메뉴 건너뛰기




Volumn 46, Issue 3, 2010, Pages 592-601

Synthesis and properties of poly(ether ether ketone)-block-sulfonated polybutadiene copolymers for PEM applications

Author keywords

Block copolymer; Fuel cell; Proton conductivity; Proton exchange membrane; Selective sulfonation

Indexed keywords

AVERAGE SIZE; DEGREE OF SULFONATION; DOUBLE BONDS; ELONGATION AT BREAK; FEED RATIOS; HIGH REACTIVITY; HYDROPHILIC REGIONS; NOVEL SERIES; PROTON EXCHANGE MEMBRANES; SELECTIVE SULFONATION; SPHERICAL DOMAIN; SULFONATE GROUPS; SULFONATED BLOCK COPOLYMERS; SULFONIC ACID GROUPS; TEM IMAGES; TENSILE TESTS; THERMAL STABILITY;

EID: 76749160642     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2009.11.007     Document Type: Article
Times cited : (22)

References (36)
  • 1
    • 0035891321 scopus 로고    scopus 로고
    • Materials for fuel-cell technologies
    • Steele B.C.H., and Heinzel A. Materials for fuel-cell technologies. Nature 414 (2001) 345-352
    • (2001) Nature , vol.414 , pp. 345-352
    • Steele, B.C.H.1    Heinzel, A.2
  • 2
    • 0001274509 scopus 로고    scopus 로고
    • Efficiency and economics of proton exchange membrane fuel cells
    • Barbir F., and Gomez T. Efficiency and economics of proton exchange membrane fuel cells. Int J Hydrogen Energy 22 10/11 (1997) 1027-1037
    • (1997) Int J Hydrogen Energy , vol.22 , Issue.10-11 , pp. 1027-1037
    • Barbir, F.1    Gomez, T.2
  • 3
    • 0033905920 scopus 로고    scopus 로고
    • Recent advances in direct methanol fuel cells at Los Alamos National Laboratory
    • Ren X., Zelency P., and Thomas S. Recent advances in direct methanol fuel cells at Los Alamos National Laboratory. J Power Sources 86 1-2 (2000) 111-116
    • (2000) J Power Sources , vol.86 , Issue.1-2 , pp. 111-116
    • Ren, X.1    Zelency, P.2    Thomas, S.3
  • 4
    • 0002860723 scopus 로고    scopus 로고
    • Fuel cells - fundamentals and applications
    • Carrette L., Friedrich K., and Stimming U. Fuel cells - fundamentals and applications. Fuel Cells 1 (2001) 5-39
    • (2001) Fuel Cells , vol.1 , pp. 5-39
    • Carrette, L.1    Friedrich, K.2    Stimming, U.3
  • 5
    • 7544228532 scopus 로고    scopus 로고
    • Alternative polymer systems for proton exchange membranes (PEMs)
    • Hickner M.A., Ghassemi H., Kim Y.S., Einsla B.R., and Mcgrath J.E. Alternative polymer systems for proton exchange membranes (PEMs). Chem Rev 104 (2004) 4587-4612
    • (2004) Chem Rev , vol.104 , pp. 4587-4612
    • Hickner, M.A.1    Ghassemi, H.2    Kim, Y.S.3    Einsla, B.R.4    Mcgrath, J.E.5
  • 6
    • 0028767779 scopus 로고
    • Blends of Nafion and Dow perfluorosulfonated ionomer membranes
    • Zaluski C., and Xu G. Blends of Nafion and Dow perfluorosulfonated ionomer membranes. Macromolecules 27 23 (1994) 6750-6754
    • (1994) Macromolecules , vol.27 , Issue.23 , pp. 6750-6754
    • Zaluski, C.1    Xu, G.2
  • 7
    • 0037374710 scopus 로고    scopus 로고
    • Structural characterization and surface modification of sulfonated polystyrene-(ethylene-butylene)-styrene triblock proton exchange membranes
    • Won J., Choi S.W., Kang Y.S., Ha H.Y., Oh I.H., Kim H.S., et al. Structural characterization and surface modification of sulfonated polystyrene-(ethylene-butylene)-styrene triblock proton exchange membranes. J Membr Sci 214 (2003) 245-257
    • (2003) J Membr Sci , vol.214 , pp. 245-257
    • Won, J.1    Choi, S.W.2    Kang, Y.S.3    Ha, H.Y.4    Oh, I.H.5    Kim, H.S.6
  • 8
    • 0037374710 scopus 로고    scopus 로고
