Particle characterization at the Cape Verde atmospheric observatory during the 2007 RHaMBLe intensive

Atmospheric Chemistry and Physics

Volumn 10, Issue 6, 2010, Pages 2709-2721

  Muller K ^a   Lehmann, S ^a   Van Pinxteren, D ^a   Gnauk, T ^a   Niedermeier, N ^a   Wiedensohler, A ^a   Herrmann, H ^a  

^a LEIBNIZ INSTITUTE FOR TROPOSPHERIC RESEARCH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

AEROSOL PROPERTY; AIR MASS; BROMIDE; CHLORIDE; DUST; HALOGEN; MARINE ATMOSPHERE; NITRATE; PARTICLE SIZE; SEA SALT;

CANARY ISLANDS; CAPE VERDE; SPAIN;

EID: 77949864232     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-10-2709-2010     Document Type: Article

References (56)

1. Allan, J. D., Topping, D. O., Good, N., Irwin, M., Flynn, M., Williams, P. I., Coe, H., Baker, A. R., Martino, M., Niedermeier, N., Wiedensohler, A., Lehmann, S., Müller, K., Herrmann, H., and McFiggans, G.: Composition and properties of atmospheric particles in the eastern Atlantic and impacts on gas phase uptake rates, Atmos. Chem. Phys., 9, 9299-9314, 2009, http://www.atmos- chem-phys.net/9/9299/2009/.
2. Allen, A. G., Dick, A. L., and Davison, B. M.: Sources of atmospheric methanesulphonate, non-sea-salt sulphate, nitrate and related species over the temperate South Pacific, Atmos. Environ., 31(2), 191-205, 1997.
3. Andreae, M. O., Berresheim, H., Andreae, T. W., Kritz, M. A., Bates, T. S., and Merrill, J. T.: Vertical-Distribution of Dimethyl-sulfide, Sulfur-Dioxide, Aerosol Ions, and Radon over the Northeast Pacific-Ocean, J. Atmos. Chem., 6(1-2), 149-173, 1988.
4. Ayers, G. P., Ivey, J. P., and Goodman, H. S.: Sulfate and Methane-sulfonate in the maritime aerosol at Cape Grim, Tasmania, J. At-mos. Chem., 4 (1), 173-185, 1986.
5. Ayers, G. P., Gillett, R. W., Cainey, J. M., and Dick, A. L.: Chloride and bromide loss from sea-salt particles in southern ocean air, J. Atmos. Chem., 33, 299-319, 1999.
6. Baboukas, E. D., Kanakidou, M., and Mihalopoulos, N.: Car-boxylic acids in gas and particulate phase above the Atlantic Ocean, J. Geophys. Res.-Atmos., 105(D11), 14459-14471, 2000.
7. Baker, A. R. and Jickells, T. D.: Mineral particle size as a control on aerosol iron solubility, Geophys. Res. Lett., 33, L17608, doi:10.1029/ 2006GL026557, 2006.
8. Barrie, L. A., Li, S.-M., Toom, D. L., Landsberger, S., and Sturges, W.: Lower tropospheric measurements of halogens, nitrates, and sulphur oxides during Polar Sunrise Experiment 1992, J. Geo-phys. Res., 99D, 25453-25467, 1994.
9. Bates, T. S., Calhoun, J. A., and Quinn, P. K.: Variations in the Methanesulfonate to Sulfate Molar Ratio in Submicrometer Marine Aerosol-Particles over the South-Pacific Ocean, J. Geophys. Res., 97 (D9), 9859-9865, 1992.
10. Birmili, W., Stratmann, F., and Wiedensohler, A.: Design of a DMA-based size spectrometer for a large particle size range and stable operation, J. Aer. Sci., 30, 549-553, 1999.
11. Bonnet, S. and Guieu, C.: Dissolution of atmospheric iron in seawater, Geophys. Res. Lett., 31(3), L03303, doi:10.1029/2003GL018423, 2004.
12. Charlson, R. J., Lovelock, J. E., Andreae, M. O., and Warren, S. G.: Oceanic phytoplankton, atmospheric sulphur, cloud albedo and climate, Nature, 326, 655-661, 1987.
13. Chen, Y. and Siefert, R. L.: Seasonal and spatial distribution s and dry deposition fluxes of atmospheric total and labile iron over the tropical and subtropical North Atlantic Ocean, J. Geophys. Res., 109, D09305, doi:10.1029/2003JD003958, 2004. (Pubitemid 38990973)
