Moringa oleifera-A solid phase extractant for the removal of copper, nickel and zinc from aqueous solutions

Chemical Engineering Journal

Volumn 158, Issue 2, 2010, Pages 188-199

  Helen Kalavathy, M ^a   Miranda, Lima Rose ^a  

^a ANNA UNIVERSITY   (India)

Author keywords

Adsorption isotherms; Adsorption mechanism; Desorption; FT IR; Heavy metals; Moringa oleifera; SEM

Indexed keywords

ADSORBATE CONCENTRATION; ADSORPTION MECHANISM; ADSORPTION PROCESS; AQUEOUS SOLUTIONS; CARBON DOSE; CONTACT TIME; DUBININ-RADUSHKEVICH; EFFECTIVE DIFFUSION COEFFICIENTS; ENTHALPY CHANGE; ENTROPY CHANGES; EQUILIBRIUM DATA; EXTRACTANTS; FILM DIFFUSION; FREE ENERGY CHANGE; FREUNDLICH; INTRA-PARTICLE DIFFUSION; ISOTHERM MODELS; KINETIC MODELS; KINETIC STUDY; LANGMUIRS; MORINGA OLEIFERA; OPERATING VARIABLES; OPTIMUM PH; PARTICLE DIFFUSION; PSEUDO-FIRST-ORDER; PSEUDO-SECOND ORDER MODEL; SEM; SOLID-PHASE; SOLUTION PH; SYNTHETIC WASTE WATER; THERMODYNAMIC PARAMETER;

ACTIVATED CARBON; ADSORPTION ISOTHERMS; AGRICULTURAL PRODUCTS; CHEMICALS REMOVAL (WATER TREATMENT); DESORPTION; DIFFUSION IN SOLIDS; DYES; HEAVY METALS; KINETIC THEORY; METAL IONS; METAL RECOVERY; METALS; NICKEL ALLOYS; PH EFFECTS; RATE CONSTANTS; SOLID WASTES; WASTEWATER; ZINC;

ADSORPTION;

ACTIVATED CARBON; ADSORPTION; AGRICULTURE; DESORPTION; DIFFUSION; DYES; HEAVY METALS; ISOTHERMS; MORINGA; NICKEL COMPOUNDS; WASTE WATERS; WATER TREATMENT;

MORINGA OLEIFERA;

EID: 77649275987     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2009.12.039     Document Type: Article

References (69)