    • Structural characterization and surface modification of sulfonated polystyrene-(ethylene-butylene)-styrene triblock proton exchange membranes
    • Won J., and Choi S.W. Structural characterization and surface modification of sulfonated polystyrene-(ethylene-butylene)-styrene triblock proton exchange membranes. J Membr Sci 214 2 (2003) 245-257
    • (2003) J Membr Sci , vol.214 , Issue.2 , pp. 245-257
    • Won, J.1    Choi, S.W.2
  • 9
    • 0000300904 scopus 로고    scopus 로고
    • Evaluation of a sol-gel derived Nafion/silica hybrid membrane for polymer electrolyte membrane fuel cell applications. II. Methanol uptake and methanol permeability
    • Miyake N., Wainright J.S., and Savinell R.F. Evaluation of a sol-gel derived Nafion/silica hybrid membrane for polymer electrolyte membrane fuel cell applications. II. Methanol uptake and methanol permeability. J Electrochem Soc 148 (2001) 898-904
    • (2001) J Electrochem Soc , vol.148 , pp. 898-904
    • Miyake, N.1    Wainright, J.S.2    Savinell, R.F.3
  • 10
    • 0347418166 scopus 로고    scopus 로고
    • Approaches and recent development of polymer electrolyte membranes for fuel cells operating above 100 °C
    • Li Q., He R., Jensen J.O., and Bjerrum N.J. Approaches and recent development of polymer electrolyte membranes for fuel cells operating above 100 °C. Chem Mater 15 26 (2003) 4896-4915
    • (2003) Chem Mater , vol.15 , Issue.26 , pp. 4896-4915
    • Li, Q.1    He, R.2    Jensen, J.O.3    Bjerrum, N.J.4
  • 11
    • 13844275891 scopus 로고    scopus 로고
    • Recent progress in proton conducting membranes for PEFCs
    • Miyatake K., and Watanabe M. Recent progress in proton conducting membranes for PEFCs. Electrochemistry 73 1 (2005) 12-19
    • (2005) Electrochemistry , vol.73 , Issue.1 , pp. 12-19
    • Miyatake, K.1    Watanabe, M.2
  • 12
    • 22144438362 scopus 로고    scopus 로고
    • Proton conductive membranes of sulfonated poly(ether ketone ketone)
    • Vetter S., Ruffmann B., Buder I., and Nunes S.P. Proton conductive membranes of sulfonated poly(ether ketone ketone). J Membr Sci 260 (2005) 181-186
    • (2005) J Membr Sci , vol.260 , pp. 181-186
    • Vetter, S.1    Ruffmann, B.2    Buder, I.3    Nunes, S.P.4
  • 13
    • 23844506470 scopus 로고    scopus 로고
    • Directly copolymerized poly(arylene sulfide sulfone) disulfonated copolymers for PEM-based fuel cell systems. I. Synthesis and characterization
    • Willes K.B., Wang F., and McGrath J.E. Directly copolymerized poly(arylene sulfide sulfone) disulfonated copolymers for PEM-based fuel cell systems. I. Synthesis and characterization. J Polym Sci A: Polym Chem 43 14 (2005) 2964-2976
    • (2005) J Polym Sci A: Polym Chem , vol.43 , Issue.14 , pp. 2964-2976
    • Willes, K.B.1    Wang, F.2    McGrath, J.E.3
  • 14
    • 4744368250 scopus 로고    scopus 로고
    • Synthesis and properties of poly(aryl ether ether ketone) copolymers with pendant methyl groups
    • Rao V.L., Sabeena P.U., Saxena A., Gopalakrishnan C., Krishnan K., Ravindran P.V., et al. Synthesis and properties of poly(aryl ether ether ketone) copolymers with pendant methyl groups. Eur Polym J 40 (2004) 2645-2651
    • (2004) Eur Polym J , vol.40 , pp. 2645-2651
    • Rao, V.L.1    Sabeena, P.U.2    Saxena, A.3    Gopalakrishnan, C.4    Krishnan, K.5    Ravindran, P.V.6
  • 15
    • 0037137364 scopus 로고    scopus 로고
    • Novel sulfonated polyimides as polyelectrolytes for fuel cell application. 1. Synthesis, proton conductivity, and water stability of polyimides from 4,4′-diaminodiphenyl ether-2,2′-disulfonic acid