14. Chiapello, I., Bergametti, G., Gomes, L., Chatenet, B., Dulac, F., Pimenta, J., and Santos Suares, E.: An Additional Low Layer Transport of Sahelian and Saharan Dust over the North-Eastern Tropical Atlantic, Geophys. Res. Lett., 22, 3191-3194, 1995.
15. DeCarlo, P. F., Slowik, J. G., Warsnop, D. R., Davidovits, P., and Jimenez, J. L.: Particle morphology and density characterization by combined mobility and aerodynamic diameter measurements. Part 1: Theory, Aerosol Sci. Technol., 38, 1185-1205, 2004.
16. Duce, R. A., Wasson, J. T., Winchester, J. W., and Burns, E.: Atmospheric iodine, bromine, and chlorine, J. Geophys. Res., 68(13), 3943, 1963.
17. Gabriel, R., von Glasow, R., Sander, R., Andreae, M. O., and Crutzen, P. J.: Bromide content of sea-salt aerosol particles collected over the Indian Ocean during INDOEX 1999, J. Geophys. Res., 107(D19), 8032, doi:10.1029/ 2001JD001133, 2002.
18. Guieu, C., Loÿe-Pilot, M.-D., Ridame, C., and Thomas C.: Chemical characterization of the Saharan dust end-member: Some biogeochemical implications for the western Mediterranean Sea, J. Geophys. Res., 107(D15), 4258, doi:10.1029/2001JD000582, 2002. (Pubitemid 43211878)
19. Hand, J. L., Mahowald, N. M., Chen, Y., Siefert, R. L., Luo, C., Subramaniam, A., and Fung, I.: Estimates of atmospheric-processed soluble iron from observations and a global mineral aerosol model: Biogeochemical implications, J. Geophys.Res., 109(D17), D17205, doi:10.1029/2004JD004574, 2004. (Pubitemid 39547474)
20. Herrmann, H.: Kinetics of aqueous phase reactions relevant for atmospheric chemistry, Chem. Rev., 103, 4691-4716, 2003.
21. Herrmann, H., Brüggemann, E., Franck, U., Gnauk, T., Löschau, G., Müller, K., Plewka, A., and Spindler, G.: A source study of PM in Saxony by size-segregated characterization, J. Atmos. Chem., 55, 103-130, 2006.
22. Hsieh, L. Y., Kuo, S. C., Chen, C. L., and Tsai, Y. I.: Origin of low-molecular-weight dicarboxylic acids and their concentration and size distribution variation in suburban aerosol, Atmos. Environ., 41 (31), 6648-6661, 2007.
23. Hsieh, L. Y., Kuo, S. C., Chen, C. L., and Tsai, Y. I.: Size distributions of nano/micron dicarboxylic acids and inorganic ions in suburban PM episode and non-episodic aerosol, Atmos. Environ., 43(29), 4396-4406, 2009.
24. Johansen, A. M., Siefert, R. L., and Hoffmann, M. R.: Chemical composition of aerosol collected over the tropical North Atlantic Ocean, J. Geophys. Res., 105, 15277-15312, 2000.
25. Keene, W. C., Pszenny, A. A. P., Jacob, D. J., Duce, R. A., Galloway, J. N., Schultz-Tokos, J. J., Sievering, H., and Boatman, J. F.: The geochemical cycling of reactive chlorine through the marine troposphere, Global Biogeochem. Cy., 4, 407-430, 1990.
26. Keene, W. C., Pszenny, A. A. P., Maben, J. R., and Sander, R.: Variation of marine aerosol acidity with particle size, Geophys. Res. Lett., 29(7), 1101, doi:10.1029/2001GL013881, 2002.
27. Keene, W. C., Pszenny, A. A. P., Maben, J. R., Stevenson, E., and Wall, A.: Closure evaluation of size-resolved aerosol pH in the New England coastal atmosphere during summer, J. Geophys. Res., 109, D23307, doi:10.1029/ 2004JD004801, 2004. (Pubitemid 40318572)
28. Keene, W. C., Long, M. S., Pszenny, A. A. P., Sander, R., Maben, J. R., Wall, A. J., O'Halloran, T. L., Kerkweg, A., Fischer, E. V., Schrems, O.: Latitudinal variation in the multiphase chemical processing of inorganic halogens and related species over the eastern North and South Atlantic ocean, Atmos. Chem. Phys., 9, 7361-7385, 2009, http://www.atmos-chem-phys.net/9/7361/ 2009/.
29. Kettle, A. J. and Andreae, M. O.: Flux of dimethylsulfide from the oceans: a comparison of updated data sets and flux models, J. Geophys. Res., 105, 26793-26808, 2000.
