Using nanoparticle-filled microcapsules for site-specific healing of damaged substrates: Creating a "repair-and-go" system

ACS Nano

Volumn 4, Issue 2, 2010, Pages 1115-1123

  Kolmakov, German V ^a   Revanur, Ravindra ^b   Tangirala, Ravisubhash ^b   Emrick, Todd ^b   Russell, Thomas P ^b   Crosby, Alfred J ^b   Balazs, Anna C ^a  

^a University of Pittsburgh   (United States)

^b UNIVERSITY OF MASSACHUSETTS   (United States)

Author keywords

Computer simulation; Cracks; Microcapsules; Nanoparticles; Surfaces

Indexed keywords

DAMAGED REGION; DAMAGED SUBSTRATES; FINITE TIME; HIGH VOLUME FRACTION; HYBRID COMPUTATIONAL; MICROCAPSULES; MICROCARRIERS; MICROSCOPIC CRACKS; PARTICLE DEPOSITIONS; SIMPLE SHEAR FLOW; SITE-SPECIFIC;

COMPUTATIONAL METHODS; COMPUTER SIMULATION; ENCAPSULATION; NANOPARTICLES; REPAIR; SHEAR FLOW; SUBSTRATES;

CRACKS;

EID: 77649106228     PISSN: 19360851     EISSN: 1936086X     Source Type: Journal    
DOI: 10.1021/nn901296y     Document Type: Conference Paper

References (38)

