Sorption behavior of monosodium titanate and amorphous peroxotitanate materials under weakly acidic conditions

Separation Science and Technology

Volumn 45, Issue 1, 2010, Pages 66-72

  Elvington, Mark C ^a   Click, Damon R ^a   Hobbs, David T ^a  

^a SAVANNAH RIVER NATIONAL LABORATORY   (United States)

Author keywords

Cadmium; Chromium; Decontamination factor; Ion exchange; Metals; Surface charge

Indexed keywords

ACIDIC CONDITIONS; BATCH METHODS; CONTACT TIME; DECONTAMINATION FACTOR; DECONTAMINATION FACTORS; MIXED-METALS; MONOSODIUM TITANATE; SCREENING PROCESS; SORBATES; SORPTION CHARACTERISTICS;

ADSORPTION; ALKALI METALS; ALKALINE EARTH METALS; ALKALINITY; CADMIUM; CADMIUM COMPOUNDS; CHARGED PARTICLES; CHROMIUM; DECONTAMINATION; ION EXCHANGE; ION EXCHANGERS; LIGHT METALS; METALLOIDS; METALS;

AMORPHOUS MATERIALS;

ADSORPTION ISOTHERM; ION EXCHANGE; METAL; SURFACE MODIFICATION; SURFACE PROPERTY;

EID: 77949417830     PISSN: 01496395     EISSN: 15205754     Source Type: Journal    
DOI: 10.1080/01496390903401820     Document Type: Article

References (33)

