Silsesquioxane-based hybrid nanocomposite with self-assembling properties for porous limestones conservation

High Performance Polymers

Volumn 22, Issue 1, 2010, Pages 42-55

  Simionescu, Bogdana ^a   Olaru, Mihaela ^b   Aflori, Magda ^b   Cotofana, Corneliu ^b  

^a UNIVERSITY OF OVIEDO   (Spain)

^b PETRU PONI INSTITUTE OF MACROMOLECULAR CHEMISTRY   (Romania)

Author keywords

Nanocomposite; Porous limestone conservation; Self assembling; Silsesquioxane

Indexed keywords

HYBRID NANOCOMPOSITES; NANO METER RANGE; POROUS LIMESTONE CONSERVATION; PRIMARY AMINES; PROPYL METHACRYLATE; RADICAL POLYMERIZATION; SELF-ASSEMBLING; SELF-ASSEMBLING PROPERTIES; SILSESQUIOXANES; SOL-GEL APPROACH; SYNTHESIS AND CHARACTERIZATION;

LIMESTONE; ORGANIC POLYMERS; POLYMER BLENDS; SILICA; SOL-GELS; SUPRAMOLECULAR CHEMISTRY; SURFACE ACTIVE AGENTS; SYNTHESIS (CHEMICAL);

NANOCOMPOSITES;

EID: 77649265757     PISSN: 09540083     EISSN: 13616412     Source Type: Journal    
DOI: 10.1177/0954008308100905     Document Type: Article

References (39)

