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Volumn 48, Issue 3, 2010, Pages 198-204

EPR/Spin-trapping study of free radical intermediates in the photolysis of trifluoromethyl ketones with initiators

Author keywords

EPR; Irradiation; Photolysis; Spin adduct; Spin trap; Trifluoromethyl ketones

Indexed keywords

ABSTRACTING; CHAINS; ELECTRON SPIN RESONANCE SPECTROSCOPY; FREE RADICALS; KETONES; PARAMAGNETIC RESONANCE; PHOTOLYSIS;

EID: 77149169121     PISSN: 07491581     EISSN: 1097458X     Source Type: Journal    
DOI: 10.1002/mrc.2566     Document Type: Article
Times cited : (11)

References (27)
  • 3
    • 0001596517 scopus 로고
    • Ed: W. A. Pryor, Academic Press: New York
    • E. G. Janzen, in Free Radicals in Biology, vol. 4 (Ed: W. A. Pryor), Academic Press: New York, 1980, pp 116.
    • (1980) Free Radicals in Biology , vol.4 , pp. 116
    • Janzen, E.G.1
  • 9
    • 0004032955 scopus 로고
    • ch. 7, Ed, J. K. Kochi, Wiley-Interscience: New York
    • G. A. Rusell, in Free Radicals, ch. 7, vol. 1, (Ed.: J. K. Kochi, Wiley-Interscience: New York, 1973.
    • (1973) Free Radicals , vol.1
    • Rusell, G.A.1
  • 11
    • 0042791782 scopus 로고
    • Substituent Effects in Radical Chemistry
    • H. G. Viehe, Z. Janousek, R. Merényi, Eds, D. Reidel Publishing Co, New York
    • H. G. Viehe, Z. Janousek, R. Merényi, Eds. Substituent Effects in Radical Chemistry, NATO ASI Series, D. Reidel Publishing Co.: New York, 1986.
    • (1986) NATO ASI Series
  • 18
    • 0012316435 scopus 로고    scopus 로고
    • WINSIM program was provided by, National Institute of Environmental Health Sciences, Bethesda MD
    • WINSIM program was provided by D. Dulog, Public EPR Software Tools, National Institute of Environmental Health Sciences, Bethesda MD 1996.
    • (1996) Public EPR Software Tools
    • Dulog, D.1
  • 21
    • 85164051843 scopus 로고    scopus 로고
    • Trifluoromethyl radical was first trapped from photolysis of trifluoroiodomethane in benzene in the presence of phenyl-tert-butylnitrone PBN, E. G. Janzen, B. J. Blackburn, J. Am. Chem. Soc. 1968, 90, 5909;
    • Trifluoromethyl radical was first trapped from photolysis of trifluoroiodomethane in benzene in the presence of phenyl-tert-butylnitrone (PBN) (E. G. Janzen, B. J. Blackburn, J. Am. Chem. Soc. 1968, 90, 5909;
  • 22
    • 85164052751 scopus 로고
    • J.Klabunde
    • or in the presence of 2-nitroso-2-methylpropane (MNP) as spin trap K
    • or in the presence of 2-nitroso-2-methylpropane (MNP) as spin trap K. J.Klabunde, J. Am. Chem. Soc. 1970, 92, 2427;
    • (1970) J. Am. Chem. Soc , vol.92 , pp. 2427
  • 23
    • 85164044162 scopus 로고    scopus 로고
    • Trifluoromethyl radical was also detected in gas-phase by photolysis of 1,1,1-trifluoroacetone in the presemce of PBN E. G. Janzen, I. G. Lopp, T. V. Morgan, J. Phys. Chem. 1973, 77, 139.
    • Trifluoromethyl radical was also detected in gas-phase by photolysis of 1,1,1-trifluoroacetone in the presemce of PBN E. G. Janzen, I. G. Lopp, T. V. Morgan, J. Phys. Chem. 1973, 77, 139.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.