Does Brillouin light scattering probe the primary glass transition process at temperatures well above glass transition?

Journal of Chemical Physics

Volumn 132, Issue 7, 2010, Pages

  Voudouris, P ^a   Gomopoulos, N ^b   Le Grand, A ^c   Hadjichristidis, N ^d   Floudas, G ^e   Ediger, M D ^f   Fytas, G ^a,b  

^a UNIVERSITY OF CRETE   (Greece)

^b MAX PLANCK INSTITUTE FOR POLYMER RESEARCH   (Germany)

^c Domaine Universitaire   (France)

^d UNIVERSITY OF ATHENS   (Greece)

^e UNIVERSITY OF IOANNINA   (Greece)

^f UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ARRHENIUS; BRILLOUIN LIGHT SCATTERING; BULK POLYMER; CHARACTERISTIC RELAXATION TIME; DEPOLARIZED LIGHT SCATTERING; EXPONENTIAL DECAYS; FITTING PROCEDURE; GIGAHERTZ FREQUENCIES; GLASS FORMER; GLASS TRANSITION DYNAMICS; GLASS TRANSITION TEMPERATURE; GLASS-FORMING SYSTEMS; HIGH TEMPERATURE; LONGITUDINAL MODULUS; MOLECULAR DYNAMICS SIMULATIONS; O-TERPHENYL; ORDER OF MAGNITUDE; PHONON DISPERSIONS; RELAXATION TIME DISTRIBUTION; TEMPERATURE DEPENDENT; TORSIONAL AUTOCORRELATION FUNCTION; TWO RELAXATION TIME; VOGEL-FULCHER-TAMMANN EQUATION; WAVE VECTOR;

BRILLOUIN SCATTERING; DISPERSION (WAVES); DISTRIBUTION FUNCTIONS; MOLECULAR DYNAMICS; PHOTON CORRELATION SPECTROSCOPY; POLYMERIC GLASS; PROBES; REFRACTION; REGRESSION ANALYSIS; RELAXATION TIME; SCATTERING;

GLASS TRANSITION;

1,4 POLYISOPRENE; 1,4-POLYISOPRENE; GLASS; HEMITERPENE; LATEX; POLYMER; POLYPROPYLENE; TERPHENYL DERIVATIVE;

ARTICLE; CHEMICAL MODEL; CHEMISTRY; INSTRUMENTATION; METHODOLOGY; MOLECULAR DYNAMICS; MOLECULAR WEIGHT; SPECTROSCOPY; STEREOISOMERISM; TRANSITION TEMPERATURE;

GLASS; HEMITERPENES; LATEX; MODELS, CHEMICAL; MOLECULAR DYNAMICS SIMULATION; MOLECULAR WEIGHT; POLYMERS; POLYPROPYLENES; SPECTRUM ANALYSIS; STEREOISOMERISM; TERPHENYL COMPOUNDS; TRANSITION TEMPERATURE;

EID: 77149168474     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.3319687     Document Type: Article

References (34)

