Mixed matrix blend membranes of poly(vinyl alcohol)-poly(vinyl pyrrolidone) loaded with phosphomolybdic acid used in pervaporation dehydration of ethanol

Journal of Membrane Science

Volumn 354, Issue 1-2, 2010, Pages 150-161

  Magalad, Veeresh T ^a   Gokavi, Gavisiddappa S ^a   Raju, K V S N ^b   Aminabhavi, Tejraj M ^a  

^a SHIVAJI UNIVERSITY   (India)

^b INDIAN INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

Author keywords

Ethanol water mixture; Pervaporation; Phosphomolybdic acid; PVA PVP blend

Indexed keywords

ARRHENIUS RELATIONSHIP; AZEOTROPIC MIXTURE; BLEND MEMBRANES; DYNAMIC MECHANICAL TESTING; ETHANOL DEHYDRATION; ETHANOL WATER MIXTURES; ETHANOL-WATER MIXTURE; FEED WATER; FLORY-HUGGINS THEORY; FTIR; HEAT OF SORPTION; LANGMUIR MODE; MIXED MATRIX; PERMEABILITY RATIO; PERVAPORATION DEHYDRATION; PHOSPHOMOLYBDIC ACID; POLY(VINYL PYRROLIDONE); PV PERFORMANCE; SEM; THREE-COMPONENT SYSTEM; TWO-COMPONENT; XRD;

ACIDS; ANGLE MEASUREMENT; CONTACT ANGLE; DEHYDRATION; DEWATERING; DYNAMIC MECHANICAL ANALYSIS; ETHANOL; EVAPORATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; MECHANICAL TESTING; MIXTURES; PERVAPORATION; PNEUMATIC CONTROL EQUIPMENT; SCANNING ELECTRON MICROSCOPY; SORPTION; SULFUR COMPOUNDS; X RAY DIFFRACTION;

MEMBRANES;

ALCOHOL; MOLYBDIC ACID; PHOSPHOMOLYBDIC ACID; POLYVINYL ALCOHOL; POVIDONE; UNCLASSIFIED DRUG;

ARTICLE; CONTACT ANGLE; CONTROLLED STUDY; DIFFUSION; ENANTIOSELECTIVITY; INFRARED SPECTROSCOPY; LOADING TEST; MEMBRANE BIOLOGY; MEMBRANE FORMATION; MEMBRANE PERMEABILITY; MEMBRANE STRUCTURE; MOLECULAR INTERACTION; PERVAPORATION; PRIORITY JOURNAL; SCANNING ELECTRON MICROSCOPY; TEMPERATURE DEPENDENCE; THERMODYNAMICS; THERMOSTABILITY; X RAY DIFFRACTION;

EID: 77950370387     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2010.02.055     Document Type: Article

References (52)