1. Clement R.E., Eiceman G.A., and Koester C.J. Environmental analysis. Anal. Chem. 67 (1995) 221R-255R
2. MacCarthy P., Klusman R.W., Cowling S.W., and Rice J.A. Water analysis. Anal. Chem. 67 (1995) 525R-582R
3. Barceloux D.G. Copper. J. Toxicol. Clin. Toxicol. 37 (1999) 217-230
4. Barceloux D.G. Nickel. J. Toxicol. Clin. Toxicol. 37 (1999) 239-258
5. Burrell D.C. Atomic Spectrometric Analysis of Heavy Metal Pollutants in Water (1974), Ann Arbor Science Publishers, Ann Arbor, Michigan pp. 19-45
6. Berman E. Toxic Metals and their Analysis (1980), Heyden, London
7. WHO's Guidelines for Drinking-water Quality, set up in Geneva, 1993.
8. Meunier N., Drogui P., Montane C., Hausler R., Mercier G., and Blais J.F. Comparison between electrocoagulation and chemical precipitation for metals removal from acidic soil leachate. J. Hazard. Mater. 137 (2006) 581-590
9. Kurniawan T.A., Chan G.Y.S., Lo W.H., and Babel S. Physico-chemical treatment techniques for wastewater laden with heavy metals. Chem. Eng. J. 118 (2006) 83-98
10. Cochrane E.L., Lu S., Gibb S.W., and Villaescusa I. A comparison of low-cost biosorbents and commercial sorbents for the removal of copper from aqueous media. J. Hazard. Mater. 137 (2006) 198-206
11. Srivastava S.K., Tyagi R., and Pant N. Adsorption of heavy metal ions on carbonaceous material developed from the waste slurry generated in local fertilizer plants. Water Res. 23 (1989) 1161-1165
12. Galiatsatou P., Metaxas M., and Kasselouri R.V. Adsorption of zinc by activated carbon prepared from solvent extracted olive pulp. J. Hazard. Mater. B91 (2002) 187-203
13. Bailey S.E., Olin T.J., Bricka R.M., and Adrian D.D. A review of potentially low-cost sorbents for heavy metals. Water Res. 33 (1999) 2469-2479
14. 2+ by a sequencing batch reactor (SBR) system. Bioresour. Technol. 98 (2007) 808-818
15. Matheickal J.T., and Yu Q. Biosorption of lead(II) and copper(II) from aqueous solutions by pre-treated biomass of Australian marine algae. Bioresour. Technol. 69 (1999) 223-229
16. Bansal R.C., Donnet J.B., and Stoeckli F. Active Carbon (1988), Marcel Dekker, New York
17. Rodri{dotless}guez-Reinoso F., and Molina-Sabio M. Activated carbons from lignocellulosic materials by chemical and/or physical activation: an overview. Carbon 30 (1992) 1111-1118
18. Wigmans T. Industrial aspects of production and use of activated carbon. Carbon 27 (1989) 13-22
19. Jaytogen M., Thwaites M., Stencel J., McEnaney B., and Derbyshire F. Adsorbent carbon synthesis from coals by phosphoric acid activation. Carbon 30 (1992) 1089-1096
20. Warhurst A.M., McConnachie G.L., and Pollard S.J.T. Characterisation and applications of activated carbon produced from Moringa oleifera seed husks by single-step steam pyrolysis. Water Res. 31 (1997) 759-766
21. Warhurst A.M., McConnachie G.L., and Pollard S.J.T. The production of activated carbon for water treatment in Malawi from the waste seed husks of Moringa oleifera. Water Sci. Tech. 34 (1996) 177-184
22. Bhatti H.N., Mumtaz B., Hanif M.A., and Nadeem R. Removal of Zn(II) ions from aqueous solution using Moringa oleifera Lam. (horseradish tree) biomass. Proc. Biochem. 42 (2007) 547-553
23. 2+ from aqueous solutions by Moringa oleifera bark: Equilibrium and kinetic studies. J. Hazard. Mater. 174 (2010) 831-838
24. Sharma P., Kumari P., Srivastava M.M., and Srivastava S. Removal of cadmium from aqueous system by shelled Moringa oleifera Lam. seed powder. Bioresour. Technol. 97 (2006) 299-305
25. - activated rubber wood sawdust. J. Colloid Interface Sci. 292 (2005) 354-362