    • Fang J., Guo X., Harada S., Watari T., Tanaka K., Kita H., et al. Novel sulfonated polyimides as polyelectrolytes for fuel cell application. 1. Synthesis, proton conductivity, and water stability of polyimides from 4,4′-diaminodiphenyl ether-2,2′-disulfonic acid. Macromolecules 35 (2002) 9022-9028
    • (2002) Macromolecules , vol.35 , pp. 9022-9028
    • Fang, J.1    Guo, X.2    Harada, S.3    Watari, T.4    Tanaka, K.5    Kita, H.6
  • 16
    • 18844395642 scopus 로고    scopus 로고
    • Sulfonated naphthalene dianhydride based polyimide copolymers for proton-exchange-membrane fuel cells. II. Membrane properties and fuel cell performance
    • Einsla B.R., Kim Y.S., Hickner M.A., Hong Y.T., Hill M.L., Pivovar B.S., et al. Sulfonated naphthalene dianhydride based polyimide copolymers for proton-exchange-membrane fuel cells. II. Membrane properties and fuel cell performance. J Membr Sci 255 (2005) 141-148
    • (2005) J Membr Sci , vol.255 , pp. 141-148
    • Einsla, B.R.1    Kim, Y.S.2    Hickner, M.A.3    Hong, Y.T.4    Hill, M.L.5    Pivovar, B.S.6
  • 17
    • 3342959170 scopus 로고    scopus 로고
    • New multiblock copolymers of sulfonated poly(4′-phenyl-2,5-benzophenone) and poly(arylene ether sulfone) for proton exchange membranes. II
    • Ghassemi H., Ndip G., and McGrath J.E. New multiblock copolymers of sulfonated poly(4′-phenyl-2,5-benzophenone) and poly(arylene ether sulfone) for proton exchange membranes. II. Polymer 45 17 (2004) 5855-5862
    • (2004) Polymer , vol.45 , Issue.17 , pp. 5855-5862
    • Ghassemi, H.1    Ndip, G.2    McGrath, J.E.3
  • 18
    • 34548503645 scopus 로고    scopus 로고
    • Hybrid materials for polymer electrolyte membrane fuel cells: water uptake, mechanical and transport properties
    • Vona M.L.D., Marani D., Epifanio A.D., Licoccia S., Beurroies I., Denoyel R., et al. Hybrid materials for polymer electrolyte membrane fuel cells: water uptake, mechanical and transport properties. J Membr Sci 304 (2007) 76-81
    • (2007) J Membr Sci , vol.304 , pp. 76-81
    • Vona, M.L.D.1    Marani, D.2    Epifanio, A.D.3    Licoccia, S.4    Beurroies, I.5    Denoyel, R.6
  • 19
    • 12044252995 scopus 로고
    • Condensation polyimides: synthesis, solution behavior, and imidization characteristics
    • Volksen W. Condensation polyimides: synthesis, solution behavior, and imidization characteristics. Adv Polym Sci 117 (1994) 158-159
    • (1994) Adv Polym Sci , vol.117 , pp. 158-159
    • Volksen, W.1
  • 20
    • 0030835243 scopus 로고    scopus 로고
    • Synthesis and mechanical properties of poly(styrene-b-isobutylene-b-styrene) block copolymer ionomers
    • Storey R.F., and Chisholm B.J. Synthesis and mechanical properties of poly(styrene-b-isobutylene-b-styrene) block copolymer ionomers. Polym Eng Sci 37 1 (1997) 73-80
    • (1997) Polym Eng Sci , vol.37 , Issue.1 , pp. 73-80
    • Storey, R.F.1    Chisholm, B.J.2
  • 21
    • 0038392683 scopus 로고    scopus 로고
    • Triblock copolymer ionomer membranes. Part I. Methanol and proton transport
    • Elabd Y.A., Napadensky E., Sloan J.M., Crawford D.M., and Walker C.W. Triblock copolymer ionomer membranes. Part I. Methanol and proton transport. J Membr Sci 217 (2003) 227-242
    • (2003) J Membr Sci , vol.217 , pp. 227-242
    • Elabd, Y.A.1    Napadensky, E.2    Sloan, J.M.3    Crawford, D.M.4    Walker, C.W.5
  • 22
    • 1242292930 scopus 로고    scopus 로고
    • Triblock copolymer ionomer membranes. Part II. Structure characterization and its effects on transport properties and direct methanol fuel cell performance
