Allylbenzene isomerisation over as-synthesized MgAl and NiAl containing LDHs: Basicity-activity relationships

Applied Clay Science

Volumn 48, Issue 1-2, 2010, Pages 243-249

  Jinesh, C M ^a   Antonyraj, Churchil A ^a   Kannan, S ^a  

^a CSIR CENTRAL SALT AND MARINE CHEMICALS RESEARCH INSTITUTE   (India)

Author keywords

Allylbenzene isomerisation; Basicity; CO2 temperature programmed desorption; Phenol adsorption

Indexed keywords

ALLYLBENZENE; ATOMIC RATIO; BASICITY; HYDROTALCITES; ISOMERISATION; MODEL REACTIONS; PHENOL ADSORPTION; SURFACE BASICITY;

ADSORPTION; CALCINATION; ISOMERIZATION; ORGANIC SOLVENTS; PHENOLS; STYRENE;

TEMPERATURE PROGRAMMED DESORPTION;

ADSORPTION; ALUMINUM; BENZENE; CARBON DIOXIDE; DESORPTION; HYDROTALCITE; MAGNESIUM; MINERAL SYNTHESIS; NICKEL; PHENOL;

EID: 76849109833     PISSN: 01691317     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.clay.2009.11.026     Document Type: Article

References (37)