30. Kouvarakis, G. and Mihalopoulos, N.: Seasonal variation of dimethylsulfide in the gas phase and of methanesulfonate and non-sea-salt sulfate in the aerosols phase in the Eastern Mediterranean atmosphere, Atmos. Environ., 36 (6), 929-938, 2002.
31. Lafon, S., Rajot, J. L., Alfaro, S. C., and Gaudichet, A.: Quantification of iron oxides in desert aerosol, Atmos. Environ., 38(8), 1211-1218, 2004.
32. Lawler, M. J., Finley, B. D., Keene, W. C., Pszenny, A. A. P., Read, K. A., von Glasow, R., and Saltzmann, E. S.: Pollution-enhanced reactive chlorine chemistry in the eastern tropical Atlantic boundary layer, Geophys. Res. Lett., 36, L08810, doi:10.1029/2008GL036666, 2009.
33. Lee, J. D., McFiggans, G., Allan, J. D., Carpenter, L. J., Jones, C. E., Lewis, A. C., Moller, S. J., Read, K. A., Methven, J., Fuentes, E., Good, N., Irwin, M., Commane, R., Furneuax, K. L., God-dard, A., Ingham, T., Whalley, L. K., Heard, D. E., Mahajan, A., Oetjen, H., Plane, J. M. C., Saiz-Lopez, A., Hollingworth, A., Ball, S. M., Benton, A., Jones, R., Baker, A. R., O'Doherty, S., Young, D., Müller, K., Lehmann, S., Niedermeier, N., Müller, T., Herrmann, H., Wiedensohler, A., Pszenny, A. A. P., Kenne, W. C., Long, M. S., Sander, R., Lawler, M. J., Saltzman, E. S., and Finley, B. D.: Reactive halogens in the marine boundary layer (RHaMBLe): context of the tropical North Atlantic Ocean experiments, Atmos. Chem. Phys., 10, 1031-1055, 2010, http://www.atmos- chem-phys.net/10/1031/2010/.
34. Mahowald, N. M., Baker A. R., Bergametti, G., Brooks, N., Duce, R. A., Jickells, T. D., Kubilay, N., Prospero, J. M., and Tegen, I.: Atmospheric global dust cycle and iron inputs to the ocean, Global Biogeochem. Cy., 19, GB4025, doi:10.1029/2004GB002402, 2005. (Pubitemid 43280688)
35. 4 dicarboxylic acids in the marine aerosols, Geophys. Res. Lett., 30(13), 1672, doi:10.1029/2003GL017451, 2003.
36. Moreno, T., Querol, X., Castillo, S., Alastuey, A., Cuevas, E., Herrmann, L., Mounkaila, M., Elvira, J., and Gibbons, W.: Geochemical variations in aeolian mineral particles from the Sahara-Sahel Dust Corridor, Chemosphere, 65, 261-270, 2006.
37. Müller, C., Iinuma, Y., Karstensen, J., van Pinxteren, D., Lehmann, S., Gnauk, T., and Herrmann, H.: Seasonal variation of aliphatic amines in marine sub-micrometer particles at the Cape Verde islands, Atmos. Chem. Phys., 9, 9587-9597, 2009, http://www.atmos-chem-phys.net/9/9587/2009/.
38. Neusüß, C., Weise, D., Birmili, W., Wex, H., Wiedensohler, A., and Covert, D. S.: Size-segregated chemical, gravimetric and number distribution-derived mass closure of the aerosol in Sagres, Portugal during ACE-2. Tellus (B), 52, 169-184, 2000.
39. Neusüß, C., Gnauk, T., Plewka, A., Herrmann, H., and Quinn, P. K., Carbonaceous aerosol over the Indian Ocean: OC/EC fractions and selected specifications from size-segregated onboard samples, J. Geophys. Res., 107(D19), 8031, doi:10.1029/2001JD000327, 2002.
40. Prospero, J. M. and Carlson, T. N.: Saharan Air Outbreaks over the Tropical North-Atlantic, Pure Appl. Geophys., 119, 677-691, 1981.
41. Read, K. A., Mahajan, A. S., Carpenter, L. J., Evans, M. J., Faria, B. V. E., Heard, D. E., Hopkins, J. R., Lee, J. D., Moller, S. J., Lewis, A. C., Mendes, L., McQuaid, J. B., Oetjen, H., Saiz-Lopez, A., Pilling, M. J., and Plane, J. M. C.: Extensive halogen-mediated ozone destruction over the tropical Atlantic Ocean, Nature, 453, 1232-1235, doi:10.1038/nature07035, 2008.