1. Hartmann, S., Brandhuber, D. and Hüsing, N. (2007). Glycol-Modified Silanes: Novel Possibilities for the Synthesis of Hierarchically Organized (Hybrid) Porous Materials, Acc. Chem. Res., 40: 885-894.
2. Rottman, C., Grader, G.S., De Hazan, Y. and Avnir, D. (1996). Sol-Gel Entrapment of ET (30) in Ormosils. Interfacial Polarity-Fractality Correlation, Langmuir, 12: 5505-5508.
3. Braun, S., Rappoport, S., Zusman, R., Avnir, D. and Ottolenghi, M. (1990). Biochemically Active Sol-gel Glasses: the Trapping of Enzymes, Mater. Lett., 10: 1-5.
4. Li, B. and Takahashi, H. (2004). New Immobilization Method for Enzyme Stabilization Involving a Mesoporous Material and an Organic/inorganic Hybrid Gel, Biotechnol. Lett., 22: 1953-1958.
5. Chiu, W.M., Yang, C.F. and Zhang, Y.S. (2007). Synthesis of Silicon Dioxide Optical Films Mixed with Acrylic Series Monomers by Sol-gel Process, Polym. Plast. Technol. Eng., 46: 767-773.
6. 2/poly(vinyl pyrrolidone) Composite Materials for Optical Waveguides, Chem. Mater., 8: 235-241. (Pubitemid 126485096)
7. Wang, B., Li, B., Deng, Q. and Dong, S. (1998). Amperometric Glucose Biosensor Based on Sol-Gel Organic-Inorganic Hybrid Material, Anal. Chem., 70: 3170-3174.
8. Scherer, G.W. and Wheeler, G.S. (2009). Silicate Consolidants for Stone, Key Eng. Mater., 391: 1-26.
9. Ji, X., Hampsey, J.E., Hu, Q., He, J., Yang, Z. and Lu, Y. (2003). Mesoporous Silica-Reinforced Polymer Nanocomposites, Chem. Mater., 15: 3656-3662.
10. Wight, A.P. and Davis, M.E. (2002). Design and Preparation of Organic-Inorganic Hybrid Catalysts, Chem. Rev., 102: 3589-3614.
11. Pescarmona, P.P. and Maschmeyer, T. (2002). Oligomeric Silsesquioxanes: Synthesis, Characterization and Selected Applications, Aust. J. Chem., 54: 583-596.
12. Du, J. and Chen, Y. (2005). Hairy Nanospheres by Gelation of Reactive Block Copolymer Micelles, Macromol. Rapid Commun., 26: 491-494.
13. Du, J. and Chen, Y. (2004). Preparation of Organic/Inorganic Hybrid Hollow Particles Based on Gelation of Polymer Vesicles, Macromolecules, 37: 5710-5716.
14. Du, J., Chen, Y., Zhang, Y., Han, C.C., Fischer, K. and Schmidt, M. (2003). Organic/Inorganic Hybrid Vesicles Based on A Reactive Block Copolymer, J. Am. Chem. Soc., 125: 14710-14711.
15. Du, J. and Chen, Y. (2004). Organic-Inorganic Hybrid Nanoparticles with a Complex Hollow Structure, Angew. Chem. Int. Ed., 43: 5084-5087.
16. Jackson, C.L., Bauer, B.J., Nakatani, A.I. and Barnes, J.D. (1996). Synthesis of Hybrid Organic-Inorganic Materials from Interpenetrating Polymer Network Chemistry, Chem. Mater., 8: 727-733.
17. Wheeler, G.S., Fleming, S.A. and Ebersole, S. (1992). In Delgado, J., Henriques, F. and Jeremias, F. (eds), Proceedings of the 7th International Congress on Deterioration and Conservation of Stone, Lisbon.
18. Ji, X., Hampsey, J.E., Hu, Q., He, J., Yang, Z. and Lu, Y. (2003). Mesoporous Silica-Reinforced Polymer Nanocomposites, Chem. Mater., 15: 3656-3662.
19. Wight, A.P. and Davis, M.E. (2002). Design and Preparation of Organic-Inorganic Hybrid Catalysts, Chem. Rev., 102: 3589-3614.
20. Mosquera, M.J., de los Santos, D.M., Montes, A. and Valdez-Castro, L. (2008). New Nanomaterials for Consolidating Stone, Langmuir, 24: 2772-2778.
21. Mosquera, M.J., de los Santos, D.M., Montes, A., Valdez-Castro and Esquivias, L. (2008). New Route for Producing Crack-Free Xerogels: Obtaining Uniform Pore Size, J. Non-Cryst. Solids, 354: 645-650.
22. Brinker, C.J., Keefer, K.D., Schaefer, D.W. and Ashley, C.S. (1982). Sol-gel Transition in Simple Silicates, J. Non-Cryst. Solids, 48: 47-64.
23. Miller, J.D., Hoh, K.P. and Ishida, H. (1984). Studies of the Simulation of Silane Coupling Agent Structures on Particulate Fillers; the pH Effect, Polym. Compos., 5: 18-28.
24. Brown, J.F. (1965). The Polycondensation of Phenylsilanetriol, J. Am. Chem. Soc., 87: 4317-4324.
25. Xu, H., Xie, P. and Zhang, R. (2001). Synthesis and Characterization of Oligomeric Silsesquioxane with Pendent Carboxylic Acid Groups, Eur. Polym. J., 37: 2397-2405.
26. åurca Vuk, A., Fir, M., Jeåe, R., Vilänik, A. and Orel, B. (2008). Structural Studies of Sol-gel Urea/polydimethylsiloxane Barrier Coatings and Improvement of their Corrosion Inhibition by Addition of Various Alkoxysilanes, Progr. Org. Coat., 63: 123-132.
27. Brown Jr, J.F., Vogt Jr, L.H., Katchman, A., Eustance, J.W., Kiser, K.M. and Krantz, K.W. (1960). Double Chain Polymers of Phenylsilsesquioxane, J. Am. Chem. Soc., 82: 6194-6195.
28. Prado, L.A.S.D., Radovanovic, E., Pastore, H.O., Yoshida, I.V.P. and Torriani, I.L. (2000). Poly(phenylsilsesquioxane)s: Structural and Morphological Characterization, J. Polym. Sci. Part A: Polym. Chem., 38: 1580-1589.
29. West, A.R. (1984). Solid State Chemistry and its Applications, Ed. John Wiley & Sons, New York.
30. Burleigh, M.C., Markowitz, M.A., Spector, M.S. and Gaber, B.P. (2001). Amine-Functionalized Periodic Mesoporous Organosilicas, Chem. Mater., 13: 4760-4766.
31. Kopesky, E.T., Haddad, T.S., McKinley, G.H. and Cohen, R.E. (2005). Miscibility and Viscoelastic Properties of Acrylic Polyhedral Oligomeric Silsesquioxane-poly(methyl methacrylate) Blends, Polymer, 46: 4743-4752.
32. Kopesky, E.T., Haddad, T.S., Cohen, R.E. and McKinley, G.H. (2004). Thermomechanical Properties of Poly(methyl methacrylate)s Containing Tethered and Untethered Polyhedral Oligomeric Silsesquioxanes, Macromolecules, 37: 8992-9004.
33. Liu, H., Zheng, S. and Nie, K. (2005). Morphology and Thermomechanical Properties of Organic-Inorganic Hybrid Composites Involving Epoxy Resin and an Incompletely Condensed Polyhedral Oligomeric Silsesquioxane, Macromolecules, 38: 5088-5097.
34. Bharadwaj, R.K., Berry, R.J. and Farmer, B.L. (2000). Molecular Dynamics Simulation Study of norbornene-POSS polymers, Polymer, 41: 7209-7221.
35. Li G., Wang, L., Ni, H. and Pittman, C.U. (2001). Polyhedral Oligomeric Silsesquioxane (POSS) Polymers and Copolymers: A Review, J. Inorg. Organomet. Polym., 11: 123-154.
36. Xu, H.Y., Kuo, S.W., Lee, J.S. and Chang, F.C. (2002). Preparations, Thermal Properties, and Tg Increase Mechanism of Inorganic/Organic Hybrid Polymers Based on Polyhedral Oligomeric Silsesquioxanes, Macromolecules, 35: 8788-8793.
37. Romo-Uribe, A., Mather, P.T., Haddad, T.S. and Lichtenhan, J.D. (1998). Viscoelastic and Morphological Behavior of Hybrid Styryl-based Polyhedral Oligomeric Silsesquioxane (POSS) Copolymers, J. Polym. Sci. Part B: Polym. Phys., 36: 1857-1872.
38. Abad, M.J., Barral, L., Fasce, D.F. and Williams, R.J.J. (2003). Epoxy Networks Containing Large Mass Fractions of a Monofunctional Polyhedral Oligomeric Silsesquioxane (POSS), Macromolecules, 36: 3128-3135.
39. Cocca, M., d′Arienzo, L.D., D′Orazio, L., Gentile, G. and Martuscelli, E. (2004). Polyacrylates for Conservation: Chemico-physical Properties and Durability of Different Commercial Products, Polym. Test., 23: 333-342.