One-pot synthesis of α,β-epoxy ketones by palladium-catalyzed epoxidation-oxidation of terminal allylic alcohols

Tetrahedron Letters

Volumn 51, Issue 13, 2010, Pages 1671-1673

  Singh, Fateh V ^a   Pena, Jesus M ^a   Stefani, Hélio A ^a  

^a UNIVERSITY OF SÃO PAULO   (Brazil)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL DERIVATIVE; ALLYL COMPOUND; ALPHA BETA EPOXY KETONE; KETONE; PALLADIUM; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; ELECTRON; EPOXIDATION; ONE POT SYNTHESIS; OXIDATION;

EID: 76949092919     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2010.01.065     Document Type: Article

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15. 3) δ 75.18, 114.11, 126.80, 127.62, 128.10, 128.14, 128.38, 133.27, 138.74, 140.08, 150.03; CG/MS: m/z (relative, %) 244 (36), 104 (100), 93 (41), 77 (67).
16. 3) δ 55.13, 63.10, 125.29, 128.42, 128.62, 129.10, 129.97, 131.38, 132.26, 135.26, 140.34, 193.53; CG/MS: m/z (relative, %) 258 (13), 242 (6), 165 (15), 141 (32), 139 (100), 119 (62), 105 (26), 91 (60).