Preparation and properties of medium temperature membranes based on zirconium sulfophenylphosphate/sulfonated poly(phthalazinone ether sulfone ketone) for direct methanol fuel cells

Journal of Membrane Science

Volumn 351, Issue 1-2, 2010, Pages 50-57

  Li, Zhongfang ^a   Dong, Feilong ^a   Xu, Lijuan ^a   Wang, Suwen ^a   Yu, Xianjin ^a  

^a SHANDONG UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

Composite membrane; Direct methanol fuel cells; Medium temperature proton exchange membrane; Sulfonated poly(phthalazinone ether sulfone ketone); Zirconium sulfophenyl phosphate

Indexed keywords

MEDIUM TEMPERATURE; POLY(PHTHALAZINONE ETHER SULFONE KETONE); PROTON EXCHANGE MEMBRANES; SULFOPHENYL;

ATMOSPHERIC HUMIDITY; DIELECTRIC RELAXATION; DIRECT METHANOL FUEL CELLS (DMFC); ETHERS; GRAVIMETRIC ANALYSIS; HYDROGEN BONDS; INFRARED SPECTROSCOPY; KETONES; METHANOL; METHANOL FUELS; PROTON CONDUCTIVITY; PROTON EXCHANGE MEMBRANE FUEL CELLS (PEMFC); SCANNING ELECTRON MICROSCOPY; X RAY DIFFRACTION; X RAY DIFFRACTION ANALYSIS; X RAY SPECTROSCOPY; ZIRCONIUM;

COMPOSITE MEMBRANES;

METHANOL; POLY(PHTHALAZINONE ETHER SULFONE KETONE); POLYMER; UNCLASSIFIED DRUG; ZIRCONIUM SULFOPHENYL PHOSPHATE;

ARTICLE; ARTIFICIAL MEMBRANE; BIOFUEL PRODUCTION; CHEMICAL ANALYSIS; CONCENTRATION (PARAMETERS); CONTROLLED STUDY; CULTURE MEDIUM; HUMIDITY; HYDROGEN BOND; INFRARED SPECTROSCOPY; MEMBRANE COMPONENT; MEMBRANE PERMEABILITY; PRIORITY JOURNAL; PROTON TRANSPORT; SCANNING ELECTRON MICROSCOPY; SULFONATION; SYNTHESIS; TEMPERATURE DEPENDENCE; THERMOGRAVIMETRY; THERMOSTABILITY; X RAY DIFFRACTION; X RAY SPECTROMETRY;

EID: 77549087930     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2010.01.027     Document Type: Article

References (36)

