Organization of molybdenum oxide nanohybrids by intercalation of aminohydroxy ligands into layered molybdic acid: Efficient catalysts in oxidation of alcohols

Current Nanoscience

Volumn 6, Issue 1, 2010, Pages 82-88

  Afsharpour, M ^a   Mahjoub, A R ^a   Amini, M M ^b   Khodadadi, A A ^c  

^a TARBIAT MODARES UNIVERSITY   (Iran)

^b Shahid Beheshti ^*  (Iran)

^c UNIVERSITY OF TEHRAN   (Iran)

Author keywords

Alcohol; Hybrid; Intercalation; Molybdenum oxide; Oxidation

Indexed keywords

ANALYSIS METHOD; BOND STRENGTH; BONDING NATURE; CALCINED MATERIALS; CATALYTIC ACTIVITY; CATALYTIC PERFORMANCE; CATALYTIC REACTIONS; DIETHYLENETRIAMINE; DIFFERENT STRUCTURE; EFFICIENT CATALYSTS; HYBRID; INORGANIC COMPONENTS; INORGANIC LAYERS; MOLYBDIC ACID; NANO-PLATELETS; NANOHYBRIDS; ORGANIC GROUP; ORGANIC MOLECULES; ORGANIC-INORGANIC HYBRID MATERIALS; OXIDATION OF ALCOHOLS; SURFACE AREA;

CALCINATION; CATALYSIS; CATALYST ACTIVITY; ETHANOL; HYBRID MATERIALS; LIGANDS; MOLYBDENUM; OXIDATION;

MOLYBDENUM OXIDE;

2 (2 AMINOETHOXY)ETHANOL; 2 (2 AMINOETHYLAMINO)ETHANOL; ALCOHOL DERIVATIVE; AMINE; DIETHYLENETRIAMINE; INORGANIC COMPOUND; MOLYBDENUM; MOLYBDIC ACID; ORGANIC COMPOUND; UNCLASSIFIED DRUG;

ALCOHOL OXIDATION; AMINOHYDROXYLATION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; CHEMICAL STRUCTURE; HYBRID; NANOTECHNOLOGY; PRIORITY JOURNAL; REACTION ANALYSIS;

EID: 77950438836     PISSN: 15734137     EISSN: None     Source Type: Journal    
DOI: 10.2174/157341310790226261     Document Type: Article

References (27)

