The à - X̃ absorption of vinoxy radical revisited: Normal and Herzberg-Teller bands observed via cavity ringdown spectroscopy

Journal of Chemical Physics

Volumn 132, Issue 11, 2010, Pages

  Thomas, Phillip S ^a   Chhantyal Pun, Rabi ^a   Kline, Neal D ^a   Miller, Terry A ^a  

^a OHIO STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CAVITY RING-DOWN SPECTROSCOPY; ELECTRONIC ABSORPTION SPECTRA; ELECTRONIC STRUCTURE CALCULATIONS; ELECTRONIC TRANSITION; NORMAL BAND; ROOM TEMPERATURE; SYMMETRIC VIBRATIONS; VIBRATIONAL FREQUENCIES; VINOXY RADICALS;

ABSORPTION; ELECTRONIC STRUCTURE; VIBRATION ANALYSIS;

ABSORPTION SPECTROSCOPY;

EID: 77949676059     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3352976     Document Type: Article

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43. c traces of Fig. is the result of a second order effect. This effect arises from quadratic terms which have been neglected in the expansion of Eq. These terms, by symmetry, do not affect transitions involving single excitations of asymmetric normal modes of interest here.