Electro-oxidation of methane on roughened palladium electrode in acidic electrolytes at ambient temperatures

Analytical Letters

Volumn 43, Issue 6, 2010, Pages 1055-1065

  Zhang, Yan ^a   Zhang, Liqin ^a,b   Shuang, Shaomin ^a   Feng, Feng ^a   Qiao, Jie ^a   Guo, Yujing ^a   Choi, Martin M F ^c   Dong, Chuan ^a  

^a SHANXI UNIVERSITY   (China)

^b Shanxi Center of Geo Environment Monitoring   (China)

^c HONG KONG BAPTIST UNIVERSITY   (Hong Kong)

Author keywords

Electro oxidation; Methane; Roughened Pd electrode

Indexed keywords

EID: 77949326263     PISSN: 00032719     EISSN: 1532236X     Source Type: Journal    
DOI: 10.1080/00032710903492508     Document Type: Article

References (28)

1. Alarnes-Varela, G., A. L. Suárez-Fernández, and A. Costa-García. 1998. Formation of mercury-coated carbon fiber microelectrodes in aprotic media: Application to the voltammetric study of vitamin K1. Electrochim. Acta 44(5): 763-772.
2. Athanasiou, C., G. Marnellos, P. Tsiakaras, and M. Stoukides. 1996. Catalytic and electro-catalytic oxidation of methane on palladium electrodes in a solid electrolyte cell. Ionics. 2(5-6): 353-360.
3. Au, S. F., L. Blum, A. Dengel, B. Groß, L. G. J. de Haart, K. Kimmerle, and M. Wolf. 2005. Utilization of Mine Gas with a SOFC high-temperature fuel cell. J. Power Sources 145: 582-587.
4. Bartlett, P. N., B. Gollas, S. Guerin, and J. Marwan. 2002. The preparation and characterisation of H1-e palladium films with a regular hexagonal nanostructure formed by electro-chemical deposition from lyotropic liquid crystalline phases. Phys. Chem. Chem. Phys. 4: 3835-3842.
5. Bensebaa, F., A. A. Farah, D. Wang, C. Bock, X. Du, J. Kung, and Y. L. Page. 2005. Microwave synthesis of polymer-embedded Pt Ru catalyst for direct methanol fuel cell. J. Phys. Chem. B 109(32): 15339-15344.
6. Chierchie, T., C. Mayer, and W. J. Lorenz. 1982. Structural changes of surface oxide layers on palladium. J. Electroanal. Chem. 135(2): 211-220.
7. Chun, J. H., S. K. Jeon, and J. Y. Chun. 2007. The phase-shift method and correlation constants for determining adsorption isotherms of hydrogen at a palladium electrode interface. Int. J. Hydrogen Energy 32(12): 1982-1990.
8. Frese, K. W. 1991. Partial electrochemical oxidation of methane under mild conditions. Langmuir 7(1): 13-15.
9. García-González, R., M. T. Fernández-Abedul, A. Pernía, and A. Costa-García. 2008. Electrochemical characterization of different screen-printed gold electrodes. Electrochim. Acta 53(8): 3242-3249.
10. Goodman, D. W., and J. A. Rodriguez. 1992. The nature of the metal-metal bond in bimetallic surfaces. Science 257(5072): 897-903.
11. Hahn, F., and C. A. Melendres. 2001. Anodic oxidation of methane at noble metal electrodes: An 'in situ' surface enhanced infrared spectroelectrochemical study. Electrochim. Acta 46(23): 3525-3534.
12. Hoshi, N., K. Kida, M. Nakamura, M. Nakada, and K. Osada. 2006. Structural effects of electrochemical oxidation of formic acid on single crystal electrodes of palladium. J. Phys. Chem. B 110(25): 12480-12484.
13. Huang, T. J., and J. F. Li. 2007. Direct methane oxidation over a Bi2O3-GDC system. J. Power Sources 173: 959-964.
14. Huang, T. J., and M. C. Huang. 2008a. Electrochemical promotion of bulk lattice-oxygen extraction for syngas generation over Ni-GDC anodes in direct-methane SOFCs. Chem. Eng. J. 135: 216-223.
15. Huang, T. J., and M. C. Huang. 2008b. Temperature effect on electrochemical promotion of syngas cogeneration in direct-methane solid oxide fuel cells. J. Power Sources 175(1): 473-481.
16. Jacquinot, P., B. Muller, B. Wehrli, and P. C. Hauser. 2001. Determination of methane and other small hydrocarbons with a platinum-Nafion electrode by stripping voltammetry. Anal. Chim. Acta 432(1): 1-10.
17. Jafarian, M., M. G. Mahjani, H. Heli, F. Gobal, and M. Heydarpoor. 2003. Electrocatalytic oxidation of methane at nickel hydroxide modified nickel electrode in alkaline solution. Electrochem. Commun. 5(2): 184-188.
18. Mengoli, G., M. Bernardini, M. Fabrizio, C. Manduchi, and G. Zannoni. 1996. The insertion/ extraction of deuterium (hydrogen) at Pd sheet electrodes in D2O(H2O){thorn}LiOD(LiOH) electrolyte. J. Electroanal. Chem. 403(1-2): 143-151.
19. Mhadeshwar, A. B., and D. G. Vlachos. 2007. A catalytic reaction mechanism for methane partial oxidation at short contact times, reforming, and combustion, and for oxygenate decomposition and oxidation on platinum. Ind. Eng. Chem. Res. 46(16): 5310-5324.
20. Mukhopadhyay, S., and A. T. Bell. 2003. Direct liquid-phase sulfonation of methane to methanesulfonic acid by SO3 in the presence of a metal peroxide. Angew. Chem. Int. Ed. 42(9): 1019-1021.
21. Psofogiannakis, G., A. St-Amant, and M. Ternan. 2006. Methane oxidation mechanism on Pt(111): A cluster model DFT study. J. Phys. Chem. B 110(48): 24593-24605.
22. Randles, J. E. B. 1948. A cathode ray polarograph. Part II.-The current-voltage curves. Trans. Faraday Soc. 44: 327-338.
23. Sashikata, K., Y. Matsui, K. Itaya, and M. P. Soriaga. 1996. Adsorbed-iodine-catalyzed dissolution of Pd single-crystal electrodes: Studies by electrochemical scanning tunneling microscopy. J. Phys. Chem. 100(51): 20027-20034.
24. Savadogo, O., K. Lee, K. Oishi, S. Mitsushima, N. Kamiya, and K. I. Ota. 2004. New palladium alloys catalyst for the oxygen reduction reaction in an acid medium. Electrochem. Commun. 6(2): 105-109.
25. Sheng, M., M. Mangold, and A. Kienle. 2006. A strategy for the spatial temperature control of a molten carbonate fuel cell system. J. Power Sources 162: 1213-1219.
26. 2-d/Pt and Ce0.9Sm0.1O2-d/Pt anodes. Catal. Lett. 112(1-2): 19-26.
27. O) electrochemical system. J. Electroanal. Chem. 434(1-2): 31-36.
28. Zudans, I., J. R. Paddock, H. Kuramitz, A. T. Maghasi, C. M. Wansapura, S. D. Conklin, N. Kaval, et al. 2004. Electrochemical and optical evaluation of noble metal- and carbon-ITO hybrid optically transparent electrodes. J. Electroanal. Chem. 565(2): 311-320.