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Volumn 75, Issue 4, 2010, Pages 1119-1125

Intermediacy of eudesmane cation during catalysis by aristolochene synthase

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVE SITE; AMMONIUM IONS; BINDING AFFINITIES; BINDING MODES; CATALYZED SYNTHESIS; CHEMICAL EQUATIONS; CYCLIZATION REACTIONS; DE-RACEMIZATION; DIASTEREOMERIC EXCESS; DIPHOSPHATES; ENAMINES; FARNESYL DIPHOSPHATE; GERMACRENE; HYDROCHLORIDE SALTS; HYDROGEN BONDING INTERACTIONS; MACRO-CYCLIZATION; NMR MEASUREMENTS; PENICILLIUM ROQUEFORTI; REACTION TRANSFORMS; SESQUITERPENES; STEREO-SELECTIVE; SYNTHASES; SYNTHETIC SEQUENCE; TRANSITION-STATE ANALOGUES;

EID: 77249159870     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo902397v     Document Type: Article
Times cited : (21)

References (71)
  • 56
    • 77249149294 scopus 로고    scopus 로고
    • C14H26NCl, fw, 243.81, T, 150 K, λ, 0.71073 Å, orthorhombic, P21212 1, a, 6.7550(1) Å, b, 8.4270(2) Å, c, 25.7000(4) Å, V, 1462.96(5) Å3, Z, 4, ρ(cal, 1.107, size, 0.20 x 0.15 x 0.15 mm3, independent reflections, 3304, final R1, 0.042,wR2, 0.097, for I > 2σ(I).The datawere collected with use of graphite-monochromated Mo KR (λ, 0.710 73 Å) radiation at 150 K. The structures were solved by direct methods, using SHELXS-96, and refined with all data on F2 full-matrix least-squares, using SHELXL-97.57 All non-hydrogen atoms were refined anisotropically. Hydrogen atom positions were located from difference Fourier maps and a riding model with atomic displacement parameters 1.2 times (1.5 times for methyl groups) those of the atom to which the
    • 57 All non-hydrogen atoms were refined anisotropically. Hydrogen atom positions were located from difference Fourier maps and a riding model with atomic displacement parameters 1.2 times (1.5 times for methyl groups) those of the atom to which they are bonded was used for subsequent refinements.
  • 59
    • 77249155085 scopus 로고    scopus 로고
    • 13C (125 MHz) NMR analysis revealed that this sample was composed of 95% cis- (16) and 5% trans-decahydroquinoline (14).
    • 13C (125 MHz) NMR analysis revealed that this sample was composed of 95% cis- (16) and 5% trans-decahydroquinoline (14).
  • 69
    • 77249138181 scopus 로고    scopus 로고
    • PPi on its own is not an inhibitor of PR-AS. For details see ref 1
    • i on its own is not an inhibitor of PR-AS. For details see ref 1.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.