1. Abello S., Dhir S., Colet G., and Ramirez J.P. Accelerated study of the citral-acetone condensation kinetics over activated Mg-Al hydrotalcite. Appl. Catal., A Gen. 325 (2007) 121-129
2. Antonyraj C.A., and Kannan S. Hantzsch pyridine synthesis using hydrotalcites or hydrotalcite-like materials as solid base catalysts. Appl. Catal., A Gen. 338 (2008) 121-129
3. Aramendi{dotless}a M.A., Borau V., Jimenez C., Marinas A., Marinas J.M., and Urbano F.J. Isomerization of 3-phenyl-1-propene (allylbenzene) over base catalysts. J. Catal. 211 (2002) 556-559
4. Aramendi{dotless}a M.A., Borau V., Jimenez C., Marinas A., Marinas J.M., Ruiz J.R., and Urbano F.J. Magnesium-containing mixed oxides as basic catalysts: base characterization by carbon dioxide TPD-MS and test reactions. J. Mol. Catal., A Chem. 218 (2004) 81-90
5. Caiiron O., Dumitriu E., and Guimon C. Acido-basicity of Mg-Ni-Al mixed oxides from LDH precursors: a FTIR and XPS study. J. Phys. Chem. C 111 (2007) 8015-8023
6. Chisem I.C., Jones W., Martin I., Martin C., and Rives V. Probing the surface acidity of lithium aluminium and magnesium aluminium layered double hydroxides. J. Mater. Chem. 8 (1998) 1917-1925
7. Choudary B.M., Roy M., Roy S., Kantam M.L., Jyothi K., and Sreedhar B. Layered double hydroxide supported nanoplatinum and nanopalladium catalyzed allylation of aldehydes: a mechanistic study. Adv. Synth. Catal. 347 (2005) 2009-2014
8. - layered double hydroxide. Catal. Lett. 23 (1994) 361-367
9. Debecker D.P., Gaigneaux E.M., and Busca G. Exploring, tuning and exploiting the basicity of hydrotalcites for the applications of heterogeneous catalysis. Chem. Eur. J. 15 (2009) 3920-3935
10. Duan X., and Evans D.G. Structure and Bonding-layered Double Hydroxides (2006), Springer, Berlin
11. 3 ion pair catalysts. J. Mol. Catal., A Chem. 126 (1997) 27-36
12. Figueras F., Lopez J., Valente J.S., Vu T.T.H., Clacens J.M., and Palomeque J. Isophorone isomerization as model reaction for the characterization of solid bases: application to the determination of the number of sites. J. Catal. 211 (2002) 144-149
13. Gordijo C.R., Constantino V.R.L., and Silva D.O. Evidences for decarbonation and exfoliation of layered double hydroxide in N, N-dimethylformamide-ethanol solvent mixture. J. Solid State Chem. 180 (2007) 1967-1976
14. Jana S.K., Wu P., and Tatsumi T. NiAl hydrotalcite as an efficient and environmentally friendly solid catalyst for solvent-free liquid-phase selective oxidation of ethylbenzene to acetophenone with 1 atm of molecular oxygen. J. Catal. 240 (2006) 268-274
15. Jinesh C.M., Antonyraj C.A., and Kannan S. Isomerization of eugenol and alkenyl aromatics of perfumery interest over Ni-containing layered double hydroxides as solid base catalysts. Catal. Today 141 (2009) 176-181
16. Joint Committee on Powder Diffraction Standards, International Centre for Diffraction Data, Pennsylvania, USA, 1996, Set No. 46.
17. Kannan S., and Swamy C.S. Catalytic decomposition of nitrous oxide over calcined cobalt aluminium hydrotalcites. Catal. Today 53 (1999) 725-737
18. Kannan S., Dubey A., and Knozinger H. Synthesis and characterization of CuMgAl ternary hydrotalcites as catalysts for the hydroxylation of phenol. J. Catal. 231 (2005) 381-392
19. Kishore D., and Kannan S. Isomerisation of eugenol and safrole over MgAl hydrotalcite, a solid base catalyst. Green Chem. 4 (2002) 607-610
20. Kishore D., and Kannan S. Catalytic isomerization of estragole to anethole over hydrotalcites and HT-like compounds. J. Mol. Catal., A Chem. 244 (2006) 83-92
21. Kshirsagar S.W., Patil N.R., and Samat S.D. Mg-Al hydrotalcites as the first heterogeneous basic catalysts for the Kornblum oxidation of benzyl halides to benzaldehydes using DMSO. Tetrahedron Lett. 49 (2008) 1160-1162
22. Li F., Jiang X., Evans D.G., and Duan X. Structure and basicity of mesoporous materials from Mg/Al/In layered double hydroxides prepared by separate nucleation and aging steps method. J. Porous Mater. 12 (2005) 55-63
23. Li J., Tai J., and Davis R.J. Hydrocarbon oxidation and aldol condensation over basic zeolite catalysts. Catal. Today 116 (2006) 226-233
24. Lima E., Lasperas M., Menorval L.C., Tichit D., and Fajula F. Characterization of basic catalysts by the use of nitromethane as NMR probe molecule and reactant. J. Catal. 223 (2004) 28-35
25. Liu Z., Ma R., Osada M., Iyi N., Ebina Y., Takada K., and Sasaki T. Synthesis, anion exchange, and delamination of Co-Al layered double hydroxide: assembly of the exfoliated nanosheet/polyanion composite films and magneto-optical studies. J. Am. Chem. Soc. 128 (2006) 4872-4880
26. Liu S., Jiang X., and Zhua G. Heck reaction catalyzed by colloids of delaminated Pd-containing layered double hydroxide. J. Mol. Catal., A Chem. 290 (2008) 72-78
27. Mora M., Sanchidrian C.J., and Ruiz J.R. Suzuki cross-coupling reactions over Pd(II)-hydrotalcite catalysts in water. J. Mol. Catal. 285 (2008) 79-83
28. 2 sorption on hydrotalcite and alkali-modified (K and Cs) hydrotalcites at high temperatures. Sep. Purif. Technol. 62 (2008) 137-147
29. Onda A., Ochi T., Kajiyoshi K., and Yanagisawa K. Lactic acid production from glucose over activated hydrotalcites as solid base catalysts in water. Catal. Commun. 9 (2008) 1050-1053
30. Prinetto F., Ghiotti G., Durand R., and Tichit D. Investigation of acid-base properties of catalysts obtained from layered double hydroxides. J. Phys. Chem. B 104 (2000) 11117-11126
31. Rao K.K., Gravelle M., Valente J.S., and Figueras F. Activation of Mg-Al hydrotalcite catalysts for aldol condensation reactions. J. Catal. 173 (1998) 115-121
32. Sun L.B., Gu F.N., Chun Y., Yang J., Wang Y., and Zhu J.H. Attempt to generate strong basicity on silica and titania. J. Phys. Chem. C 112 (2008) 4978-4985
33. Tanner R., Enache D., Wells R.P.K., Kelly G., Casci J., and Hutchings G.H. Comments on the use of 2-methylbut-3-yn-2-ol decomposition as a probe reaction for the potential reactivity Mg-Al hydrotalcites as base catalysts. Catal. Lett. 100 (2005) 259-265
34. 3 synergetic catalyst for allylbenzene isomerization. Top. Catal. 52 (2009) 344-350
35. Veldurthy B., Clacens J.M., and Figueras F. Correlation between the basicity of solid bases and their catalytic activity towards the synthesis of unsymmetrical organic carbonates. J. Catal. 229 (2005) 237-242
36. Xi Y., and Davis R.J. Influence of water on the activity and stability of activated MgAl hydrotalcites for the transesterification of tributyrin with methanol. J. Catal. 254 (2008) 190-197
37. 2)3 N (R=Me, i-Pr)-catalyzed isomerization of allylaromatics, allyl phenyl sulfide, allyl phenyl sulfone, and bis-allylmethylene double bond-containing compounds. Adv. Synth. Catal. 348 (2006) 111-117