26. Onyango M.S., Kojima Y., Aoyi O., Bernardo E.C., and Matsuda H. Adsorption Equilibrium modeling and solution chemistry dependence of fluoride removal from water by trivalent cation-exchange zeolite F-9. J. Colloid Interface Sci. 279 (2004) 341-350
27. ASTM D 4607-86 Philadelphia, PA: ASTM Committee on Standards, 1986.
28. Jeffery G.H., Bassett J., Mendham J., and Denny R.C. Vogel's Text Book of Quantitative Chemical Analysis. 5th edition (1996), John Wiley and sons, New York
29. Manivasakam N. Industrial Effluents Origin, Characteristics. Effects Analysis and Treatment (1987), Sakthi Publication, Coimbatore, India
30. Nomanbhay M.S., and Palanisamy K. Removal of Heavy metal from industrial waste using chitosan coated oil palm shell charcoal. Electron. J. Biotechnol. 8 (2005) 43-53
31. Mall I.D., Srivastava V.C., Agarwal N.K., and Mishra I.M. Removal of congo red from aqueous solution by bagasse fly ash and activated carbon: Kinetic study and equilibrium isotherm analyses. Chemosphere 61 (2005) 492-501
32. Amarasinghe B.M.W.P.K., and Williams R.A. Tea waste as a low cost adsorbent for the removal of Cu and Pb from wastewater. Chem. Eng. J. 132 (2007) 299-309
33. McKay G., Otterburn M.S., and Sweeney A.G. The removal of colour from effluents using various adsorbents-III silica rate process. Water Res. 14 (1980) 15-20
34. Namasivayam C., and Yamuna R.T. Adsorption of chromium(VI) by a low cost adsorbent: Biogas residual slurry. Chemosphere 30 (1993) 561-578
35. Ho Y.S., Porter J.F., and McKay G. Equilibrium isotherm studies for the sorption of divalent metal ions onto peat: copper, nickel and lead single component systems. Water Air Soil Pollut. 141 (2002) 1-33
36. Orhan Y., and Bugukgunor H. The removal of heavy metals by using agricultural wastes. Water Sci. Technol. 28 (1993) 247-255
37. Langmuir I. The adsorption of gases on plane surfaces of glass, mica and platinum. J. Am. Chem. Soc. 40 (1918) 1361-1403
38. Freundlich H.M.F. Over the adsorption in solution. Z. Phys. Chem. 57A (1906) 385-470
39. Temkin M.J., and Pyzhev V. Kinetics of ammonia synthesis on promoted iron catalysts. Acta Physiochim. URSS 12 (1940) 327-356
40. Dubinin M.M. The potential theory of adsorption of gases and vapors for adsorbents with energetically non-uniform surface. Chem. Rev. 60 (1960) 235-266
41. Rieman W., and Walton H. Ion Exchange in Analytical Chemistry, International Series of Monographs in Analytical Chemistry, vol. 38 (1970), Pergamon Press, Oxford
42. 3+ pretreated low-silica synthetic zeolites: adsorption equilibrium and rate studies. Sep. Sci. Technol. 41 (2006) 683-704
43. Agrawal A., Sahu K.K., and Pandey B.D. Removal of zinc from aqueous solutions using sea nodule residue. Colloids Surf. A: Physicochem. Eng. Asp. 237 (2004) 133-140
44. Lagergren S. Zur theorie der sogenannten adsorption gelöster stoffe. Kungliga Svenska Vetenskapsakademiens. Handlingar 24 (1898) 1-39
45. Ho T.S., and McKay G. The Kinetics of sorption of basic dyes from aqueous solution by sphagnum moss peat. Can. J. Chem. Eng. 76 (1998) 822-827
46. Weber W.J., and Morris J.C. Kinetics of adsorption on carbon from solution. J. Sanit. Eng. Div. Am. Soc. Civ. Eng. 89 (1963) 31-60
47. Vermeulen T. Theory of irreversible and constant-pattern solid diffusion. Ind. Eng. Chem. 45 (1953) 1664-1670
48. Boyd G.E., Adamson A.W., and Meyers L.S. The exchange adsorption of ions from solution from organic zeolites. II. Kinetics. J. Am. Chem. Soc. 69 (1947) 2836-2848
49. Chen B., Hui C.M., and Mckay G. Film-pore diffusion modelling for the sorption of metal ions from aqueous effluents onto peat. Water Res. 35 (2001) 3345-3356
