Enantioseparation via EIC-OSN: Process design and improvement of enantiomers resolvability and separation performance

AIChE Journal

Volumn 56, Issue 4, 2010, Pages 893-904

  Sereewatthanawut, Issara ^a   Ferreira, Frederico Castelo ^b,c   Ghazali, Nazlee F ^c   Livingston, Andrew G ^c  

^a Membrane Extraction Technology Ltd   (United Kingdom)

^b INSTITUTO SUPERIOR TÉCNICO   (Portugal)

^c IMPERIAL COLLEGE LONDON   (United Kingdom)

Author keywords

Chiral resolution; Enantioselective inclusion complexation; Membrane separation; Organic solvent nanofiltration; Resolvability

Indexed keywords

CHIRAL RESOLUTIONS; ENANTIOSELECTIVE; INCLUSION COMPLEXATION; MEMBRANE SEPARATION; ORGANIC SOLVENT NANOFILTRATION;

CHIRALITY; ENANTIOMERS; MATHEMATICAL MODELS; NANOFILTRATION; ORGANIC SOLVENTS;

PROCESS DESIGN;

EID: 77949295962     PISSN: 00011541     EISSN: 15475905     Source Type: Journal    
DOI: 10.1002/aic.12025     Document Type: Article

References (12)

1. Breuer M, Ditrich K, Habicher T, Hauer B, Kesseler M, Stürmer R, Zelinski T. Industrial methods for the production of optically active intermediates. Angew Chem Int Ed. 2004;43:788-824.
2. Kozma D. CRC Handbook of Optical Resolution via Diastereomeric Salt Formation. Boca Raton: CRC Press, 2002.
3. Toda F. Inclusion by acetylenic alcohols and some other novel host compounds. In: Atwood JL, Davies JED, MacNicol DD. Inclusion compounds: Volume 4. New York, NY: Oxford University Press, 1991:126-187.
4. Pellissier H. Use of TADDOLs and their derivatives in asymmetric synthesis. Tetrahedron. 2008;64:10279-10317.
5. Müller S, Afraz MC, de Gelder R, Ariaans GJA, Kaptein B, Broxterman QB, Bruggink A. Design and evaluation of inclusion resolution, based on readily available host compounds. Eur J Org Chem. 2005;1082-1096.
6. Xie R, Chu L-Y, Deng J-G. Membranes and membrane processes for chiral resolution. Chem Soc Rev. 2008;37:1243-1263.
7. Vandezande P, Gevers LEM, Vankelecom IFJ. Solvent resistant nanofiltration: separating on a molecular level. Chem Soc Rev. 2008;37:365-405.
8. Nasso M, Livingston AG. Solvent nanofiltration in organic process: a rapid and scalable purification technology. Chim Oggi. 2008;26: 62-66.
9. Ghazali NF, Ferreira FC, White AJP, Livingston AG. Enantiomer separation by enantioselective inclusion complexation-organic solvent nanofiltration. Tetrahedron Asymmetry. 2006;17:1846-1852.
10. Fogassy E, Lopata A, Faigl F, Darvas F, A ́ cs M, To ̃ke L. A quantitative approach to optical resolution. Tetrahedron Lett. 1980;21: 647-650.
11. Toda F, Tanaka K, Ootani M, Hayashi A, Miyahara I, Hirotsu K. Structure study of host-guest molecular association in solution and in the solid state. J Chem Soc Chem Commun. 1993;1413-1415.
12. Allred AL. Electronegativity values from thermochemical data. J Inorg Nucl Chem. 1961;17:215-221.