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While somewhat arbitrary, the cut-o. distance of 7.3 Å was calculated as follows: for simplicity, we considered that one quinoline moiety overlaps the second having one vertex situated on top of the half C-C distance of the other, as in Scheme 2a. This arrangement makes the distance between the centroid of one quinoline ring to the far vertex of the second ring 5 times the altitude of the equilateral triangle formed by one C-C bond length and the two corresponding centroid-C distances; the cut-off distance of 7.3 Å was found by applying twice the Pythagorean Theorem. Even in such an extreme case, there would still be an overlap of the π cloud of the quinoline rings, as pictured in Scheme 2, with a calculated Ct2-Ct4 distance of 4.2 Å
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4 distance of 4.2 Å
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