50. Srivastava V.C., Mall I.D., and Mishra I.M. Characterization of mesoporous rice husk ash (RHA) and adsorption kinetics of metal ions from aqueous solution onto RHA. J. Hazard. Mater. B134 (2006) 257-267
51. Imamoglu M., and Tekir O. Removal of copper (II) and lead (II) ions from aqueous solutions by adsorption on activated carbon from a new precursor hazelnut husks. Desalination 228 (2008) 108-113
52. Machida M., Aikawa M., and Tatsumoto H. Prediction of simultaneous adsorption of Cu(II) and Pb(II) onto activated carbon by conventional Langmuir type equations. J. Hazard. Mater. B120 (2005) 271-275
53. Weng C.H., Tsai C.Z., Chu S.H., and Sharma Y.C. Adsorption characteristics of copper(II) onto spent activated clay. Sep. Purif. Technol. 54 (2007) 187-197
54. Acar F.N., and Eren Z. Removal of Cu(II) ions by activated poplar sawdust (Samsun Clone) from aqueous solutions. J. Hazard. Mater. 137 (2006) 909-914
55. Teker M., Imamoglu M., and Saltabas O. Adsorption of copper and cadmium ions by activated carbon from rice hulls. Turkish J. Chem. 23 (1999) 185-191
56. Ozer A., and Tumen F. Cd(II) adsorption from aqueous solution by activated carbon from sugar beet pulp impregnated with phosphoric acid. Fresen. Environ. Bull. 12 (2003) 1050-1058
57. Budinova T.K., Gergova K.M., Petrov N.V., and Minkova V.N. Removal of metal ions from aqueous solution by activated carbons obtained from different raw materials. J. Chem. Technol. Biotechnol. 60 (1994) 177-182
58. Periasamy K., and Namasivayam C. Process development for removal and recovery of cadmium from wastewater by a low-cost adsorbent: adsorption rates and equilibrium studies. Ind. Eng. Chem. Res. 33 (1994) 317-320
59. Mohan D., and Singh K.P. Single-and multi-component adsorption of cadmium and zinc using activated carbon derivated from bagasse-an agricultural waste. Water Res. 36 (2002) 2304-2318
60. Demirbas E., Kobya M., Oncel S., and Sencan S. Removal of Ni(II) from aqueous solution by adsorption onto hazelnut shell activated carbon: equilibrium studies. Bioresour. Technol. 84 (2002) 291-293
61. Periasamy K., and Namasivayam C. Removal of nickel (II) from aqueous solution wastewater using an agricultural waste: peanut hulls. Waste Manage. 15 (1995) 63-68
62. Kadirvelu K., Thamaraiselvi K., and Namasivayam C. Adsorption of nickel(II) from aqueous solution onto activated carbon prepared from coirpith. Sep. Purif. Technol. 24 (2001) 497-505
63. Erdogan S., Onal Y., Akmil-Basar C., Bilmez-Erdemoglu S., Sari{dotless}ci{dotless}-Ozdemir C., Koseoglu E., and Icduygu G. Optimization of nickel adsorption from aqueous solution by using activated carbon prepared from waste apricot by chemical activation. Appl. Surf. Sci. 252 (2005) 1324-1331
64. Amuda O.S., Giwa A.A., and Bello I.A. Removal of heavy metal from industrial wastewater using modified activated coconut shell carbon. Biochem. Eng. J. 36 (2007) 174-181
65. Aklil A., Mouflih M., and Sebti S. Removal of heavy metal ions from water by using calcined phosphate as a new adsorbent. J. Hazard. Mater. A112 (2004) 183-190
66. Lopez E., Soto B., Arias M., Nunez A., Rubinos D., and Barral M.T. Adsorbent properties of red mud and its use for wastewater treatment. Water Res. 32 (1998) 1314-1322
67. Allen S.J., and Brown P. Isotherm analysis for single component and multi-component metal sorption onto lignite. J. Chem. Technol. Biotechnol. 62 (1995) 17-24
68. McKay G., Vong B., and Porter J.F. Isotherm studies for the sorption of metal ions onto peat. Adsorpt. Sci. Technol. 16 (1998) 51-66
69. Srivastava S.K., Gupta V.K., and Mohan D. Design parameters for fixed bed reactors of activated carbon developed from fertilizer waste for the removal of some heavy metal ions. Waste Manage. 17 (1997) 517-522