    • Elabd Y.A., Walker C.W., and Beyer F.L. Triblock copolymer ionomer membranes. Part II. Structure characterization and its effects on transport properties and direct methanol fuel cell performance. J Membr Sci 231 (2004) 181-188
    • (2004) J Membr Sci , vol.231 , pp. 181-188
    • Elabd, Y.A.1    Walker, C.W.2    Beyer, F.L.3
  • 23
    • 30944432823 scopus 로고    scopus 로고
    • Transport properties of sulfonated poly(styrene-b-isobutylene-b-styrene) triblock copolymers at high ion-exchange capacities
    • Elabd Y.A., Napadensky E., Walker C.W., and Winey K.I. Transport properties of sulfonated poly(styrene-b-isobutylene-b-styrene) triblock copolymers at high ion-exchange capacities. Macromolecules 39 1 (2006) 399-407
    • (2006) Macromolecules , vol.39 , Issue.1 , pp. 399-407
    • Elabd, Y.A.1    Napadensky, E.2    Walker, C.W.3    Winey, K.I.4
  • 24
    • 0034307739 scopus 로고    scopus 로고
    • Studies of sulfonated block copolymer and its blends
    • Mokrini A., and Acosta J.L. Studies of sulfonated block copolymer and its blends. Polymer 42 1 (2001) 9-15
    • (2001) Polymer , vol.42 , Issue.1 , pp. 9-15
    • Mokrini, A.1    Acosta, J.L.2
  • 25
    • 0035868498 scopus 로고    scopus 로고
    • Complex impedance studies of S-SEBS block polymer proton-conducting membranes
    • Edmondson C.A., Fontanella J.J., Chung S.H., Greenbaum S.G., and Wnek G.E. Complex impedance studies of S-SEBS block polymer proton-conducting membranes. Electrochim Acta 46 10-11 (2001) 1623-1628
    • (2001) Electrochim Acta , vol.46 , Issue.10-11 , pp. 1623-1628
    • Edmondson, C.A.1    Fontanella, J.J.2    Chung, S.H.3    Greenbaum, S.G.4    Wnek, G.E.5
  • 26
    • 0037200840 scopus 로고    scopus 로고
    • Effect of casting solvent on morphology and physical properties of partially sulfonated polystyrene-block-poly(ethylene-ran-butylene)-block-polystyrene copolymers
    • Kim J., Kim B., Jung B., Kang Y.S., Ha H.Y., Oh I.H., et al. Effect of casting solvent on morphology and physical properties of partially sulfonated polystyrene-block-poly(ethylene-ran-butylene)-block-polystyrene copolymers. Macromol Rapid Commun 23 13 (2002) 753-756
    • (2002) Macromol Rapid Commun , vol.23 , Issue.13 , pp. 753-756
    • Kim, J.1    Kim, B.2    Jung, B.3    Kang, Y.S.4    Ha, H.Y.5    Oh, I.H.6
  • 27
    • 0842266479 scopus 로고    scopus 로고
    • Synthesis of poly[arylene ether sulfone-b-vinylidene fluoride] block copolymers
    • Yang Y., Shi Z., and Holdcroft S. Synthesis of poly[arylene ether sulfone-b-vinylidene fluoride] block copolymers. Eur Polym J 40 3 (2004) 531-541
    • (2004) Eur Polym J , vol.40 , Issue.3 , pp. 531-541
    • Yang, Y.1    Shi, Z.2    Holdcroft, S.3
  • 28
    • 1642619521 scopus 로고    scopus 로고
    • Synthesis of sulfonated polysulfone-block-PVDF copolymers: enhancement of proton conductivity in low ion exchange capacity membranes
    • Yang Y., Shi Z.Q., and Holdcroft S. Synthesis of sulfonated polysulfone-block-PVDF copolymers: enhancement of proton conductivity in low ion exchange capacity membranes. Macromolecules 37 5 (2004) 1678-1681
    • (2004) Macromolecules , vol.37 , Issue.5 , pp. 1678-1681
    • Yang, Y.1    Shi, Z.Q.2    Holdcroft, S.3
  • 29
    • 19944363190 scopus 로고    scopus 로고
    • Synthesis and proton conductivity of partially sulfonated poly([vinylidene difluoride-co-hexafluoropropylene]-b-styrene) block copolymers
    • Shi Z.Q., and Holdcroft S. Synthesis and proton conductivity of partially sulfonated poly([vinylidene difluoride-co-hexafluoropropylene]-b-styrene) block copolymers. Macromolecules 38 10 (2005) 4193-4201
