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26
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77149128575
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We were not able to isolate or detect aldehydes resulting from isomerization of the starting (epoxy-allyl)silane
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We were not able to isolate or detect aldehydes resulting from isomerization of the starting (epoxy-allyl)silane.
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27
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0001501433
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77149126314
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B. Rickborn in Comprehensive Organic Synthesis Carbon-Carbon α-Bond Formation (Ed.: G. Pattenden), Pergamon Press, Oxford, 1991, 3, p. 733.
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b) B. Rickborn in Comprehensive Organic Synthesis Carbon-Carbon α-Bond Formation (Ed.: G. Pattenden), Pergamon Press, Oxford, 1991, vol. 3, p. 733.
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A. Barbero, Y. Blanco, C. García, F. J. Pulido, Synthesis 2000, 1223-1228.
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0035966223
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Y. Kita, A. Furukawa, J. Futamura, K. Ueda, Y. Sawama, H. Hamamoto, F. Fujioka, J. Org. Chem. 2001, 66, 8779-8786.
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34
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0001373492
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Products of epoxide rearrangement have been obtained in a similar cyclization reaction: X.-Y. Xiao, S.-K. Park, G. D. Prestwich, J. Org. Chem. 1988, 53, 4869-4872.
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Products of epoxide rearrangement have been obtained in a similar cyclization reaction: X.-Y. Xiao, S.-K. Park, G. D. Prestwich, J. Org. Chem. 1988, 53, 4869-4872.
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38
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77149131762
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None of the direct 5-exo or 6-endo epoxy-cyclization products (see Scheme 4) were observed.
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None of the direct 5-exo or 6-endo epoxy-cyclization products (see Scheme 4) were observed.
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39
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77149168370
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M. J. Frisch, G. W. Trucks, H. B. Schlegel, G. E. Scuseria, M. A. Robb, J. R. Cheeseman, V. G. Zakrzewski, J. A. Montgomery, R. E. Stratmann, J. C. Burant, S. Dapprich, J. M. Millam, A. D. Daniels, K. N. Kudin, M. C. Strain, O. Farkas, J. Tomasi, V. Barone,M. Cossi, R. Cammi, B.Mennucci, C. Pomelli, C. Adamo, S. Clifford, J. Ochterski, G. A. Petersson, P. Y. Ayala, Q. Cui, K. Morokuma, D. K. Malick, A. D. Rabuck, K. Raghavachari, J. B. Foresman, J. Cioslowski, J. V. Ortiz, B. B. Stefanov, G. Liu, A. Liashenko, P. Piskorz, I. Komaromi, R. Gomperts, R. L. Martin, D. J. Fox, T. Keith, M. A. Al-Laham, C. Y. Peng, A. Nanayakkara, C. Gonzalez, M. Challacombe, P. M. W. Gill, B. G. Johnson, W. Chen, M. W. Wong, J. L. Andres, M. Head-Gordon, E. S. Replogle, J. A. Pople, Gaussian 98 (Revision A.7, Gaussian, Inc, Pittsburgh, PA, 1998. Theoretical level: MP2(fc)/3-21G*//HF/3-21G*
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