 21, 5292-5300
31. c) M. W. Cooke. T. S. Cameron, K. N. Robertson, J. C. Swarts, M. A. S. Aquino. Organometaltics 2002, 21, 5962-5971
32. d) Q.-H. Wei, L.-X. Zhang, L.-X. Shi, Z.-N. Chen. lnorg. Chem. Commun. 2004, 7, 286-288
33. e) G.-L. Zheng, J.- F. Ma, Z.-M. Su, L.-K. Yan, J. Yang, Y.-Y. Li. J.-F. Liu. Angew. Chem. 2004, 116, 2463-2465
34. Angew. Chem. Int. Ed. 2004, 43, 2409-2411
35. f) A. Albinali, F.F. deBiani, P. Leoni, L. Marchelti, M. Pasquali, S. Rizzato, P. Zanello, Angew. Chem. 2005, 117, 5847-5851
36. Angew. Chem. Int. Ed. 2005, 44, 5701-5705
37. a) J. Jiao, G. J. Long, L. Rebbouh, F. Grandjean, A. M. Beatty, T. P. Fehlner, J. Am. Chem. Soc. 2005, 127, 17819-17831
38. b) J. Jiao, G. J. Long, F. Grandjean, A. M. Beatty, T. P. Fehlner, J. Am. Chem. Soc. 2003, 125, 7522-7523
39. 3OH was required to prepare the solution for the electrochemical measurements.
40. 2, was not observed for 5 and 6 in the potential region studied and may be shifted beyond the potential window due to the highly positive charge (+5) of the electrochemically generated species.
41. a) D. E. Richardson, H. Taube, Coord. Chem. Rev. 1984, 60, 107-129
42. b) Y. Sasaki, M. Abe, Chem. Rec. 2004, 4, 279-290.
43. V. Mereacre, M. Nakano, J. Gmez-Segura, I. Imaz, C. Sporer, K. Wurst, J. Veciana, C. Turta, D. Ruiz-Molina, P. Jaitner. lnorg. Chem. 2006, 45, 10443-10445
44. For example, see: M. W. Cooke, G. S. Hanan, F. Loiseau, S. Campagna. M. Watanabe, Y. Tanaka, Angew. Chem. 2005, 117, 4959-4962
45. Angew. Chem. Int. Ed. 2005, 44, 4881-4884