Evidence for the formation of cobalt porphyrin-quinone complexes stabilized at carbon-based surfaces toward the design of efficient non-noble-metal oxygen reduction catalysts

Journal of Physical Chemistry Letters

Volumn 1, Issue 1, 2010, Pages 398-401

  Elbaz, L ^a   Korin, E ^a   Soifer, L ^a   Bettelheim, A ^a  

^a BEN GURION UNIVERSITY OF THE NEGEV   (Israel)

Author keywords

Catalysis; Interfaces; Surfaces

Indexed keywords

AEROGEL CARBON; CARBON STRUCTURES; CARBON-BASED; CATALYTIC ELECTRODES; CHARGE TRANSFER COMPLEX; COBALT ION; COBALT PORPHYRINS; DEPTH PROFILE; FILM LAYERS; INTERFACES; METALLOPORPHYRINS; OUTER LAYER; OXYGEN REDUCTION; OXYGEN REDUCTION CATALYSTS; Q BANDS; QUINONE COMPLEXES; RED SHIFT; SORET BANDS; UV VISIBLE SPECTROSCOPY;

ADSORPTION; CARBON FILMS; CATALYSIS; COBALT COMPOUNDS; COMPLEXATION; ELECTROLYTIC REDUCTION; ELECTRONIC STRUCTURE; FUEL CELLS; GLASSY CARBON; METAL FUELS; OXYGEN; PHENOLS; PHOTOIONIZATION; PHOTONS; PORPHYRINS; PRECIOUS METALS; ULTRAVIOLET SPECTROSCOPY; X RAY PHOTOELECTRON SPECTROSCOPY;

COBALT;

EID: 77149178045     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz900310c     Document Type: Article

References (20)

1. Alonso, C. M. A.; Neves, M. G. P. M. S.; Tome, A. C.; Silva, A. M. S.; Cavaleiro, J. A. S. Reaction of (2-Amino-5,10,15,20-tetraphenylporphyrinato)nickel(II) with Quinones. Tetrahedron 2005,61,11866-11872.
2. Speck, M.; Niethammer, D.; Senge, M. O. Isomeric Porphyrin Phenanthrenequinones: Synthesis, NMR Spectroscopy, Electrochemical Properties, And in Situ EPR/ENDOR Studies of the o-Semiquinone Anion Radicals. J. Chem. Soc., Perkin Trans. 2 2002, 3, 455-462.
3. Hayashi, T.; Ogoshi, H. Molecular Modeling of Electron Transfer Systems by Noncovalently Linked Porphyrin-Acceptor Pairing. Chem. Soc. Rev. 1997, 26, 355-364.
4. Castro, C. E.; Hathaway, G. M.; Havlin, R. Oxidation and Reduction of Iron Porphyrins and Hemoproteins by Quinones and Hydroquinones. J. Am. Chem. Soc. 1977, 99, 8032-8039.
5. Kessel, S. L.; Hendrickson, D. N. Binuclear Ferric Porphyrins Bridged by the Dianions of Hydroquinones. Inorg. Chem. 1980,19,1883-1889.
6. Backvall, J.-E.; Hopkins, R. B.; Grennberg, H.; Mader, M. M.; Awasthi, A. K. Multistep Electron Transfer in PalladiumCatalyzed Aerobic Oxidations via a Metal Macrocycle-Quinone System. J. Am. Chem. Soc. 1990, 112, 5160-5166.
7. Hill, H. A. O.; Macfarlane, A. J.; Mann, B. E.; Williams, R. J. P. Molecular Complexes of Vitamin K3 with a Porphyrin and Chlorophyll. Chem. Commun. 1968, 3, 123-124.
8. Hill, H. A. O.; Macfarlane, A. J.; Williams, R. J. P. Molecular Complexes of Porphyrins. J. Chem. Soc. A 1969, 11, 1704-1707.
9. Ford, L.; Hill, H.A.O.; Mann, B.E.; Sadler, P.J.; Williams, R.J.P. Nuclear Magnetic Resonance Spectroscopy of Cobalt(II) Porphyrin-Quinone Complexes. Biochim. Biophys. 1976, 430,413-418.
10. Nakanishi, I.; Fukuzumi, S.; Barbe, J.-M.; Guilard, R.; Kadish, K. M. Base Control of Electron-Transfer Reactions of Manganese(III) Porphyrins. Eur. J. Inorg. Chem. 2000, 7, 1557-1562.
11. A Al-Muhtaseb, S. A.; Ritter, J. A. Preparation and Properties of Resorcinol-Formaldehyde Organic and Carbon Gels. Adv. Mater. 2003, 15, 101-114.
12. L Elbaz, L.; Korin, E.; Soifer, L.; Bettelheim, A. Electrocatalytic Oxygen Reduction by Co(III) Porphyrins Incorporated in Aerogel Carbon Electrodes. J. Electroanal. Chem. 2008, 621, 91-96.
13. Elbaz, L.; Korin, E.; Soifer, L.; Bettelheim, A. Mediation at High Potentials for the Reduction of Oxygen to Water by Cobalt Porphyrin-Quinone Systems in Porous Aerogel Carbon Electrodes. J. Electrochem. Soc. 2010, 157, B27-B31.
14. Bettelheim, A.; White, B. A.; Raybuck, S. A.; Murray, R. W. Electrochemical Polymerization of Amino-, Pyrrole-, and Hydroxy-Substituted Tetraphenylporphyrins. Inorg. Chem. 1987,26,1009-1017.
15. Harada, R.; Matsuda, Y.; Okawa, H.; Kojima, T. A Porphyrin Nanotube: Size-Selective Inclusion of Tetranuclear Molybdenum-Oxo Clusters. Angew. Chem. 2004, 43, 1825-1828.
16. Artyushkova, K.; Pylypenko, S.; Olson, T. S.; Fulghum, J. E.; Atanassov, P. Predictive Modeling of Electrocatalyst Structure Based on Structure-to-Property Correlations of X-ray Photoelectron Spectroscopic and Electrochemical Measurements. Langmuir 2008, 24, 9082-9088.
17. Flechtner, K.; Kretschmann, A.; Steinruck, H.-P.; Gottfried, J. M. NO-Induced Reversible Switching of the Electronic Interaction between a Porphyrin-Coordinated Cobalt Ion and a Silver Surface. J. Am. Chem. Soc. 2007, 129, 12110-12111.
18. Han, S. W.; Joo, S. W.; Ha, T. H.; Kim, Y.; Kim, K. Adsorption Characteristics of Anthraquinone-2-carboxylic Acid on Gold. J. Phys. Chem. B 2000, 104, 11987-11995.
19. Terekhov, S. N.; Kruglik, S. G.; Malinovskii, V. L.; Galievsky, V. A.; Chirvony, V. S.; Turpin, P.-y. Resonance Raman Characterization of Cationic Co(II) and Co(III) Tetrakis(N-methyl4-pyridinyl)porphyrins in Aqueous and Non-Aqueous Media. J. Raman Spectrosc. 2003, 34, 868-881.
20. Collman, J. P.; Wagenknecht, P. S.; Hutchison, J. E. Cofacial Bis(metallo)diporphyrins as Potential Molecular Catalysts for Multielectron Reductions and Oxidations of Small Molecules. Angew. Chem. 1994, 106, 1620-1639.