Redox potential of the Khibiny magmatic system and genesis of abiogenic hydrocarbons in alkaline plutons

Geology of Ore Deposits

Volumn 51, Issue 6, 2009, Pages 425-440

  Ryabchikov, I D ^a   Kogarko, L N ^b  

^a INSTITUTE OF GEOLOGY OF ORE DEPOSITS   (Russian Federation)

^b VERNADSKY INSTITUTE OF GEOCHEMISTRY AND ANALYTICAL CHEMISTRY   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

GRAPHITE; HYDROCARBONS; MAGNETITE; REDOX REACTIONS; SILICATE MINERALS;

ABIOGENIC; CARBONATE ANION; HIGH TEMPERATURE; LOWER TEMPERATURES; MAGMATIC SYSTEMS; PRODUCTS OF REACTION; REDOX CONDITION; REDOX POTENTIALS;

FISCHER-TROPSCH SYNTHESIS;

CARBON DIOXIDE; CHEMICAL ANALYSIS; CRYSTALLIZATION; GRAPHITE; HYDROCARBON; MAGMATISM; PETROGENESIS; PLUTON; REDOX CONDITIONS; REDOX POTENTIAL; TEMPERATURE;

EID: 77949716603     PISSN: 10757015     EISSN: 15556476     Source Type: Journal    
DOI: 10.1134/S1075701509060014     Document Type: Article

References (50)

