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Volumn 34, Issue 3, 2010, Pages 439-452

8-Quinoline based ligands and their metallic derivatives: A structural and statistical investigation of quinoline π-π stacking interactions

Author keywords

[No Author keywords available]

Indexed keywords

8 SULFONYL(1 PYRAZOLYL)QUINOLINE; DIMER; LIGAND; METAL DERIVATIVE; QUINOLINE; UNCLASSIFIED DRUG;

EID: 77949444300     PISSN: 11440546     EISSN: 13699261     Source Type: Journal    
DOI: 10.1039/b9nj00547a     Document Type: Article
Times cited : (43)

References (128)
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  • 32
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    • While somewhat arbitrary, the cut-o. distance of 7.3 Å was calculated as follows: for simplicity, we considered that one quinoline moiety overlaps the second having one vertex situated on top of the half C-C distance of the other, as in Scheme 2a. This arrangement makes the distance between the centroid of one quinoline ring to the far vertex of the second ring 5 times the altitude of the equilateral triangle formed by one C-C bond length and the two corresponding centroid-C distances; the cut-off distance of 7.3 Å was found by applying twice the Pythagorean Theorem. Even in such an extreme case, there would still be an overlap of the π cloud of the quinoline rings, as pictured in Scheme 2, with a calculated Ct2-Ct4 distance of 4.2 Å
    • 4 distance of 4.2 Å
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.