1. Amnuaypanich S., and Kongchana N. Natural rubber/polyacrylic acid semi-interpenetrating polymer network membranes for the pervaporation of water-ethanol mixtures. J. Appl. Polym. Sci. 114 (2009) 3509
2. Kalyani S., Smitha B., Sridhar S., and Krishnaiah A. Pervaporation separation of ethanol-water mixtures through sodium alginate membranes. Desalination 229 (2008) 68
3. Aminabhavi T.M., Khinnavar R.S., Harogoppad S.B., Aithal U.S., Nguyen Q.T., and Hansen K.C. Pervaporation separation of organic-aqueous and organic-organic binary mixtures. J. Macromol. Sci. Rev. Macromol. Chem. Phys. C 34 (1994) 139
4. Bhat S.D., and Aminabhavi T.M. Pervaporation separation using sodium alginate and its modified membranes-a review. Sep. Purif. Rev. 36 (2007) 203
5. Huang R.Y.M. Pervaporation Membrane Separation Processes (1991), Elsevier Science Publishers, Amsterdam, Netherlands
6. 4-5) molecular sieve-loaded novel sodium alginate composite membranes for pervaporation dehydration of aqueous-organic mixtures near their azeotropic compositions. J. Membr. Sci. 282 (2006) 473
7. Bhat S.D., and Aminabhavi T.M. Zeolite K-LTL-loaded sodium alginate mixed matrix membranes for pervaporation dehydration of aqueous-organic mixtures. J. Membr. Sci. 306 (2007) 173
8. Chen J.H., Liu Q.L., Zhang X.H., and Zhang Q.G. Pervaporation and characterization of chitosan membranes cross-linked by 3-aminopropyltriethoxysilane. J. Membr. Sci. 292 (2007) 125
9. Zhang X.H., Liu Q.L., Xiong Y., Zhu A.M., Chen Y., and Zhang Q.G. Pervaporation dehydration of ethyl acetate/ethanol/water azeotrope using chitosan/poly(vinyl pyrrolidone) blend membranes. J. Membr. Sci. 327 (2009) 274
10. Ma Y., Wang J., and Tsuru T. Pervaporation of water/ethanol mixtures through microporous silica membranes. Sep. Purif. Tecnol. 66 (2009) 479
11. Zheng H., Du Y., Yu J., Huang R., and Zang L. Preparation and characterization of chitosan/poly(vinyl alcohol) blend fibers. J. Appl. Polym. Sci. 80 (2001) 2558
12. Naidu B.V.K., Sairam M., Raju K.S.V.N., and Aminabhavi T.M. Pervaporation of water + IPA mixture using novel nanocomposite membranes of poly(vinyl alcohol) and polyaniline. J. Membr. Sci. 260 (2005) 131
13. Aminabhavi T.M., and Naik H.G. Synthesis of graft copolymeric membranes of poly(vinyl alcohol) and polyacrylamide for the pervaporation separation of water/acetic acid mixtures. J. Appl. Polym. Sci. 83 (2002) 244
14. Kurkuri M.D., Toti U.S., and Aminabhavi T.M. Synthesis and characterization of blend membranes of sodium alginate and poly(vinyl alcohol) for pervaporation separation of water-isopropanol mixtures. J. Appl. Polym. Sci. 86 (2002) 3642
15. Aminabhavi T.M., and Toti U.S. Pervaporation separation of water-acetic acid mixtures using polymer membranes. Des. Monomers Polym. 6 (2003) 211
16. Naidu B.V.K., Bhat S.D., Wali A.C., Sawant D.P., Mallikarjuna N.N., Halligudi S.B., and Aminabhavi T.M. Comparative study on the pervaporation separation of water + acetonitrile mixtures using zeolite-filled sodium alginate and poly-(vinyl alcohol)-polyaniline IPN membranes. J. Appl. Polym. Sci. 96 (2004) 1968
17. Adoor S.G., Prathab B., Manjeshwar L.S., and Aminabhavi T.M. Mixed matrix membranes of sodium alginate and poly(vinyl alcohol) for pervaporation dehydration of isopropanol at different temperatures. Polymer 48 (2007) 5417
18. Lu J., Nguyen Q.T., Zhou L., Xu B., and Ping Z. Study of the role of water in the transport of water and THF through hydrophilic membranes by pervaporation. J. Membr. Sci. 226 (2003) 135
19. Ping Z.H., Nguyen Q.T., and Neel J. Investigation of poly(vinyl alcohol) poly(n-vinyl-2-pyrrolidone) blends. 3. Permeation properties of polymer blend membranes. Macromol. Chem. Phys. 195 (1994) 2107
20. Mahajan R., Burns R., Schaeffer M., and Koros W.J. Challenges in forming successful mixed matrix membranes with rigid polymeric materials. J. Appl. Polym. Sci. 86 (2002) 881
21. Huang Z., Shi Y., Wen R., Guo Y., Su J., and Matsuura T. Multilayer poly(vinyl alcohol)-zeolite 4A composite membranes for ethanol dehydration by means of pervaporation. Sep. Purif. Technol. 51 (2006) 126
22. Huang Z., Guan H., Tan W., Qiao X., and Kulprathipanja S. Pervaporation study of aqueous ethanol solution through zeolite-incorporated multilayer poly(vinyl alcohol) membranes: effect of zeolites. J. Membr. Sci. 276 (2006) 260
23. Moore T.T., and Koros W.J. Non-ideal effects in organic-inorganic materials for gas separation membranes. J. Mol. Struct. 739 (2005) 87
24. 40 blended polysulfone film in the oxidation of ethanol to acetaldehyde. J. Catal. 144 (1993) 348