1. A. P. Sokolov, Science SCIEAS 0036-8075 273, 1675 (1996). 10.1126/science.273.5282.1675
2. M. D. Ediger, C. A. Angell, and S. R. Nagel, J. Phys. Chem. JPCHAX 0022-3654 100, 13200 (1996). 10.1021/jp953538d
3. V. N. Novikov and A. P. Sokolov, Nature (London) NATUAS 0028-0836 431, 961 (2004). 10.1038/nature02947 (Pubitemid 39434412)
4. G. Floudas, G. Fytas, and I. Alig, Polymer POLMAG 0032-3861 32, 2307 (1991). 10.1016/0032-3861(91)90065-Q (Pubitemid 21708750)
5. N. J. Tao, G. Li, and H. Z. Cummins, Phys. Rev. B PRBMDO 0163-1829 43, 5815 (1991). 10.1103/PhysRevB.43.5815
6. C. Dreyfus, M. J. Lebon, H. Z. Cummins, J. Toulouse, B. Bonello, and R. M. Pick, Phys. Rev. Lett. PRLTAO 0031-9007 69, 3666 (1992). 10.1103/PhysRevLett. 69.3666
7. G. Monaco, D. Fioretto, L. Comez, and G. Ruocco, Phys. Rev. E PLEEE8 1063-651X 63, 061502 (2001). 10.1103/PhysRevE.63.061502
8. C. Dreyfus, M. J. Lebon, F. Vivicorsi, A. Aouadi, R. M. Pick, and H. Z. Cummins, Phys. Rev. E PLEEE8 1063-651X 63, 041509 (2001). 10.1103/PhysRevE.63. 041509
9. A. Brodin, M. Frank, S. Wiebel, G. Q. Shen, J. Wuttke, and H. Z. Cummins, Phys. Rev. E PLEEE8 1063-651X 65, 051503 (2002). 10.1103/PhysRevE.65.051503
10. N. J. Tao, G. Li, and H. Z. Cummins, Phys. Rev. B PRBMDO 0163-1829 45, 686 (1992). 10.1103/PhysRevB.45.686
11. L. Comez, D. Fioretto, F. Scamponi, and G. Monaco, J. Chem. Phys. JCPSA6 0021-9606 119, 6032 (2003). 10.1063/1.1601608
12. W. Götze, in Liquids, Freezing and the Glass Transition, edited by, J. P. Hansen, D. Levesque, and, J. Zinn-Justin, (North-Holland, Amsterdam, 1991), pp. 289-503.
13. T. Dorfmüller, G. Fytas, W. Mersch, and D. Samios, J. Chem. Soc. Faraday Discussions II 11, 106 (1977); A. Patkowski, J. Gapinski, G. Meier, and H. Kriegs, J. Chem. Phys. JCPSA6 0021-9606 126, 014508 (2007) 10.1063/1.2426347; H. Kriegs, G. Meier, J. Gapinski, and A. Patkowski, J. Chem. Phys. JCPSA6 0021-9606 128, 014507 (2008). 10.1063/1.2816136
14. G. Floudas, P. Placke, P. Stepanek, W. Brown, G. Fytas, and K. L. Ngai, Macromolecules MAMOBX 0024-9297 28, 6799 (1995). 10.1021/ma00124a015
15. S. C. Santucci, D. Fioretto, L. Gomez, A. Gessini, and C. Masciovecchio, Phys. Rev. Lett. PRLTAO 0031-9007 97, 225701 (2006). 10.1103/PhysRevLett.97. 225701 (Pubitemid 44826918)
16. M. Doxastakis, D. N. Theodorou, G. Fytas, F. Kremer, R. Faller, F. Muller-Plathe, and N. Hadjichristidis, J. Chem. Phys. JCPSA6 0021-9606 119, 6883 (2003). 10.1063/1.1603720
17. T. Cherdhirankorn, V. Harmandaris, A. Juhari, P. Voudouris, G. Fytas, K. Kremer, and K. Koynov, Macromolecules MAMOBX 0024-9297 42, 4858 (2009). 10.1021/ma900605z
18. A. Gitsas and G. Floudas, Macromolecules MAMOBX 0024-9297 41, 9423 (2008). 10.1021/ma8014992
19. G. Tommaseo, G. Petekidis, W. Steffen, G. Fytas, A. B. Schofield, and N. Stefanou, J. Chem. Phys. JCPSA6 0021-9606 126, 014707 (2007). 10.1063/1.2429067 (Pubitemid 46068417)
20. G. Fytas, G. Meier, and Th. Dorfmüller, Macromolecules MAMOBX 0024-9297 18, 993 (1985) 10.1021/ma00147a031; A. Patkowski, J. Gapinski, G. Meier, H. Kriegs, A. Le Grand, and C. Dreyfus, Europhys. Lett. EULEEJ 0295-5075 73, 607 (2006) 10.1209/epl/i2005-10429-y; C. Dreyfus, A. Aouadi, J. Gapinski, M. Matos-Lopes, W. Steffen, A. Patkowski, and R. M. Pick, Phys. Rev. E PLEEE8 1063-651X 68, 011204 (2003). 10.1103/PhysRevE.68.011204
21. L. Borjesson, J. R. Stevens, and L. M. Torell, Polymer POLMAG 0032-3861 28, 1803 (1987) 10.1016/0032-3861(87)90281-3; G. D. Patterson, J. Polym. Sci., Part B: Polym. Phys. JPBPEM 0887-6266 15, 455 (1977).
22. F. Kremer and A. Schönhals, Broadband Dielectric Spectroscopy (Springer, Berlin, 2003).
23. J. Jäckle and R. Richert, Phys. Rev. E PLEEE8 1063-651X 77, 031201 (2008). 10.1103/PhysRevE.77.031201
24. See supplementary material at http://dx.doi.org/10.1063/1.3319687 E-JCPSA6-132-009008 for relaxation-retardation time relationship and generalized hydrodynamics.
25. R. Richert, J. Chem. Phys. JCPSA6 0021-9606 123, 154502 (2005). 10.1063/1.2064667
26. M. K. Mapes, S. F. Swallen, and M. D. Ediger, J. Phys. Chem. B JPCBFK 1089-5647 110, 507 (2006). 10.1021/jp0555955 (Pubitemid 43136742)
27. G. Fytas, C. H. Wang, D. Lilge, and Th. Dorfmüller, J. Chem. Phys. JCPSA6 0021-9606 75, 4247 (1981) 10.1063/1.442626; W. Steffen, A. Patkowski, G. Meier, and E. W. Fischer, J. Chem. Phys. JCPSA6 0021-9606 96, 4171 (1992) 10.1063/1.461873; W. Steffen, A. Patkowski, H. Glaser, G. Meier, and E. W. Fischer, Phys. Rev. E PLEEE8 1063-651X 49, 2992 (1994) 10.1103/PhysRevE.49.2992; A. Patkowski, E. W. Fischer, W. Steffen, H. Glaser, M. Baumann, T. Ruths, and G. Meier, Phys. Rev. E PLEEE8 1063-651X 63, 061503 (2001). 10.1103/PhysRevE.63. 061503
28. H. Z. Cummins, G. Li, W. M. Du, Y. H. Hwang, and G. Q. Shen, Prog. Theor. Phys. Suppl. PTPSEP 0375-9687 126, 21 (1997). 10.1143/PTPS.126.21
29. I. Bahar, B. Erman, G. Fytas, and W. Steffen, Macromolecules MAMOBX 0024-9297 27, 5200 (1994). 10.1021/ma00096a051
30. R. Böhmer, K. L. Ngai, C. A. Angell, and D. J. Plazek, J. Chem. Phys. JCPSA6 0021-9606 99, 4201 (1993). 10.1063/1.466117
31. R. Torre, A. Taschin, and M. Sampoli, Phys. Rev. E PLEEE8 1063-651X 64, 061504 (2001). 10.1103/PhysRevE.64.061504
32. S. M. Lippow, X. H. Qiu, and M. D. Ediger, J. Chem. Phys. JCPSA6 0021-9606 115, 4961 (2001). 10.1063/1.1391455 (Pubitemid 32902748)
33. S. J. Antoniadis, C. T. Samara, and D. N. Theodorou, Macromolecules MAMOBX 0024-9297 31, 7944 (1998). 10.1021/ma9807318
34. B. Berne and R. Pecora, Dynamic Light Scattering (Wiley, New York, 1976).