Interaction of a phosphorus-based FR, a nanoclay and PA6. Part 2 interaction of the complete PA6 polymer nanocomposites

Fire and Materials

Volumn 34, Issue 2, 2010, Pages 77-93

  Ramani, Alwar ^a   Hagen, Martin ^a   Hereid, Johan ^a   Zhang, Jianping ^a   Delichatsios, Michael ^a  

^a UNIVERSITY OF ULSTER   (United Kingdom)

Author keywords

Exolit OP1311; Nanocomposite; PA6; TGA FTIR; Thermal decomposition

Indexed keywords

CHAR FORMATION; CLOISITE; DECOMPOSITION PRODUCTS; DEGRADATION TEMPERATURES; EVOLVED GAS; FIRE RETARDANT; GASPHASE; HYDROGEN CYANIDE; NANO CLAYS; PA6; PA6 NANOCOMPOSITES; POLYAMIDE 6; POLYMER NANOCOMPOSITE; RESIDUAL MASS; TGA-FTIR; THERMAL DECOMPOSITIONS; THERMAL DEGRADATIONS; THERMO-OXIDATIVE DEGRADATION;

CARBON DIOXIDE; CARBON MONOXIDE; CYANIDES; FLAME RETARDANTS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HYDROCARBONS; NANOCOMPOSITES; NANOSTRUCTURED MATERIALS; PHOSPHORUS; PHOTODEGRADATION; PHOTORESISTS; PYROLYSIS; REACTION KINETICS;

THERMOGRAVIMETRIC ANALYSIS;

EID: 77649325122     PISSN: 03080501     EISSN: 10991018     Source Type: Journal    
DOI: 10.1002/fam.1012     Document Type: Article

References (16)

1. Levchik SV, Weil ED, Lewin M. Thermal decomposition of aliphatic nylons. Polymer International 1999; 48:532-537.
2. Pramoda KP, Liu T, Liu Z, He C, Sue HJ. Thermal degradation behaviour of polyamide 6/clay nanocomposite. Polymer Degradation and Stability 2003; 81:47-56.
3. Jang BN, Wilkie CA. The effect of clay on the thermal degradation of polyamide 6 in polyamide 6/clay nanocomposites. Polymer 2005; 46:3264-3274.
4. Hay JN, Holland BJ. Thermal degradation of nylon polymers. Polymer International 2000; 49:943-948.
5. Dabrowski F, Bourbigot S, Delobel R, Le Bras M. Kinetic modelling of the thermal degradation of polyamide-6 nanocomposite. European Polymer Journal 2002; 36:273-284.
6. Kashiwagi T, Harris RH, Zhang X, Briber RM, Cipriano BH, Raghavan SR, Awad WH, Shields JR. Flame retardant mechanism of polyamide 6-clay nanocomposites. Polymer 2004; 45:881-891.
7. Bourbigot S, Duquesne S, Jama C. Polymer nanocomposites: how to reach low flammability. Macromolecular Symposium, Bruges, Belgium, vol.233, 2006; 180-190.
8. Laachachi A, Cochez M, Leroy E, Ferriol M, Lopez-Cuesta JM. Fire retardant systems in poly(methyl methacrylate): interactions between metal oxide nanoparticles and phosphinates. Polymer Degradation and Stability 2007; 92:61-69.
9. Braun U, Balabanovich AI, Schartel B, Knoll U, Artner J, Ciesielski M, Döring M, Perez R, Sandler JKW, Altstädt V, Hoffmann T. Pospiech D. Influence of the oxidation state of phosphorus on the decomposition and fire behaviour of flame-retarded epoxy resin composites. Polymer 2006; 47:8495-8508.
10. Samyn F, Bourbigot S, Jama C, Nazare S, Hull R, Fina A, Castrovinci A, Camino G. Characterisation of the dispersion in polymer flame retarded nanocomposites. European Polymer Journal 2008; 44:1631-1641.
11. Ramani A, Hagan M, Hereid J, Zhang J, Bakirtzis D, Delichatsios M. Interaction of a phosphorus based FR, a nanoclay and PA6 part 1. Interaction of FR and nanoclay. Fire and Materials 2009; DOI: 10.1002/fam.1004.
12. Holland J, Hay N. Thermal degradation of nylon polymers. Polymer International 2000; 49:943-948.
13. Braun U, Schartel B. The effect of red phosphorous and melamine polyphosphate on fire behaviour of HIPS. Journal of Fire Sciences 2005; 23:5.
14. Braun U, Schartel B, Fichera MA, Jäger C. Flame retardancy mechanisms of aluminium phosphinate with melamine polyphosphate and zinc borate in glass-fibre reinforced polyamide 6,6. Polymer Degradation and Stability 2007; 92:1528-1545.
15. Jenwein E, Kleriner HB, Wanzke W, Budzinsky W. US patent 6,365,071, 2002.
16. Bourbigot S, Le Bras M, Dabrowski F, Gilman JW, Kashiwagi T. PA6 clay nanocomposite hybrid as char forming agent in intumescent formulations. Fire and Materials 2000; 24:201-208.