The one-electron cleavage of benzylic bromides at palladium and palladized cathodes: Benzyl radicals generation and immobilization onto solid interfaces

Electrochemistry Communications

Volumn 12, Issue 3, 2010, Pages 331-334

  Jouikov, Viatcheslav ^a   Simonet, Jacques ^a  

^a UNIVERSITÉ DE RENNES 1   (France)

Author keywords

Benzyl radicals; Cathodic reduction; Cleavage of carbon halogen bond; Organic halides; Surface modification

Indexed keywords

BENZYL RADICALS; CARBON-HALOGEN BOND; CATHODIC REDUCTIONS; ORGANIC HALIDES; SURFACE MODIFICATION;

BROMINE COMPOUNDS; DIMETHYLFORMAMIDE; ELECTRODES; FREE RADICALS; PROPYLENE; SILVER; SURFACE TREATMENT;

PALLADIUM;

EID: 76449113377     PISSN: 13882481     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.elecom.2009.12.009     Document Type: Article

References (13)

1. Heck R.F. Acc. Chem. Res. 12 (1979) 146
2. March J. Advanced Organic Chemistry; Reactions, Mechanisms, and Structure. third ed. (1985), Wiley-Interscience, NY, Chichester
3. Peters D.G. In: Lund H., and Hammerich O. (Eds). Organic Electrochemistry. fourth ed. (2001), M.M. Dekker, NY 343 and references given therein
4. Simonet J. Electrochem. Commun. 7 (2005) 619
5. Rondinini S., and Vertova A. Electrochim. Acta 49 (2005) 4035
6. Isse A., Mussini P.R., and Gennaro A. J. Phys. Chem. C 113 (2009) 14983
7. Simonet J., Poizot P., and Laffont L. J. Electroanal. Chem. 19 (2006) 591
8. Poizot P., Laffont-Dantras L., and Simonet J. J. Electroanal. Chem. 52 (2008) 624
9. Isse A.A., De Guisti A., and Gennaro A. Tetrahedron Lett. 47 (2006) 7735
10. Pinson J., and Podvorica F. Chem. Soc. Rev. 34 (2005) 429
11. J. Simonet, unpublished works.
12. Gonzalez F.J., Hapiot P., Konovalov V., and Saveant J.M. J. Am. Chem. Soc. 120 (1998) 10171
13. Chandra H., Davidson I.M.T., and Symons M.C.R. J. Chem. Soc., Faraday Trans. I 79 (1983) 2705