1. 3(4,4 ′-bipyridyl)(0.5). Chem. Mater., 2003, 15(2), 433-442.
2. 3 nanostructures and their optical properties. J. Phys. Condens. Matter., 2003, 15(35), L547-L552.
3. Taurino, A. M.; Forleo, A.; Francioso, L.; Siciliano, P.; Stalder, M.; Nesper, R. Synthesis, electrical characterization, and gas sensing properties of molybdenum oxide nanorods. Appl. Phys. Lett., 2006, 88(15), 152111.
4. Takenaka, S.; Tanaka, T.; Funabiki, T.; Yshida, S. Structures of molybdenum species in silica-supported molybdenum oxide and alkali-ion-modified silica-supported molybdenum oxide. J. Phys. Chem. B, 1998, 102(16), 2960-2969.
5. 3. J. Mater. Chem., 1994, 4(4), 551-555.
6. Oyama, S. T.; Zhang, W. In situ laser Raman studies of intermediates in the catalytic oxidation of ethanol over supported molybdenum oxide. J. Am. Chem. Soc., 1996, 118(25), 7173-7177.
7. Zhang, W. M.; Desikan, A.; Oyama, S. T. Effect of support in ethanol oxidation on molybdenum oxide. J. Phys. Chem., 1995, 99(39), 14468-14476.
8. Takenaka, S.; Tanaka, T.; Funabiki, T. Effect of alkali-metal ion addition to silica-supported molybdenum oxide on photocatalysis - Photooxidation of propane and propene, and photo-assisted metathesis of propene. J. Chem. Soc. Farad. Trans., 1998, 94(5), 695-700.
9. Oyama, S. T.; Radhakrishnan, S.; Seman, M.; Kondo, J. N.; Domen, K.; Asakura, K. Control of reactivity in C-H bond breaking reactions on oxide catalysts: Methanol oxidation on supported molybdenum oxide. J. Phys. Chem. B, 2003, 107(8), 1845-1852.
10. 3. Mat. Sci. Eng. B, 2007, 138(1), 55-59.
11. 3 nanocomposite as a result of direct polymer intercalation. J. Mater. Chem., 2002, 12(5), 1446-1449.
12. Zapf, P. J.; Laduca, R. L.; Rarig, R. S.; Johnson, K. M.; Zubieta, J. A two-dimensional network constructed via hydrogen-bonded cross-linkages of molybdenum oxide chains. Inorg. Chem., 1998, 37(13), 3411-3414.
13. 3 intercalation compounds with nicotinamide and hexamethylenetetramine. Mater. Chem. Phys., 2005, 90(2-3), 302-309.
14. An Y.X.; Koh, L.L. Investigations into the engineering of inorganic/Organic solids: hydrothermal synthesis and structure characterization of one-dimensional molybdenum oxide polymers. Chem. Mater., 1996, 8(4), 814-818.
15. 3-pyrazine hybrids. Int. J. Inorg. Mater., 2001, 3(4-5), 303-307.
16. 9(2,2′-bipy)(2)]. Chem. Mater., 1997, 9(9), 2019-2024.
17. 5OH]. Inorg. Chem. Commun., 2007, 10(1), 23-26.
18. Ung, V. A.; Thompson, A. M. W. C.; Bardwell, D. A.; Gaheschi, D.; Jeffery, J.C.; McCleverty, J.A.; Totti, F.; Ward, M.D. Roles of bridging ligand topology and conformation in controlling exchange interactions between paramagnetic molybdenum fragments in dinuclear and trinuclear complexes. Inorg. Chem., 1997, 36(16), 3447-3454.
19. Xu, Y.; Lu, J. Hydrothermal assembly and structural characterization of two low-dimensional molybdenum oxide/2,2 ′-dipyridylamine hybrid materials. Inorg. Chim. Acta, 1999, 295(2), 222-228.
20. Yan, B.; Xu, Y.; Goh, N. K.; Chia, L. S. Hydrothermal synthesis and crystal structures of two novel hybrid open-frameworks and a two-dimensional network based on tungsten(VI) oxides. Chem. Commun., 2000, 2169-2170.
21. Hagerman, P. J.; Laduca, R. L.; Koo, H. J.; Rarig, R.; Haushalter, R. C.; Whangbo, M. H.; Zubieta, J. Ligand influences on the structures of molybdenum oxide networks. Inorg. Chem., 2000, 39(19), 4311-4317.
22. Niederberger, M.; Krumeich, F.; Muhr, H. J.; Muller, M.; Nesper, R. Synthesis and characterization of novel nanoscopic molybdenum oxide fibers. J. Mater. Chem., 2001, 11(7), 1941-1945.
23. Schukoor, M. I.; Therese, H. A.; Gorgishvili, L.; Glasser, G.; Kolb, U.; Tremel, W. From layered molybdic acid to lower-dimensional nanostructures by intercalation of amines under ambient conditions. Chem. Mater., 2006, 18(8), 2144-2151.
24. 3(4,4 ′-bipyridyl)(0. 5). J. Phys. Chem. B, 2003, 107(12), 2619-2622.
25. 3. J. Phys. Chem. B, 2001, 105(30), 7178-7181.
26. 2S/H-2 and O-2/N-2. Chem. Mater., 2002, 14(4), 1788-1796.
27. Dong, C. PowderX: Windows-95-based program for powder X-ray diffraction data processing. J. Appl. Crystalloger., 1999, 32(4), 838-839.