25. Lee J.K., Song I.K., Lee W.Y.J., and Kim J. Modification of 12-molybdophosphoric acid catalyst by blending with polysulfone and its catalytic activity for 2-propanol conversion reaction. J. Mol. Catal. A 104 (1996) 311
26. Wijmans J.G., and Baker R.W. The solution-diffusion model: a review. J. Membr. Sci. 107 (1995) 1
27. Guo W.F., Chung T.S., Matsuura T., Wang R., and Liu Y. Pervaporation study of water and tert-butanol mixtures. J. Appl. Polym. Sci. 91 (2004) 4082
28. Holmes M.J., and Winkle M.V. Prediction of ternary vapor-liquid equilibria from binary data. Ind. Eng. Chem. 62 (1970) 21
29. Baker R.W., Wijmans J.G., and Huang Y. Permeability, permeance and selectivity: a preferred way of reporting pervaporation performance data. J. Membr. Sci. 348 (2010) 346
30. Naidu B.V.K., and Aminabhavi T.M. Pervaporation separation of water/2-propanol mixtures by use of the blend membranes of sodium alginate and hydroxyethyl cellulose: roles of permeate-membrane interactions, zeolite filling, and membrane swelling. Ind. Eng. Chem. Res. 44 (2005) 7481
31. Flory P.J. Principles of Polymer Chemistry (1953), Cornell University Press, Ithaca, New York
32. Aminabhavi T.M., and Munk P. Preferential adsorption onto polystyrene in mixed solvent systems. Macromolecules 12 (1979) 607
33. Mulder M.H.V., and Smolders C.A. On the mechanism of separation of ethanol/water mixtures by pervaporation. Part I. Calculations of concentration profiles. J. Membr. Sci. 17 (1984) 289
34. Brandrup J., Immergut E.H., and Grulke E.A. Polymer Hand Book (1999), Wiley/Interscience, New York
35. Aithal U.S., Aminabhavi T.M., and Cassidy P.E. Interactions of organic halides with a polyurethane elastomer. J. Membr. Sci. 50 (1990) 225
36. Aralaguppi M.I., Aminabhavi T.M., Balundgi R.H., and Joshi S.S. Thermodynamic interactions in mixtures of bromoform with hydrocarbons. J. Phys. Chem. 95 (1991) 5299
37. Aminabhavi T.M., and Munk P. Diffusion coefficients of some nonideal liquid mixtures. J. Phys. Chem. 84 (1980) 442
38. DECHEMA Chemistry Data Series by Gmehling, Onken, and Arlt., vol. 1, part 1b, 1977.
39. Lakshminarayana G., and Nogami M. Synthesis and characterization of proton conducting inorganic-organic hybrid nanocomposite membranes based on tetraethoxysilane/trimethylphosphate/3 glycidoxypropyl trimethoxysilane/heteropoly acids. Electrochim. Acta 54 (2009) 4731
40. Chen J.H., Liu Q.L., Zhu A.M., Zhang Q.G., and Fang J. Pervaporation separation of MeOH/DMC mixtures using STA/CS hybrid membranes. J. Membr. Sci. 315 (2008) 74
41. Sunitha K., Ravi Kumar Y.V.L., and Sridhar S. Effect of PVP loading on pervaporation performance of poly(vinyl alcohol) membranes for THF/water mixtures. J. Mater. Sci. 44 (2009) 6280
42. Wang Y., Fan S., Lee K.R., Li C.L., Huang S.H., Tsai H.A., and Lai J.Y. Polyamide/SDS-clay hybrid nanocomposite membrane application to water-ethanol mixture pervaporation separation. J. Membr. Sci. 239 (2004) 219
43. Shanmugam S., Vishwanathan B., and Varadarajan T.K. Esterification by solid catalysts-a comparison. J. Mol. Catal. A 223 (2004) 143
44. Kozhevnikov I.V. Catalysis by heteropoly acids and multicomponent polyoxometalates in liquid-phase reactions. Chem. Rev. 98 (1998) 171
45. Aminabhavi T.M., Patil M.B., Bhat S.D., Halgeri A.B., Vijayalakshmi R.P., and Kumar P. Activated charcoal-loaded composite membranes of sodium alginate in pervaporation separation of water-organic azeotropes. J. Appl. Polym. Sci. 113 (2009) 966
46. Zhang Q.G., Liu Q.L., Jiang Z.Y., Ye L.Y., and Zhang X.H. Effects of annealing on the physico-chemical structure and permeation performance of novel hybrid membranes of poly(vinyl alcohol)/γ-aminopropyl-triethoxysilane. Microporous Mesoporous Mater. 110 (2008) 379
47. D. Bahrens, R. Eckermann (Eds.), Vapor-liquid Equilibrium Data Collection, vol. 1, Part 6C, DECHEMA, 1983.
48. Moon G.Y., Pal R., and Huang R.Y.M. Novel two-ply composite membranes of chitosan and sodium alginate for the pervaporation dehydration of isopropanol and ethanol. J. Membr. Sci. 156 (1999) 17
49. Kanti P., Srigowri K., Madhuri J., Smitha B., and Sridhar S. Dehydration of ethanol through blend membranes of chitosan and sodium alginate by pervaporation. Sep. Purif. Technol. 40 (2004) 259
50. Wang X.P., Shen Z.Q., Zhang Y.F., and Zhang. A novel composite chitosan membrane for the separation of alcohol-water mixtures. J. Membr. Sci. 119 (1996) 191
51. Yeom C.K., Jegal J.G., and Lee K.H. Characterization of relaxation phenomena and permeation behaviors in sodium alginate membrane during pervaporation separation of ethanol-water mixture. J. Appl. Polym. Sci. 62 (1996) 1561
52. Toutianoush A., Krasemann L., and Tieke B. Polyelectrolyte multilayer membranes for pervaporation separation of alcohol/water mixtures. Colloids Surf. A 198 (2002) 881-889