1. C. Ballhaus, "Redox States of Lithospheric and Asthenospheric Upper Mantle," Contrib. Mineral. Petrol. 114, 341-348 (1993).
2. C. Ballhaus, R. F. Berry, and D. H. Green, "Oxygen Fugacity Controls in the Earth's Upper Mantle," Nature 348, 437-440 (1990).
3. B. Beeskow, P. J. Treloar, A. H. Rankin, et al., "A Reassessment of Models for Hydrocarbon Generation in the Khibiny Nepheline Syenite Complex, Kola Peninsula, Russia," Lithos 91, 1-18 (2006).
4. B. E. Borutsky, Rock-Forming Minerals of High-Alkaline Complexes (Nauka, Moscow, 1988) [in Russian].
5. A. F. Buddington and D. H. Lindsley, "Iron-Titanium Oxide Minerals and Synthetic Equivalents," J. Petrol. 5, 310-357 (1964).
6. D. Canil, "Vanadium Partitioning and the Oxidation State of Archean Komatiite Magmas," Nature 389, 842-845 (1997).
7. D. Canil, "Vanadium Partitioning between Orthopyroxene, Spinel and Silicate Melt and the Redox States of Mantle Source Regions for Primary Magmas," Geochim. Cosmochim. Acta 63, 557-572 (1999).
8. D. Canil, "Vanadium in Peridotites, Mantle Redox and Tectonic Environments: Archean to Present," Earth Planet. Sci. Lett. 195, 75-90 (2002).
9. B. R. Frost and D. H. Lindsley, "Occurrence of Iron-Titanium Oxides in Igneous Rocks: Oxide Minerals: Petrologic and Magnetic Significance," Rev. Mineral. 25, 433-467 (1991).
10. B. R. Frost, D. H. Lindsley, and D. J. Andersen, "Fe-Ti Oxide-Silicate Equilibriums: Assemblages with Fayalitic Olivine," Am. Mineral. 73, 727-740 (1988).
11. M. S. Ghiorso and R. O. Sack, "Fe-Ti Oxide Geothermometry: Thermodynamic Formulation and the Estimation of Intensive Parameters in Silicic Magmas," Contrib. Mineral. Petrol. 108, 485-510 (1991a).
12. M. S. Ghiorso and R. O. Sack, "Thermochemistry of the Oxide Minerals: Oxide Minerals: Petrologic and Magnetic Significance," Rev. Mineral. 25, 221-264 (1991b).
13. D. H. Green, T. J. Falloon, and W. R. Taylor, "Mantle-Derived Magmas: Roles of Variable Source Peridotite and Variable C-O-H Fluid Compositions," in Magmatic Processes: Physicochemical Principles Geochem. Soc. Spec. Publ. 1, 139-154 (1987).
14. R. Halama, T. Vennemann, W. Siebel, and G. Markl, "The Gronnedal-Ika Carbonatite-Syenite Complex, South Greenland: Carbonatite Formation by Liquid Immiscibility," J. Petrol. 46, 191-217 (2005).
15. T. J. B. Holland, "Activities of Components in Omphacitic Solid Solutions. Application of Landau Theory to Mixtures," Contrib. Mineral. Petrol. 105, 446-453 (1990).
16. 2O in the Range 1 Bar to 50 Kbar and 100-1600°C," Contrib. Mineral. Petrol. 109, 265-273 (1991).
17. T. J. B. Holland and R. Powell, "An Internally Consistent Thermodynamic Data Set for Phases of Petrological Interest," J. Metamorphic Geol. 16, 309-343 (1998).
18. S. V. Ikorsky and N. A. Shugurova, "New Data on Age of Gases in Minerals from the Alkaline Rocks of the Khibiny Massif," Geokhimiya 12(6), 943-947 (1974).
19. L. N. Kogarko, Genesis of Peralkaline Magmas (Nauka, Moscow, 1977) [in Russian].
20. L. N. Kogarko, C. Kosztolanyi, and I. D. Ryabchikov, "Geochemistry of Reduced Fluids of Alkaline Magmas," Geokhimiya 24(12), 1688-1695 (1986).
21. E. E. Kostyleva-Labuntsova, B. E. Borutsky, M. N. Sokolova, et al., Mineralogy of the Khibiny Massif. Minerals (Nauka, Moscow, 1978) [in Russian].
22. U. Mann, M. Marks, and G. Markl, "Influence of Oxygen Fugacity on Mineral Compositions in Peralkaline Melts: The Katzenbuckel Volcano, Southwest Germany," Lithos 91, 262-285 (2006).
23. G. Markl, M. Marks, G. Schwinn, and H. Sommer, "Phase Equilibrium Constraints on Intensive Crystallization Parameters of the Ilímaussaq Complex, South Greenland," J. Petrol. 42, 2231-2257 (2001).
24. M. Marks and G. Markl, "Fractionation and Assimilation Processes in the Alkaline Augite Syenite Unit of the Ilímaussaq Intrusion, South Greenland, As Deduced from Phase Equilibriums," J. Petrol. 42, 1947-1969 (2001).
25. M. A. W. Marks, J. Schilling, I. M. Coulson, et al., "The Alkaline-Peralkaline Tamazeght Complex, High Atlas Mountains, Morocco: Mineral Chemistry and Petrological Constraints for Derivation from a Compositionally Heterogeneous Mantle Source," J. Petrol. 49, 1097-1131 (2008).
26. V. A. Nivin, "Gas Concentrations in Minerals with Reference to the Problem of the Genesis of Hydrocarbon Gases in Rocks of the Khibiny and Lovozero Massifs," Geochem. Intern. 40, 883-898 (2002).