1. Verberg, R.; Dale, A. T.; Kumar, P.; Alexeev, A.; Balazs, A. C. Healing Substrates with Mobile Particle-Filled Microcapsules: Designing a 'Repair and Go' System. J. R. Soc. Interface 2007, 4, 349-357.
2. Breitenkamp, K.; Emrick, T. Novel Polymer Capsules from Amphiphilic Graft Copolymers and Ring-Opening Cross Metathesis. J. Am. Chem. Soc. 2003, 125, 12070-12071.
3. Lin, Y.; Skaff, H.; Emrick, T.; Dinsmore, A. D.; Russell, T. P. Nanoparticles at Liquid-Liquid Interfaces: Assembly, Displacement and Transport. Science 2003, 299, 226-229.
4. Boker, A.; He, J.; Emrick, T.; Russell, T. P. Self-Assembly of Nanoparticles at Interfaces. Soft Matter 2007, 3, 1231-1248.
5. Gupta, S.; Zhang, Q. L.; Emrick, T.; Balazs, A. C.; Russell, T. P. Entropy-Driven Segregation of Nanoparticles to Cracks: A Route to Self-Healing Systems. Nat. Mater. 2006, 5, 229-233.
6. Balazs, A. C.; Emrick, T.; Russell, T. P. Nanoparticle-Polymer Composites: Where Two Small Worlds Meet. Science 2006, 314, 1107-1110.
7. Revanur, R.; McCloskey, B.; Breitenkamp, K.; Freeman, B. D.; Emrick, T. Reactive Amphiphilic Graft Copolymer Coatings Applied to Poly(vinylidene fluoride) Ultrafiltration Membranes. Macromolecules 2007, 40, 3624-3630.
8. Berdichevsky, Y.; Khandurinab, J.; Guttmanb, A.; Loa, Y.-H. UV/Ozone Modification of Poly(dimethylsiloxane) Microfluidic Channels. Sens. Actuators, B 2004, 97, 402-408.
9. Mills, K. L.; Zhu, X. Y.; Takayama, S. C.; Thouless, M. D. The Mechanical Properties of a Surface-Modified Layer on Polydimethylsiloxane. J. Mater. Res. 2008, 23, 37-48.
10. Crosby, A. Private communication.
11. Buxton, G. A.; Verberg, R.; Jasnow, D; Balazs, A. C. Newtonian Fluid Meets an Elastic Solid: Coupling Lattice Boltzmann and Lattice Spring Models. Phys. Rev. E 2005, 71, 056707-56718
12. Alexeev, A.; Verberg, R.; Balazs, A. C. Designing Compliant Substrates to Regulate the Motion of Vesicles. Phys. Rev. Lett. 2006, 96, 148103.
13. Alexeev, A; Verberg, R.; Balazs, A. C. Modeling the Motion of Microcapsules on Compliant Polymeric Surfaces. Macromolecules 2005, 38, 10244-10260.
14. Alexeev, A.; Balazs, A. C. Designing Smart Systems To Selectively Entrap and Burst Microcapsules. Soft Matter 2007, 3, 1500-1505.
15. Usta, O. B.; Alexeev, A.; Balazs, A. C. Fork in the Road: Patterned Surfaces Direct Microcapsules to Make a Decision. Langmuir 2007, 23, 10887-10890.
16. Alexeev, A.; Verberg, R.; Balazs, A. C. Patterned Surfaces Segregate Compliant Microcapsules. Langmuir 2007, 23, 983-987.
17. Verberg, R.; Alexeev, A.; Balazs, A. C. Modeling the Release of Nanoparticles from Mobile Microcapsules. J. Chem. Phys. 2006, 125, 224712.
18. Usta, O. B.; Alexeev, A.; Zhu, G.; Balazs, A. C. Modeling Microcapsules That Communicate through Nanoparticles To Undergo Self-Propelled Motion. ACS Nano 2008, 2, 471-476.
19. Therriault, D; White, S. R.; Lewis, J. A. Chaotic Mixing in Three-Dimensional Microvascular Networks Fabricated by Direct-Write Assembly. Nat. Mater. 2003, 2, 265-271.
20. Stone, H. A.; Stroock, A. D.; Ajdari, A. Engineering Flows in Small Devices: Microfluidics Toward a Lab-on-a-Chip. Ann. Rev. Fluid Mech. 2004, 36, 381-411.
21. Dubreuil, F.; Elsner, N.; Fery, A. Elastic Properties of Polyelectrolyte Capsules Studied by Atomic-Force Microscopy and RICM. Eur. Phys. J. E 2003, 12, 215-221.
22. Elsner, N.; Kozlovskaya, V.; Sukhishvili, S. A.; Fery, A. pH-Triggered Softening of Crosslinked Hydrogen-Bonded Capsules. Soft Matter 2006, 2, 966-972.
23. Succi, S. The Lattice Boltzmann Equation for Fluid Dynamics and Beyond; Clarendon Press: Oxford, 2001.
24. Ladd, A. J. C.; Kinney, J. H.; Breunig, T. M. Deformation and Failure in Cellular Materials. Phys. Rev. E 1997, 55, 3271-3275.
25. Buxton, G. A.; Care, C. M.; Cleaver, D. J. A Lattice Spring Model of Heterogeneous Material with Plasticity. Modell. Simul. Mater. Sci. Eng. 2001, 9, 485-497.
26. Lallemand, P.; Luo, L.-S. Theory of the Lattice Boltzmann Method: Dispersion, Dissipation, Isotropy, Galilean Invariance, and Stability. Phys. Rev. E 2000, 61, 6546-6562.
27. Verberg, R; Yeomans, J. M.; Balazs, A. C. Modeling the Flow of Fluid/Particle Mixtures in Microchannels: Encapsulating Nanoparticles within Monodisperse Droplets. J. Chem. Phys. 2005, 123, 224706.
28. Szymchak, P.; Ladd, A. J. C. Boundary Conditions for Stochastic Solutions of the Convective-Diffusion Equations. Phys. Rev. E 2003, 68, 036704.
29. Ottinger, H. C. Stochastic Processes in Polymeric Fluids; Springer: Berlin, 1996.
30. Cali, A.; Succi, S.; Cancelliere, A.; Benzi, R.; Gramignani, M. Diffusion and Hydrodynamic Dispersion with the Lattice Boltzmann Method. Phys. Rev. A 1992, 45, 5771-5774.
31. Caruso, M. M.; Davis, D. A.; Shen, Q.; Odom, S. A.; Sottos, N. R.; White, S. R.; Moore, J. S. Mechanically-Induced Chemical Changes in Polymeric Materials. Chem. Rev. 2009, 109, 5755-5798.
32. Chen, X.; Dam, M. A.; Ono, K.; Mal, A; Shen, H; Nutt, S. R.; Sheran, K.; Wudl, F. A Thermally Re-mendable Cross-Linked Polymeric Material. Science 2002, 295, 1698-1702.
33. Cordier, P.; Tournilhac, F.; Soulie-Ziakovic, C.; Leibler, L. Self-Healing and Thermoreversible Rubber from Supramolecular Assembly. Nature 2008, 451, 977-980.
34. Amendola, V.; Meneghetti, M. Self-Healing at the Nanoscale. Nanoscale 2009, 1, 74-88.
35. Trask, R. S.; Williams, H. R.; Bond, I. P. Self-Healing Polymer Composites: Mimicking Nature to Enhance Performance. Bioinspiration Biomimetics 2007, 2, P1-P9.
36. Balazs, A. C. Modeling Self-Healing Materials. Mater. Today 2007, 10, 18-23.
37. Wool, R. A. Self-Healing Materials: A Review. Soft Matter 2008, 4, 400-418.
38. Wu, D. Y.; Meure, S; Solomon, D. Self-Healing Polymeric Materials: A Review of Recent Developments. Prog. Polym. Sci. 2008, 33, 479-522.