Chemical nature of adhesion: Plasma modified styrene-butadiene elastomer and polyurethane adhesive joints

European Polymer Journal

Volumn 46, Issue 4, 2010, Pages 767-773

  Tyczkowski, J ^a   Krawczyk Klys I ^b   Kuberski, S ^a   Makowski, P ^a  

^a LODZ UNIVERSITY OF TECHNOLOGY   (Poland)

^b Laboratory of Materials and Consumer Packaging Testing   (Poland)

Author keywords

Adhesion by chemical bonding; Polyurethane adhesive; Styrene butadiene copolymer; Surface treatment by plasma

Indexed keywords

CHEMICAL BONDINGS; POLYURETHANE ADHESIVES; STYRENE-BUTADIENE COPOLYMERS;

ADHESION; ADHESIVE JOINTS; BUTADIENE; CHEMICAL BONDS; COPOLYMERIZATION; ELECTRIC DISCHARGES; FOURIER TRANSFORM INFRARED SPECTROSCOPY; ORGANIC POLYMERS; PLASMAS; RUBBER; STYRENE; SURFACE TREATMENT;

PLASMA DIAGNOSTICS;

EID: 77749270552     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2009.12.019     Document Type: Article

References (28)

1. Patrie E.M. Handbook of adhesives and sealants (2000), McGraw-Hill, New York
2. Cognard J. Some recent progress in adhesion technology and science. CR Chim 9 (2006) 13-24
3. Pastor-Blas M.M., Martin-Martinez J.M., and Boerio F.J. Mechanisms of adhesion in surface chlorinated thermoplastic rubber/thermoplastic polyurethane adhesive joints. Rubber Chem Technol 75 (2002) 825-837
4. Romero-Sanchez M.D., Pastor-Blas M.M., and Martin-Martinez J.M. Environmental friendly surface treatments of styrene-butadiene-styrene rubber: alternatives to the solvent-based halogenation treatment. Int J Adhes Adhes 25 (2005) 19-29
5. Anagreh N., Dorn L., and Bilke-Krause C. Low-pressure plasma pretreatment of polyphenylene sulfide (PPS) surfaces for adhesive bonding. Int J Adhes Adhes 28 (2007) 16-22
6. 4 radio frequency plasma immersion. Plasma Chem Plasma Process 28 (2008) 715-728
7. Cepeda-Jiménez C.M., Torregrosa-Maciá R., and Martin-Martinez J.M. Surface modifications of EVA copolymers by using RF oxidizing and non-oxidizing plasmas. Surf Coat Technol 174 /175 (2003) 94-99
8. Noeske M., Degenhardt J., Strudthoff S., and Lommatzsch U. Plasma jet treatment of five polymers at atmospheric pressure: surface modifications and the relevance for adhesion. Int J Adhes Adhes 24 (2004) 171-177
9. Martinez-García A., Sánchez-Reche A., Gisbert-Soler S., Cepeda-Jiménez C.M., Torregrosa-Maciá R., and Martin-Martinez J.M. Treatment of EVA with corona discharge to improve its adhesion to polychloroprene adhesive. J Adhes Sci Technol 17 (2003) 47-65
10. Inagaki N. Plasma surface modification and plasma polymerization (1996), Technomic, Lancaster
11. In: Strobel M., Lyons C.S., and Mittal K.L. (Eds). Plasma surface modification of polymers: relevance to adhesion (1994), VSP BV, Utrecht
12. Hamaguchi S., Yamashiro M., Matsukuma M., and Yamada H. Modelling of plasma surface interaction. J Phys: Conf Ser 86 (2007) 012016
13. Tahara M., Cuong N.K., and Nakashima Y. Improvement in adhesion of polyethylene by glow-discharge plasma. Surf Coat Technol 173 /174 (2003) 826-830
14. 2 plasma treatment. Eur Polym J 42 (2006) 1558-1568
15. Pastor-Blas M.M., Martin-Martinez J.M., and Dillard J.G. Surface characterization of synthetic vulcanized rubber treated with oxygen plasma. Surf Interface Anal 28 (1998) 385-399
16. Pastor-Blas M.M., Ferrándiz-Gómez T.P., and Martin-Martinez J.M. Assessment of the locus of failure of oxygen plasma-treated rubber/polyurethane adhesive joints using XPS and IRATR spectroscopy. Surf Interface Anal 30 (2000) 7-11
17. 2 RF plasma treatment on a synthetic vulcanized styrene-butadiene rubber. Plasmas and Polym 6 (2001) 81-105
18. Tyczkowski J., Krawczyk I., and Woźniak B. Modification of styrene-butadiene rubber surfaces by plasma chlorination. Surf Coat Technol 174 /175 (2003) 849-853
19. Tyczkowski J., Krawczyk I., and Woźniak B. Plasma surface modification of styrene-butadiene elastomers for improved adhesion. In: d'Agostino R., Favia P., Oehr C., and Werheimer M.E. (Eds). Plasma processes and polymers (2005), Wiley-VCH, Weinheim 233-252
20. 2 RF plasmas in the adhesion of thermoplastic rubber to polyurethane adhesive. In: d'Agostino R., Favia P., Oehr C., and Werheimer M.E. (Eds). Plasma processes and polymers (2005), Wiley-VCH, Weinheim 177-192
21. Tyczkowski J., Krawczyk I., Woźniak B., and Martin-Martinez J.M. Low-pressure plasma chlorination of styrene-butadiene block copolymer for improved adhesion to polyurethane adhesives. Eur Polym J 45 (2009) 1826-1835
22. Wirpsza Z. Polyurethanes-chemistry, technology and applications (1993), E. Horwood, New York
23. Bronco S., Bertoldo M., Taburoni E., Cepek C., and Sancrotti M. The effects of cold plasma treatments on LDPE wettability and curing kinetic of a polyurethane adhesive. Macromol Symp 218 (2004) 71-80
24. Pretsch E., Bühlmann P., and Affolter C. Structure determination of organic compounds-tables of spectral data (2000), Springer, Berlin
25. Software-KnowItAll® Informatics System 8.0. Bio-Rad Laboratories: Inc., Philadelphia; 2009.
26. Chu P.M., Guenther F.R., Rhoderick G.C., and Lafferty W.J. The NIST quantitative infrared database. J Res Natl Inst Stand Technol 104 (1999) 59-81
27. Infrarot-Spektren von Gasen, Analytische Systeme und Componenten GmbH. Karlsruhe; 2009. Available from .
28. Wang S.M., Chang J.R., and Tsiang R.C.C. Infrared studies of thermal oxidative degradation of polystyrene-block-polybutadiene-block-polystyrene thermoplastic elastomers. Polym Degrad Stabil 52 (1996) 51-57