1. Bereket, G.; Aroguz, A.; Ozel, M. (1997) Removal of Pb(II), Cd(II), Cu(II), and Zn(II) from aqueous solutions by adsorption on bentonite. J. Colloid Interface Sci., 187: 338.
2. Mellah, A.; Chegrouche, S. (1997) The removal of zinc from aqueous solutions by natural bentonite. Water Res., 31: 621.
3. Curkovic, L.; Cerjan-Sefanovic, S.; Filipan, T. (1997) Metal ion exchange by natural and modified zeolites. Water Res., 31: 1379.
4. Dyer, A.; Zubair, M. (1998) Ion-exchange in chabazite. Micropor. Mesopor. Mater., 22: 135.
5. Ibrahim, K. (2001) Evaluation of Jordanian faujasite tuff by comparison with other natural and synthetic zeolites. Environ. Geol., 40: 440.
6. Meir, M.; Callejas, R.; Gehr, R.; Cisneros, B.; Alvarez, P. (2001) Heavy metal removal with mexican clinoptilolite: multi-component ionic exchange. Water Res., 35: 373.
7. Lv, L.; Tsoi, G.; Zhao, X. (2004) Uptake equilibria and mechanisms of heavy metal ions on microporous titanosilicate ETS-10. Ind. Eng. Chem. Res., 43: 7900-7906.
8. Chen, C.; Wang, X. (2006) Adsorption of Ni(II) from aqueous solution using oxidized multiwall carbon nanotubes. Ind. Eng. Chem. Res., 45: 9144-9149.
9. Majdan, M.; Pikus, S.; Ternes, M.; Plaska, A.; Staszczuk, P.; Fuks, L.; Skrzypek, H. (2003) Equilibrium study of selected divalent d-electron metals adsorption on A-type zeolite. J. Colloid Interface Sci., 262: 321.
10. Bailey, S.; Olin, T.; Bricka, R.; Adrian, D. (1999) A review of potentially low-cost sorbents for heavy metals. Water Res., 33: 2469-2479.
11. Kesraouiouki, S.; Cheeseman, C.; Perry, R. (1994) Natural zeolite utilisation in pollution control: A review of applications to metals' effluents. J. Chem. Technol. Biotechnol., 59: 121-126.
12. Scheidegger, A.; Strawn, D.; Lamble, G.; Sparks, D. (1998) The kinetics of mixed Ni-Al hydroxide formation on clay and aluminum oxide minerals: time-resolved XAFS study. Geochim. Cosmochim. Acta., 62: 2233-2245.
13. Clearfield, A.; Wang, Z. (2002) Organically pillared microporous zirconium phosphonates. J. Chem. Soc. Dalton. Trans., 2937-2947.
14. Rocha, J.; Lin, Z. (2005) Microporous mixed octahedral-pentahedraltetrahedral framework silicates. Micro-Mesopor. Miner. Phases, 57: 173-201.
15. Moller, K.; Bein, T. (1998) Inclusion chemistry in periodic mesoporous hosts. Chem. Mater., 10: 2950-2963.
16. Dosch, R. (1978) Report RS-8262-2./50318; Sandia National Laboratories: Albuquerque, NM.
17. Kuznicki, S. (1989) Large-pored crystalline titanium molecular sieve zeolites. U.S. Patent 4,853,202.
18. Clearfield, A.; Lehto, J. (1988) Preparation, structure, and ion-exchange properties of Na4Ti9O20·xH2O. J. Solid State Chem., 73: 98-106.
19. Nyman, M.; Hobbs, D. (2006) A family of peroxo-titanate materials tailored for optimal strontium and actinide sorption. Chem. Mater., 18: 6425-6435.
20. Hobbs, D.; Barnes, M.; Pulmano, R.; Marshall, K.; Edwards, T.; Bronikowski, M.; Fink, S. (2005) Strontium and actinide separations from high level nuclear waste solutions using monosodium titanate 1. Simulant testing. Separation Science and Techology, 40: 3093-3111.
21. Peters, T.; Barnes, M.; Hobbs, D.; Walker, D.; Fondeur, F.; Norato, M.; Fink, S. (2006) Strontium and actinide separations from high level nuclear waste solutions using monosodium titanate 2. Actual waste testing. Separation Science and Technology, 41: 2409-2427.
22. Fondeur, F.; Hobbs, D.; Fink, S.; Barnes, M. (2005) Sorption modeling of strontium, plutonium, uranium, and neptunium adsorption on monosodium titanate. Separation Science and Technology, 40: 571-592.
23. Peters, T.B.; Hobbs, D.T.; Fink, S. (2006) Determination of Actinide loadings onto monosodium titanate (MST) under conditions relevant to the Actinide Removal Process Facility. Separation Science and Technology, 41: 2447-2460.
24. Mishra, S.; Srinivasu, N. (1992) Ion exchangers in radioactive waste management - Part II. Radiotracer studies on adsorption of barium ions on sodium titanate. Indian Journal of Technology, 30: 409-12.
25. Mishra, S.; Singh, V.; Tiwari, D. (1998) Inorganic particulates in removal of toxic heavy metal ions. Rapid and efficient removal of Hg(II) and Cr(III) ions from aqueous solutions by sodium titanate. Radiochimica Acta, 81: 227-233.
26. Mishra, S.; Singh, V.; Tiwari, D. (1997) Inorganic particulates in removal of toxic heavy metal ions. Rapid and efficient removal of Zn(II) from aqueous solutions by sodium titanate. Radiochimica Acta, 79: 11-16.
27. Mishra, S.; Singh, V.; Tiwari, D. (1997) Radiotracer technique in adsorption study, XVI: an efficient removal of cadmium ions by sodium titanate from aqueous solutions. Applied Radiation and Isotopes, 48: 435-440.
28. Mishra, S.; Singh, V.; Tiwari, D. (1998) Radiotracer technique in adsorption study: part XVII. Removal behavior of alkali metal (K and Li) titanates for Cd(II). Applied Radiation and Isotopes, 49: 1467-1475.
29. 2+ ions on lithium titanate ion exchanger. Separation Science and Technology, 39: 959-974.
30. Baes, C.; Mesmer, R. (1986) Hydrolysis of Cations; R. E. Krieger, Malabar, FL.
31. 2+ from aqueous solution. J. Colloid Interface Sci., 298: 501-507.
32. 4 nanoparticles. J. Colloid Interface Sci., 301: 402-408.
33. Environmental Protection Agency website: http://www.epa.gov/safewater/contaminants/index.html