Bioenrgy II: Tin catalysed esterification of free fatty acids

International Journal of Chemical Reactor Engineering

Volumn 8, Issue , 2010, Pages

  Da Silva, Marcio Jose ^a   Cardoso, Abiney Lemos ^a   Natalino, Ricardo ^a  

^a University Federal of Viçosa   (Mexico)

Author keywords

Biodiesel; Free fatty acids; Tin chloride

Indexed keywords

ASSOCIATION REACTIONS; BIODIESEL; CATALYST ACTIVITY; ESTERS; SATURATED FATTY ACIDS; TIN COMPOUNDS;

ACID CATALYST; AEROBIC CONDITION; CARBON-CHAIN LENGTH; DIHYDRATES; ESTERIFICATION OF FREE FATTY ACIDS; ETHANOLYSIS; FREE FATTY ACID; LEWIS ACID CATALYSTS; MINERAL ACID; ]+ CATALYST;

CHLORINE COMPOUNDS;

EID: 77249121578     PISSN: 21945748     EISSN: 15426580     Source Type: Journal    
DOI: None     Document Type: Article

References (28)

1. Aranda, D.A.G., Einloft, S., Magalhães, T. O., Dullius, J., Ligabue, R., 2008. Biodiesel from Rice Bran Oil: Transesterification by Tin Compounds Energ. Fuel, 22, 671-675
2. Bruce, D.A., Goodwin Jr, J.G., Liu, Y., Lopez, E. 2005. Synthesis of Biodiesel via Acid Catalysis, Indus. Eng. Chem. Res., 44, 5353-5363.
3. Corma, A., Garcia, H., 2003. Lewis acids: from conventional homogeneous to green homogeneous and heterogeneous catalysis, Chem Ver., 103, 4307-4365.
4. Demyrbas, A. 2008. Comparison of transesterification methods for production of biodiesel from oils and fats. Energ. Convers. Manage 49, 125-130.
5. Furuta, S., Matsuhashi, H., Arata, K., 2006. Biodiesel fuel production with solid amorphous-zirconia catalysis in fixed bed reactor. Biomass Bioenerg. 30, 870-873.
6. Kiss, A.A., Omota, F., Dimian, A., Rothenberg, G., 2006. The heterogeneous advantage: biodiesel by catalytic reactive distillation, Topics in Catal. 40 (1-4), 141-150.
7. Kiss, A.A., Dimian, A.C., Rothenberg, G. 2006. Solid Acid Catalysts for Biodiesel Production - Towards Sustainable Energy, Adv. Synth. Catal 348, 75-81.
8. Kiss A.A., A.C. Dimian, G. Rothenberg, Biodiesel by Reactive Distillation Powered by Metal Oxides, Energ. Fuels, 22 (2008), 598-604.
9. Kulkarni, M.G., Gopinath, R., Meher, L.C., Dalai, A.K., 2006. Solid acid catalyzed biodiesel production by simultaneous esterification and transesterification. Green Chem. 8, 1056-1062.
10. Lotero E., Liu Y., Lopez D.E., Suwannakarn, K., Bruce, D.A., Goodwin, J.G., 2005. Synthesis of biodiesel via acid catalysis. Ind. Eng. Chem. Res.44, 25353-25363.
11. Maa, F., Hannab M.A., 1999. Biodiesel production - A Review. Bioresour. Technol. 70, 1-15.
12. Marchetti, J.M., Miguel, V.U., Errazu A.F., 2007. Heterogeneous esterification of oil with high amount of free fatty acids. Fuel 86, 906-910.
13. Meneghetti, S.M.P., Ferreira, D.A.C., Meneghetti, M.R., Wolf, C.R., 2007. Methanolysis of soybean oil in the presence of tin(IV) complexes. Appl. Catal. A 317, 58-61.
14. Narasimharao, K., Lee, A., Wilson, K.2007. Catalysts in Production of Biodiesel: A Review. J. Biob. Mat. Bioenerg. 1, 19-30.
15. Pasias, S., Barakos, N., Alexpoulos, C., Papayannakos, N., 2006. Heterogeneously catalyzed esterification of FFAs in vegetable oils. Chem. Eng. Technol. 29, 1365-1371.
16. Rodrigues Jr., J.A., Reis, S.C.M., Lachter, E.R.R., Nascimento, R.S.V., Reid, M.G. 2005. Transesterification of brazilian vegetable oils with methanol over ionexchange. J. Am. Oil Chem. Soc. 82, 661-665.
17. Russbueldt, B.M.E, Hoelderich, W.F. 2009. New sulfonic acid ion-exchange resins for the preesterification of different oils and fats with high content of free fatty acids. Applied Catal. A: 362, 47-57.
18. Santacesaria, E., Dimiccoli, M.T., Tesser, R., Di Serio, M., Cammarota, F., Nastasi, M., 2005. Synthesis of biodiesel via homogeneous Lewis acid catalyst J. Mol. Catal. A 239, 111-115.
19. da Silva, M.J., Lemos, A.C., Neves, S.C.G., 2008. Esterification of Oleic Acid for Biodiesel Production Catalyzed by SnCl2: A Kinetic Investigation, Energies 1, 79-92.
20. da Silva, M.J., Augusti, R. 2008. Investigation on the esterification of fatty acids catalyzed by the H3PW12O40 heteropolyacid. J. Am Oil Chem Soc. 85, 555-560.
21. da Silva, M.J., Lemos, A.C., Neves, S.C.G., 2009. Alcoholysis of fatty acids catalyzed by tin chloride, Energ. Fuels, in press.
22. Sreeprasanth, P.S., Srivastava,R., Srinivas,D., Ratnasamy, P., 2006. Hydrophobic, solid acid catalysts for production of biofuels and lubricants Appl. Catal. A, 314, 148-159.
23. Suarez, P.A.Z., Abreu, F.R., Lima, D.G., Hamú, E.H., Einloft, S., Rubim, J., 2003. New metal catalyst for soybean oil transesterification J. Am. Oil Chem. Soc. 80, 601-604.
24. Suarez, P.A.Z., Abreu, F.R., Lima, D.G., Hamú, E.H., Wolf, C., 2004. Utilization of metal complexes as catalysts in the transesterification of Brazilian vegetable oils with different alcohols, J. Mol. Catal. A: 209, 29-33.
25. Suarez, P.A.Z., Macedo, C.C.S., Abreu, F.R., Tavares, A.P., Alves, M.B., Zara, L.F., Rubim, J.C., 2006. New heterogeneous metal-oxides based catalyst for vegetable oil transesterification. J. Braz. Chem. Soc., 17, 1291-1296.
26. Tanabe, Y., Wakasugi, K., Misaki, T., Yamada, K., 2000. DPAT: Active catalyst for equimolar esterification. Tetrahedron Lett. 41, 5249-5252.
27. Zabeti, M., Wan Daud, W.M.A., Aroua, M.K. 2009. Activity of solid catalysts for biodiesel production: A review, Fuel Proces. Technol. 90 (6), 770-777.
28. Zullaikah, S., Lai, C.C., Vali, S.R., Ju, Y.H., 2005. A two-step acid-catalyzed process for the production of biodiesel from rice bran oil. Bioresour. Technol. 96, 1889-1896.