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Although the UV-vis spectrum of 2 in THF, MeCN, and CH2Cl 2 reveal differences that suggest a change in the coordination sphere, one cannot rule out whether I- is still coordinated in the donor solvents. λmax for the assigned iodine-to-arsenic charge-transfer band remains the same in all solvents. We expect this band to vanish with the appearance of a new band if only L42- and solvent were coordinated. Thus, performing the UV-vis experiments in MeCN or THF cannot rule out the absence of the As-I bond but does imply a new coordination sphere presumably due to solvent ligation
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