42. Rijkenberg, M. J. A., Powell, C. F., Dall'Osto, M., Nielsdottir, M. C., Patey, M. D., Hill, P. G., Baker, A. R., Jickells, T. D., Harrison, R. M., and Achterberg, E. P.: Changes in iron speciation following a Saharan dust event in the tropical North Atlantic Ocean, Mar. Chem., 110, 56-67, 2008.
43. Saltzman, E. S., Savoie, D. L., Zika, R. G., and Prospero, J. M.: Methane Sulfonic-Acid in the marine atmosphere, J. Geophys. Res., 88(15), 897-902, 1983.
44. Saltzman, E. S., Savoie, D. L., Prospero, J. M., and Zika, R. G.: Atmospheric Methane Sulfonic-Acid and Non-Sea-Salt Sulfate at Fanning and American Samoa, Geophys. Res. Lett., 12(7), 437-440, 1985.
45. Sander, R., Keene, W. C., Pszenny, A. A. P., Arimoto, R., Ayers, G. P., Baboukas, E., Cainey, J. M., Crutzen, P. J., Duce, R. A., Honninger, G., Huebert, B. J., Maenhaut, W., Mihalopoulos, N., Turekian, V. C., and Van Dingenen, R.: Inorganic bromine in the marine boundary layer: a critical review, Atmos. Chem. Phys., 3, 1301-1336, 2003, http://www.atmos-chem-phys.net/3/1301/ 2003/.
46. Schepanski, K., Tegen, I., and Macke, A.: Saharan dust transport and deposition towards the tropical northern Atlantic, Atmos. Chem. Phys., 9, 1173-1189, 2009, http://www.atmos-chem-phys.net/9/1173/2009/.
47. Schmid, H., Laskus, L., Abraham, H.J., Baltensperger, U., La-vanchy, V., Bizjak, M., Burba, P., Cachier, H., Crow, D., Chow, J., Gnauk, T., Even, A., ten Brink, H. M., Giesen, K. P., Hitzen-berger, R., Hueglin, C., Maenhaut, W., Pio, C., Carvalho, A., Putaud, J. P., Toom-Sauntry, D., and Puxbaum, H.: Results of the "carbon conference" international aerosol carbon round robin test stage I, Atmos. Environ., 35 (12), 2111-2121, 2001.
48. Schroth, A. W., Crusius, J., Sholkowitz, E. R., and Bostick, B. C.: Iron solubility driven by speciation in dust sources to the ocean, Nature Geosci., 2, 337-340, 2009.
49. ten Brink, H. W., Maenhaut, W., Hitzenberger, R., Gnauk, T., Spindler, G., Even, A., Chi, X. G., Bauer, H., Puxbaum, H., Putaud, J. P., Tursic, J., and Berner, A.: INTERCOMP2000: the comparability of methods in use in Europe for measuring the carbon content of aerosol, Atmos. Environ., 38, 6507-6519, 2004.
50. Turpin, B. J., Saxena, P., and Andrews, E.: Measuring and simulating particulate organics in the atmosphere: problems and prospects, Atmos. Environ., 34, 2983-3013, 2000.
51. Vogt, R., Crutzen, P. J., and Sander, R.: A mechanism for halogen release from sea-salt aerosol in the remote marine boundary layer, Nature, 383(6598), 327-330, 1996.
52. von Glasow, R., Sander, R., Bott, A., and Crutzen, P. J.: Modeling halogen chemistry in the marine boundary layer. 1.Cloud-free MBL, J. Geophys. Res., 107, 4341, doi:10.1029/2001JD000942, 2002a. (Pubitemid 43206147)
53. von Glasow, R., Sander, R., Bott, A., Crutzen, P. J.: Modeling halogen chemistry in the marine boundary layer. 2. Interactions with sulphur and cloud-covered MBL, J. Geophys. Res., 107, 4341, doi:10.1029/2001JD000943, 2002b. (Pubitemid 43206141)
54. Wieprecht, W., Acker, K., Müller, K., Spindler, G., Brüggemann, E., Maenhaut, W. Chi, X., Hitzenberger, R., Bauer, H., and ten Brink, H. M.: INTERCOMP2000: Ionic constitution and comparison of filter and impactor, Atmos. Environ., 38, 6477-6486, 2004.
55. Wilson, T. R. S.: Salinity and the major elements of sea water, in: Chemical Oceanography, Vol.1, 2nd Ed., edited by: Riley, J. P. and Skirrow, G., Academic Press, 365-413, 1975.
56. Yang, H. and Yu, J. Z.: Uncertainties in charring correction in the analysis of elemental and organic carbon in atmospheric aerosol particles by thermal/optical methods, Environ Sci. Technol., 36, 5199-5204, 2002.