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Volumn 49, Issue 6, 2010, Pages 2586-2588

Four-coordinate AsIII-N,S complexes: Synthesis, structure, properties and biological relevance

Author keywords

[No Author keywords available]

Indexed keywords

NITROGEN; ORGANOARSENIC DERIVATIVE; SULFUR;

EID: 77949367469     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9025969     Document Type: Article
Times cited : (17)

References (32)
  • 3
    • 77949385494 scopus 로고    scopus 로고
    • May, accessed Nov 29, 2009
    • (c) World Health Organization. Fact Sheet No. 210, May 2001, http:// www.who.int/mediancentre/factsheets/fs210/en/indes.html (accessed Nov 29, 2009).
    • (2001) Fact Sheet , Issue.210
  • 8
    • 34547547068 scopus 로고    scopus 로고
    • Touw, D. S.; Nordman, C. E.; Stuckey, J. A; Pecoraro, V. L. Proc. Natl. Acad. Sci. U.S.A. 2007, 104, 11969.
    • (d) Touw, D. S.; Nordman, C. E.; Stuckey, J. A; Pecoraro, V. L. Proc. Natl. Acad. Sci. U.S.A. 2007, 104, 11969.
  • 30
    • 77949344861 scopus 로고    scopus 로고
    • Although the UV-vis spectrum of 2 in THF, MeCN, and CH2Cl 2 reveal differences that suggest a change in the coordination sphere, one cannot rule out whether I- is still coordinated in the donor solvents. λmax for the assigned iodine-to-arsenic charge-transfer band remains the same in all solvents. We expect this band to vanish with the appearance of a new band if only L42- and solvent were coordinated. Thus, performing the UV-vis experiments in MeCN or THF cannot rule out the absence of the As-I bond but does imply a new coordination sphere presumably due to solvent ligation
    • 2- and solvent were coordinated. Thus, performing the UV-vis experiments in MeCN or THF cannot rule out the absence of the As-I bond but does imply a new coordination sphere presumably due to solvent ligation.
  • 31
    • 53549109430 scopus 로고    scopus 로고
    • and references cited therein
    • Nolan, E. M.; Lippard, S. J. Chem. Rev. 2008, 108, 3443 and references cited therein.
    • (2008) Chem. Rev , vol.108 , pp. 3443
    • Nolan, E.M.1    Lippard, S.J.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.