Copper substitution alone and in the presence of chromium, zinc, cadmium and lead in goethite (a-FeOOH)

Clay Minerals

Volumn 44, Issue 3, 2009, Pages 293-310

  Kaur, N ^a   Singh, B ^a   Kennedy, B J ^b  

^a UNIVERSITY OF SYDNEY   (Australia)

^b UNIVERSITY OF SYDNEY   (Australia)

Author keywords

Dehydroxylation temperature; Dissolution; Goethite; Ion substitution; Rietveld refinement; Synchrotron XRD; TEM

Indexed keywords

DEHYDROXYLATION TEMPERATURE; DEHYDROXYLATIONS; ION SUBSTITUTION; TEM; XRD;

CHROMIUM; DISSOLUTION; HEMATITE; IRON ORES; LEAD; METAL RECOVERY; METALS; OXIDE MINERALS; RIETVELD METHOD; RIETVELD REFINEMENT; SYNCHROTRONS; X RAY DIFFRACTION; ZINC;

CADMIUM;

CADMIUM; CHROMIUM; DISSOLUTION; GOETHITE; HEMATITE; LEAD; RIETVELD ANALYSIS; SUBSTITUTION; X-RAY DIFFRACTION; ZINC;

EID: 77249144953     PISSN: 00098558     EISSN: 14718030     Source Type: Journal    
DOI: 10.1180/claymin.2009.044.3.293     Document Type: Article

References (23)

1. Cornell R.M. (1988) The influence of some divalent cations on the transformation of ferrihydrite to more crystalline products. Clay Minerals, 23, 329-332.
2. 2O) into crystalline products in alkaline media. Polyhedron, 7, 385-391.
3. Cornell R.M., Posner A.M. & Quirk J.P. (1974) Crystal morphology and the dissolution of goethite. Journal of Inorganic and Nuclear Chemistry, 36, 1937-1946.
4. Dudka S. & Adriano D.C. (1997) Environmental impacts of metal ore mining and processing: a review. Journal of Environmental Quality, 26, 590-602.
5. Dunitz J.D. & Orgel L.E. (1957) Electronic properties of transition-metal oxides-I Distortions from cubic symmetry. Journal of Physics and Chemistry of Solids, 3, 20-29.
6. Gerth J. (1990) Unit cell dimensions of pure and trace metal-associated goethites. Geochimica et Cosmochimia Acta, 54, 363-371.
7. Hunter B.A. (1997) Rietica for Windows v. 1.7.7. ANSTO, Sydney, Australia.
8. Huynh T., Tong A.R., Singh B. & Kennedy B.J. (2002) Studies of synthetic copper containing goethite. Paper no. 1545 in: 17th World Congress of Soil Science, Bangkok, Thailand, 14-20 August 2002, Soil and Fertilizer Society of Thailand.
9. Inouye K., Ishikawa T., Ishii S. & Kaneko K. (1972a) Effect of copper(II) on crystallization of alpha- FeOOH. Zeitschrift Fur Anorganische Und Allgemeine Chemie, 391, 86-87.
10. Inouye K., Ishikawa T. & Hozumi T. (1972b) Effect of copper(II) ions on magnetite formation of mixture of ferrous and ferric hydroxide. Kolloid-Zeitschrift and Zeitschrift Fur Polymere, 250, 262-267.
11. 2- at pH 6.5 and 8.5 on transformations of hydrous ferric oxide (HFO) as evidenced by Mössbauer spectroscopy. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 221, 55-68.
12. Kabai J. (1973) Determination of specific activation energies of metal oxides and metal oxide hydrates by measurement of the rate of dissolution. Acta Chimica Academiae Scientiarum Hungaricae, 78, 57-73.
13. Kaur N., Grafe M., Singh B. & Kennedy B.J. (2009) Simultaneous incorporations of Cr, Zn, Cd and Pb in the goethite structure. Clays and Clay Minerals, 57, 234-250.
14. Kaur N., Singh B. & Kennedy B.J. (2010) Dissolution of Cr, Cd, Zn and Pb single- and multi-metal substituted goethite; relation to structural and morphological properties. Clays and Clay Minerals, (in press).
15. Krehula S. & Music S. (2007) Influence of copper ions on the precipitation of goethite and hematite in highly alkaline media. Journal of Molecular Structure, 834, 154-161.
16. Lim-Nunez R. & Gilkes R.J. (1987) Acid dissolution of synthetic metal containing goethites and hematites. Pp. 197-204 in: Proceedings of the International Clay Conference, Denver, USA, 1985.
17. Martinez C.E. & McBride M.B. (1998) Coprecipitates of Cd, Cu, Pb and Zn in iron oxides: solid phase transformation and metal solubility after aging and thermal treatment. Clays and Clay Minerals, 46, 537-545.
18. Rietveld H.M. (1969) A profile refinement method for nuclear and magnetic structures. Journal of Applied Crystallography, 2, 65-71.
19. Schwertmann U. (1984) The double dehydroxylation peak of goethite. Thermochimica Acta, 78, 39-46.
20. Schwertmann U., Gasser U. & Sticher H. (1989) Chromium-for-iron substitution in synthetic goethites. Geochimica et Cosmochimica Acta, 53, 1293-1297.
21. Sultan K. (2006) Clay mineralogy of Central Victorian (Creswick) soils: clay mineral contents as a possible tool of environmental indicator. Soil & Sediment Contamination, 15, 339-356.
22. Szytula A., Burewicz A., Dimitrijevic Z., Krasnicki S., Rzany H., Todorovic J., Wanic A. & Wolski W. (1968) Neutron diffraction studies of a-FeOOH. Physica Status Solidi, 26, 429-434.
23. Wilcox D., Dove B., McDavid D. & Greer D. (1995) UTHSCASA Image Tool for Windows. The University of Texas Health Science Centre, San Antonio, Texas, USA.