27. V. A. Nivin, P. J. Treloar, N. G. Konopleva, and S. V. Ikorsky, "A Review of the Occurrence, Form and Origin of C-Bearing Species in the Khibiny Alkaline Igneous Complex, Kola Peninsula, NW Russia," Lithos 85, 93-112 (2005).
28. H. S. C. O'Neill and V. J. Wall, "The Olivine-Spinel Oxygen Geobarometer, the Nickel Precipitation Curve and the Oxygen Fugacity of the Upper Mantle," J. Petrol. 28, 1169-1192 (1987).
29. E. F. Osborn, "Role of Oxygen Pressure in the Crystallization and Differentiation of Basaltic Magma," Am. J. Sci. 257, 609-647 (1959).
30. A. L. Perchuk and L. Ya. Aranovich, "Thermodynamic Model of the Solid Solution of the Jadeite-Diopside-Hedenbergite," Geokhimiya 29 (4), 539-547 (1991).
31. L. L. Perchuk, K. K. Podlessky, and L. Y. Aranovich, "Themodynamics of Some Framework Silicates and Their Equilibriums: Application to Geothermobarometry," in Progress in Metamorphic and Magmatic Petrology (Univ. Press, Cambridge, 1991), pp. 131-164.
32. I. A. Petersilie, "Carbonaceous Gases and Bitumen of Intrusive Massifs in the Central Part of the Kola Peninsula," Dokl. Akad. Nauk SSSR 122(6), 1086-1089 (1958).
33. I. A. Petersilie and H. Sørensen, "Hydrocarbon Gases and Bituminous Substances in Rocks from the Ilímaussaq Alkaline Intrusion, South Greenland," Lithos 3, 59-76 (1970).
34. J. Potter, A. H. Rankin, and P. J. Treloar, "Abiogenic Fischer-Tropsch Synthesis of Hydrocarbons in Alkaline Igneous Rocks: Fluid Inclusion, Textural and Isotopic Evidence from the Lovozero Complex, N. W. Russia," Lithos 75, 311-330 (2004).
35. D. C. Presnall, "The Join Forsterite-Diopside-Iron Oxide and Its Bearing on the Crystallization of Basaltic and Ultramafic Magmas," Am. J. Sci. 264, 753-809 (1966).
36. I. D. Ryabchikov and L. N. Kogarko, "Redox Equilibriums in Alkaline Lavas from Trindade Island, Brasil," Intern. Geol. Rev. 36, 173-183 (1994).
37. I. D. Ryabchikov, Thermodynamic Analysis of the Behavior of Minor Elements during Crystallization of Silicate Melts (Nauka, Moscow, 1965) [in Russian].
38. I. D. Ryabchikov, A. V. Ukhanov, and T. Ishii, "Redox Equilibriums in the Alkaline Rocks from Upper Mantle of the Yakutian Kimberlite Province," Geokhimiya 23(5), 1110-1123 (1985).
39. I. D. Ryabchikov, I. P. Solovova, L. N. Kogarko, G. P. Brey, Th. Ntaflos, and S. G. Simakin, "Thermodynamic Parameters of Generation of Meimechites and Alkaline Picrites in the Maimecha-Kotui Province: Evidence from Melt Inclusions," Geokhimiya 40(11), 1139-1150 (2002) [Geochem. Int. 40 (11), 1031-1041 (2002)].
40. R. O. Sack and M. S. Ghiorso, "An Internally Consistent Model for the Thermodynamic Properties of Fe-Mg-Titanomagnetite-Aluminate Spinels," Contrib. Mineral. Petrol. 106, 474-505 (1991).
41. S. Salvi and A. Williams-Jones, "Alteration, HFSE Mineralization, and Hydrocarbon Formation in Peralkaline Igneous Systems: Insights from the Strange Lake Pluton, Canada," Lithos 91, 19-34 (2006).
42. K. I. Shmulovich, Carbon Dioxide in High-Temperature Mineral Formation (Nauka, Moscow, 1988) [in Russian].
43. A. V. Sobolev, V. S. Kamenetsky, and N. N. Kononkova, "New Data on Petrology of the Siberian Meimechites," Geokhimiya 29(8), 1084-1095 (1991).
44. V. L. Vinograd, "Thermodynamics of Mixing and Ordering in the Diopside-Jadeite System: I. A CVM Model," Mineral. Magazine 66, 513-536 (2002).
45. D. R. Wones, "Significance of the Assemblage Titanite + Magnetite + Quartz in Granitic Rocks," Am. Mineral. 74, 744-749 (1989).
46. B. J. Wood, L. T. Bryndzya, and K. E. Johnson, "Mantle Oxidation State and Its Relationship to Tectonic Environment and Fluid Speciation," Science 248, 337-345 (1990).
47. D. Xirouchakis and D. H. Lindsley, "Equilibriums among Titanite, Hedenbergite, Fayalite, Quartz, Ilmenite, and Magnetite: Experiments and Internally Consistent Thermodynamic Data for Titanite," Am. Mineral. 83, 712-725 (1998).
48. 4), Ca-Mg-Fe Olivine and Pyroxenes, Fe-Mg-Ti Oxides, and Quartz: Part I. Theory," Am. Mineral. 86, 247-253 (2001a).
49. 4), Ca-Mg-Fe Olivine and Pyroxenes, Fe-Mg-Ti Oxides, and Quartz: Part II. Application," Am. Mineral. 86, 254-264 (2001b).
50. 2O Systems up to 10 GPa and 2573 K," Geochim. Cosmochim. Acta 71, 2036-2055 (2007).