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Polymers containing ferrocene, silicon, and an unsaturated hydrocarbon were prepared by Sheridan and co-workers, who successfully carried out hydrosilylation reactions of 12 with diethynylbenzene spacers to yield poly[ferrocene(phenylene)bis(silylenevinylene)]s. In this work, metal insertion is exclusively through the Si-H bonds. See: Jain, R.; Lalancette, R. A.; Sheridan, J. B. Organometallics 2005, 24, 1458-1467.
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2H groups in the presence of Mg metal to yield a disilane bridge. The favorable ring-tilt of cyclopentadienyl rings toward each other in this structure suggests that formation of an intramolecular Si-Si bond is likely, as the distance between silicon atoms is considerably shorter than in the case of 12. Horáček, M.; Pinkas, J.; Gyepes, R.; Kubišta, J.; Mach, R. Organometallics 2008, 27, 2635-2642.
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2)Me] in DMF yielded disilane-bridged polymers, including 6. See: Itazaki, M.; Ueda, K.; Nakazawa, H. Angew. Chem. Int. Ed. 2009,48,3313 - 3316.
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The findings of this work were found to be in error (Sharma, H. K.; Pannell, K. H. Angew. Chem., Int. Ed. 2009,48, 7052-7054),
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Our own work with Pt catalyst shows that dehydrogenative reactions are not occurring. Instead oxygen abstraction from, the reduction of DMF leads to oligoferrocenylsiloxanes and polyferrocenylsiloxanes. See: Miles, D.; Ward, J.; Foucher, D. Macromolecudes 2009, 42, 9199-9203.
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