    • (2005) Macromolecules , vol.38 , Issue.10 , pp. 4193-4201
    • Shi, Z.Q.1    Holdcroft, S.2
  • 30
    • 37049017171 scopus 로고    scopus 로고
    • Considerations of macromolecular structure in the design of proton conducting polymer membranes: graft versus diblock polyelectrolytes
    • Tsang E.M.W., Zhang Z.B., Shi Z.Q., Soboleva T., and Holdcroft S. Considerations of macromolecular structure in the design of proton conducting polymer membranes: graft versus diblock polyelectrolytes. J Am Chem Soc 129 49 (2007) 15106-15107
    • (2007) J Am Chem Soc , vol.129 , Issue.49 , pp. 15106-15107
    • Tsang, E.M.W.1    Zhang, Z.B.2    Shi, Z.Q.3    Soboleva, T.4    Holdcroft, S.5
  • 31
    • 32244432030 scopus 로고    scopus 로고
    • Aliphatic/aromatic polyimide ionomers as a proton conductive membrane for fuel cell applications
    • Asano N., Aoki M., Suzuki S., Miyatake K., Uchida H., and Watanabe M. Aliphatic/aromatic polyimide ionomers as a proton conductive membrane for fuel cell applications. J Am Chem Soc 128 5 (2006) 1762-1769
    • (2006) J Am Chem Soc , vol.128 , Issue.5 , pp. 1762-1769
    • Asano, N.1    Aoki, M.2    Suzuki, S.3    Miyatake, K.4    Uchida, H.5    Watanabe, M.6
  • 32
    • 0030607287 scopus 로고    scopus 로고
    • Recent advances in perfluorinated ionomer membranes: structure, properties and applications
    • Wirguin C.H. Recent advances in perfluorinated ionomer membranes: structure, properties and applications. J Membr Sci 120 1 (1996) 1-33
    • (1996) J Membr Sci , vol.120 , Issue.1 , pp. 1-33
    • Wirguin, C.H.1
  • 33
    • 70449466026 scopus 로고    scopus 로고
    • Synthesis of highly sulfonated poly(arylene ether sulfone) random (statistical) copolymers via direct polymerization
    • Wang F., Hickner M., and McGrath J.E. Synthesis of highly sulfonated poly(arylene ether sulfone) random (statistical) copolymers via direct polymerization. Macromol Symp 175 (2001) 387-395
    • (2001) Macromol Symp , vol.175 , pp. 387-395
    • Wang, F.1    Hickner, M.2    McGrath, J.E.3
  • 34
    • 0000160418 scopus 로고
    • Hydrocarbon-soluble sulfonating reagents. Sulfonation of aromatic polymers in hydrocarbon solution using soluble acyl sulfates
    • Thaler W.A. Hydrocarbon-soluble sulfonating reagents. Sulfonation of aromatic polymers in hydrocarbon solution using soluble acyl sulfates. Macromolecules 16 4 (1983) 623-628
    • (1983) Macromolecules , vol.16 , Issue.4 , pp. 623-628
    • Thaler, W.A.1
  • 35
    • 20444465263 scopus 로고    scopus 로고
    • Direct synthesis of sulfonated poly(ether ether ketone ketone)s (SPEEKKs) proton exchange membranes for fuel cell application
    • Li X.F., Zhao C.J., Lu H., Wang Z., and Na H. Direct synthesis of sulfonated poly(ether ether ketone ketone)s (SPEEKKs) proton exchange membranes for fuel cell application. Polymer 46 (2005) 5820-5827
    • (2005) Polymer , vol.46 , pp. 5820-5827
    • Li, X.F.1    Zhao, C.J.2    Lu, H.3    Wang, Z.4    Na, H.5
  • 36
    • 28144438812 scopus 로고    scopus 로고
    • Synthesis of poly(arylene ether) copolymers containing pendant PEO groups and evaluation of their blends as proton conductive membranes
    • Deimede V.A., and Kallitsis J.K. Synthesis of poly(arylene ether) copolymers containing pendant PEO groups and evaluation of their blends as proton conductive membranes. Macromolecules 38 23 (2005) 9594-9601
    • (2005) Macromolecules , vol.38 , Issue.23 , pp. 9594-9601
    • Deimede, V.A.1    Kallitsis, J.K.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.