Diffusion of gaseous products through a particle surface layer in a fluidized bed reactor

International Journal of Heat and Mass Transfer

Volumn 53, Issue 11-12, 2010, Pages 2449-2458

  Daggupati, V N ^a   Naterer, G F ^a   Gabriel, K S ^a  

^a UNIVERSITY OF ONTARIO INSTITUTE OF TECHNOLOGY   (Canada)

Author keywords

Fluidized bed; Hydrogen production; Hydrolysis; Thermochemical copper chlorine cycle

Indexed keywords

CHEMICAL EQUILIBRIUMS; CUPRIC CHLORIDE; EXTERIOR SURFACES; FLUIDIZED BED REACTORS; GASEOUS PRODUCTS; GASEOUS REACTANTS; HEAT INPUT; HEAT REQUIREMENTS; HYDROGEN CHLORIDE; HYDROLYSIS REACTION; NEW RESULTS; OPERATING PARAMETERS; OPERATING PRESSURE; PARTICLE SURFACE; SCALE-UP; SHRINKING CORE MODEL; SOLID CONVERSION; SPHERICAL PARTICLE; STEAM SUPPLY; THERMOCHEMICAL COPPER-CHLORINE CYCLE; THERMOCHEMICAL CU-CL CYCLE; UNREACTED CORES; UPPER LIMITS;

CHEMICAL REACTORS; CHLORINE; CHLORINE COMPOUNDS; COPPER; COPPER COMPOUNDS; DIFFUSION; FLUID CATALYTIC CRACKING; FLUIDIZATION; FLUIDIZED BEDS; GAS PRODUCERS; GAS SUPPLY; HYDROLYSIS; INERT GASES; PHASE EQUILIBRIA; RATE CONSTANTS; SHRINKAGE; STEAM;

HYDROGEN PRODUCTION;

EID: 77649187440     PISSN: 00179310     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijheatmasstransfer.2010.01.039     Document Type: Article

References (23)

1. M.A. Lewis, M. Serban, J.K. Basco, Hydrogen production at <550 °C using a low temperature thermochemical cycle, ANS/ENS Exposition, New Orleans, November 2003.
2. M. Lewis, A. Taylor, High temperature thermochemical processes, DOE Hydrogen Program, Annual Progress Report, Washington, DC, 2006, pp. 182-185.
3. Kasahara S., Kubo S., Hino R., Onuki K., Nomura M., and Nakao S. Flow sheet study of the thermochemical water-splitting iodine-sulfur process for effective hydrogen production. Int. J. Hydrogen Energy 32 4 (2007) 489-496
4. M. Serban, M. Lewis, J. Basco, Kinetic study of the hydrogen and oxygen production reactions in the copper-chloride thermochemical cycle, in: AIChE Spring National Meeting, New Orleans, LA, April 25-29, 2004.
5. R.H. Carty, M. Mazumder, J.D. Schreider, J.B. Panborn, Thermochemical hydrogen production, GRI Report 80-0023, vol. 1, Gas Research Institute for the Institute of Gas Technology, Chicago, IL 60616, 1981.
6. Knoche K.F., Schuster P., and Ritterbex T. Thermochemical production of hydrogen by a vanadium/chlorine cycle. II: Experimental investigation of the individual reactions. Int. J. Hydrogen Energy 9 (1984) 473-482
7. Funk J.E. Thermochemical hydrogen production: past and present. Int. J. Hydrogen Energy 26 3 (2001) 185-190
8. Yildiz B., and Kazimi M.S. Efficiency of hydrogen production systems using alternative energy technologies. Int. J. Hydrogen Energy 31 (2006) 77-92
9. Reinhold M., Horst C., and Hoffmann U. Experimental and theoretical investigations of a spray dryer with simultaneous chemical reaction. Chem. Eng. Sci. 56 (2001) 1657-1665
10. Thybo P., Hovgaard L., Andersen S.K., and Lindelov J.S. Droplet size measurements for spray dryer scale-up. Pharm. Dev. Technol. 13 (2008) 93-104
11. Kocakusak S., Akcay K., Ayok T., Koroglu H.J., Koral M., Savasci O.T., and Tolun R. Production of anhydrous, crystalline boron oxide in fluidized bed reactor. Chem. Eng. Sci. 35 (1996) 311-317
12. Konttinen J.T., Zevenhoven C.A.P., and Hupa M.M. Modeling of sulfided zinc titanate regeneration in a fluidized bed reactor. 2. Scale-up of the solid conversion model. Ind. Eng. Chem. Res. 36 (1997) 5439-5446
13. Thurnhofer A., Schachinger M., Winter F., Mali H., and Schenk J.L. Iron ore reduction in a laboratory-scale fluidized bed reactor effect of pre-reduction on final reduction degree. ISI J Int. 45 2 (2005) 151-158
14. Cui H., Sauriol P., and Chaouki J. High temperature fluidized bed reactor: measurements, hydrodynamics and simulation. Chem. Eng. Sci. 58 3 (2003) 1071-1077
15. Fryer C., and Potter O.E. Experimental investigation of models for fluidized bed catalytic reactors. AIChE J. 22 (1976) 38-47
16. Grace J.R., and Sun G. Influence of particle size distribution on the performance of fluidized bed reactors. Can. J. Chem. Eng. 69 (1991) 1126-1134
17. Udhe G., and Hoffmann U. Noncatalytic gas-solid reactions: modeling of simultaneous reaction and formation of surface with a non-isothermal cracking core model. Chem. Eng. Sci. 52 (1997) 1045-1054
18. Levenspiel O. Chemical Reaction Engineering. third ed. (1998), John Wiley & Sons, New York
19. Dou B., Gao J., and Sha X. A study on the reaction kinetics of HCl removal from high temperature coal gas. Fuel Process. Technol. 72 (2001) 23-33
20. Lewis M.A., Masin J., and O'Hare P. Evaluation of alternative thermochemical cycles - part I. The methodology. Int. J. Hydrogen Energy 34 9 (2009) 4115-4124
21. Daggupati V.N., Naterer G.F., Gabriel K.S., Gravelsins R.J., and Wang Z.L. Equilibrium conversion in Cu-Cl cycle multiphase processes of hydrogen production. Thermochim. Acta 496 (2009) 117-123
22. Koretsky M.D. Engineering and Chemical Thermodynamics (2003), John Wiley & Sons, New York
23. M.S. Ferrandon, M.A. Lewis, D.F. Tatterson, R.V. Nankani, M. Kumar, L.E. Wedgewood, L.C. Nitsche, The hybrid Cu-Cl thermochemical cycle. I. Conceptual process design and H2A cost analysis. II. Limiting the formation of CuCl during hydrolysis, in: HA Annual Hydrogen Conference, Sacramento Convention Center, CA, USA, March 30-April 3, 2008.