1. 2 composite DMFC membranes: physico-chemical properties of the filler versus electrochemical performance. Electrochim. Acta 50 (2005) 1241-1246
2. Deivaraj T.C., and Lee J.Y. Preparation of carbon-supported PtRu nanoparticles for direct methanol fuel cell applications-a comparative study. J. Power Sources 142 (2005) 43-49
3. Hu Z.X., Yin Y., Okamoto K.-I., Moriyama Y., and Morikawa A. Synthesis and characterization of sulfonated polyimides derived from 2,2′-bis (4-sulfophenyl)-4, 4′-oxydianiline as polymer electrolyte membranes for fuel cell applications. J. Membr. Sci. 329 (2009) 146-152
4. DeLuca N.W., and Elabd Y.A. Polymer electrolyte membranes for the direct methanol fuel cell: a review. J. Polym. Sci. Part B: Polym. Phys. 44 16 (2006) 2201-2225
5. Silva V.S., Weisshaar S., Reissner R., Ruffmann B., Vetter S., Mendes A., Madeira L.M., and Nunes S. Performance and efficiency of a DMFC using non-fluorinated composite membranes operating at low/medium temperatures. J. Power Sources 145 (2005) 485-494
6. Alberti G., Casciola M., Massinelli L., and Bauer B. Polymeric proton conducting membranes for medium temperature fuel cells (110-160 °C). J. Membr. Sci. 185 (2001) 73-81
7. Pei H., Hong L., and Lee J.Y. Embedded polymerization driven asymmetric PEM for direct methanol fuel cells. J. Membr. Sci. 270 (2006) 169-178
8. Li L., and Wang Y. Sulfonated polyethersulfone cardo membranes for direct methanol fuel cell. J. Membr. Sci. 246 (2005) 167-172
9. Gao Y., Robertson G.P., Guiver M.D., Jian X., Mikhailenko S.D., Wang K., and Kaliaguine S. Sulfonation of poly(phthalazinones) with fuming sulfuric acid mixtures for proton exchange membrane materials. J. Membr. Sci. 227 (2003) 39-50
10. Jian X.G., Dai Y., Zheng L., and Xu R.X. Application of poly(phthalazinone ether sulfone ketone)s to gas membrane separation. J. Appl. Polym. Sci. 71 (1999) 2385-2390
11. Kim D.S., and Guiver M.D. Comparative effect of phthalazinone units in sulfonated poly(arylene ether ether ketone ketone) copolymers as proton exchange membrane materials. J. Polym. Sci. Part A: Polym. Chem. 46 (2008) 989-1002
12. Manea C., and Mulder M. Characterization of polymer blends of polyethersulfone/sulfonated polysulfone and polyethersulfone/sulfonated polyetheretherketone for direct methanol fuel cell applications. J. Membr. Sci. 206 (2002) 443-453
13. Zhang H.Q., Li X.F., Zhao C.J., Fu T.Z., Shi Y.H., and Na H. Composite membranes based on highly sulfonated PEEK and PBI: morphology characteristics and performance. J. Membr. Sci. 308 (2008) 66-74
14. Kerres J., Ulrich A., Meier F., and Haring T. Synthesis and characterization of novel acid-base polymer blends for application in membrane fuel cells. Solid State Ionics 125 (1999) 243-249
15. Deimede V., Voyiatzis G.A., Kallitsis J.K., Li Q.F., and Bjerrum N.J. Miscibility behavior of polybenzimidazole/sulfonated polysulfone blends for use in fuel cell applications. Macromolecules 33 (2000) 7609-7617
16. Cui W., Kerres J., and Eigenberger G. Development and characterization of ion-exchange polymer blend membranes. Sep. Purif. Technol. 14 (1998) 145-154
17. Silva V.S., Ruffmann B., Vetter S., Mendes A., Mandeira L.M., and Nunes S.P. Characterization and application of composite membranes in DMFCs. Catal. Today 104 (2005) 205-212
18. Chang J.H., Park J.H., Park G.G., Kim C.S., and Park O.O. Proton-conducting composite membrane derived from sulfonated hydrocarbon and inorganic materials. J. Power Sources 124 (2003) 18-25
19. Alberti G., Casciola M., and Palombari R. Inorgano-organic proton conducting membranes for fuel cells and sensors at medium temperatures. J. Membr. Sci. 172 (2000) 233-239
20. Stein Sr. E.W., Clearfield A., and Subramanian M.A. Conductivity of group IV metal sulfophosphonates and a new class of interstratified metal amine-sulfophosphonates. Solid State Ionics 83 (1996) 113-124
21. Krishnan P., Park J.S., Yang T.H., Lee W.Y., and Kim C.S. Sulfonated poly(ether ether ketone)-based composite membrane for polymer electrolyte membrane fuel cells. J. Power Sources 163 (2006) 2-8
22. Gu S., He G., Wu X., Li C., Liu H., Lin C., and Li X. Synthesis and characteristics of sulfonated poly(phthalazinone ether sulfone ketone) (SPPESK) for direct methanol fuel cell (DMFC). J. Membr. Sci. 281 (2006) 121-129
23. Vargas R.A., Garći{dotless}a A., and Wargas M.A. Phase behavior of complexes of PVA and acid salts. Electrochim. Acta 43 (1998) 1271-1274
24. Fontanella J.J., Wintersgill M.C., Wainrght J.S., Savinell R.F., and Litt M. High pressure electrical conductivity studies of acid doped polybenzimidazol. Electrochim. Acta 43 (1998) 1289-1294
25. 2O. Electrochim. Acta 44 (1999) 4227-4232
26. + cations. J. Electrochem. Soc. 145 (1998) 3798-3801
27. Carretta N., Tricoli V., and Picchioni F. Ionomeric membranes based on partially sulfonated poly(styrene): synthesis, proton conduction and methanol permeation. J. Membr. Sci. 166 (2000) 189-197
28. Pivovar B.S., Wang Y., and Cussler L. Pervaporation membranes in direct methanol fuel cells. J. Membr. Sci. 154 (1999) 155-162
29. Tricoli V., Carretta N., and Bartolozzi M. A comparative investigation of proton and methanol transport in fluorinated ionomeric membranes. J. Electrochem. Soc. 147 (2000) 1286-1290
30. Wang L., Meng Y.Z., Li X.H., Xiao M., Wang S.J., and Hay A.S. Oxidatively stable and highly proton conductive membrane from poly(arylene ether)s containing biphenyl moiety as pendent groups. J. Membr. Sci. 280 (2006) 108-115
31. Mohd Norddina M.N.A., Ismaila A.F., Ranab D., Matsuurab T., Mustafaa A., and Tabe-Mohammadic A. Characterization and performance of proton exchange membranes for direct methanol fuel cell: blending of sulfonated poly(ether ether ketone) with charged surface modifying macromolecule. J. Membr. Sci. 323 (2008) 404-413
32. Gu S., He G., Wu X., Guo Y., Liu H., Peng L., and Xiao G. Preparation and characteristics of crosslinked sulfonated poly(phthalazinone ether sulfone ketone) with poly(vinyl alcohol) for proton exchange membrane. J. Membr. Sci. 312 (2008) 48-58
33. Kim Y.T., Song M.K., Kim K.H., Park S.B., Min S.K., and Rhee H.W. Nafion/ZrSPP composite membrane for high temperature operation of PEMFCs. Electrochim. Acta 50 (2004) 645-648
34. Park Y.S., and Yamazaki Y. Low methanol permeable and high proton-conducting Nafion/calcium phosphate composite membrane for DMFC. Solid State Ionics 176 11/12 (2005) 1079-1089
35. Kauranen P.S., and Skou E. Methanol permeability in perfluorosulfonate proton-exchange membranes at elevated-temperatures. J. Appl. Electrochem. 26 (1996) 909-917
36. Chen D.Y., Wang S.J., Xiao M., and Meng Y.Z. Preparation and properties of sulfonated poly(fluorenyl ether ketone) membrane for vanadium redox flow battery application. J. Power Sources 195 (2010) 2089-2095