Comparisons of modified effective medium theory with experimental data on shear thinning of concentrated latex dispersions

Journal of Rheology

Volumn 54, Issue 1, 2010, Pages 1-26

  Takamura, Koichi ^a   Van De Ven, Theo G M ^b  

^a BASF CORPORATION   (United States)

^b MCGILL UNIVERSITY   (Canada)

Author keywords

Concentrated dispersions; Latex dispersions; Secondary electroviscous effect; Shear thinning; Stabilizing layer

Indexed keywords

ELECTRO-VISCOUS EFFECTS; LATEX DISPERSIONS; SHEAR THINNING; STABILIZING LAYER; STABILIZING LAYERS;

CARBOXYLIC ACIDS; DISPERSIONS; ELECTROLYTES; NON NEWTONIAN FLOW; ORGANIC ACIDS; SHEAR DEFORMATION; SHEAR FLOW; TITRATION; VISCOSITY;

LATEXES;

EID: 76349112506     PISSN: 01486055     EISSN: None     Source Type: Journal    
DOI: 10.1122/1.3263700     Document Type: Article

References (50)

1. Adler, P. M., " Interaction of unequal spheres: I. Hydrodynamic interaction: Colloidal forces.," J. Colloid Interface Sci. 84, 461-473 (1981).
2. Arevalillo, A., do Amaral, M., and Asua, J. M., " Rheology of concentrated polymeric dispersions.," Ind. Eng. Chem. Res. 45, 3280-3286 (2006). 10.1021/ie0510371
3. Batchelor, G. K., " The effect of Brownian motion on the bulk stress in a suspension of spherical particles.," J. Fluid Mech. 0022-1120 83, 97-117 (1977). 10.1017/S0022112077001062
4. Batchelor, G. K., and J. T. Green, " The hydrodynamic interaction of two small freely-moving spheres in a linear flow field.," J. Fluid Mech. 0022-1120 56, 375-400 (1972). 10.1017/S0022112072002927
5. Bergenholtz, J., J. F. Brady, and M. Vicic, " The non-Newtonian rheology of dilute colloidal suspensions.," J. Fluid Mech. 456 239-275 (2002). 10.1017/S0022112001007583 (Pubitemid 35054505)
6. Blackley, D. C., Emulsion Polymerization, Theory and Practice (Applied Science Publishers, Ltd., London, 1975).
7. Booth, F., " The electroviscous effect for suspensions of solid spherical particles.," Proc. R. Soc. London, Ser. A 0950-1207 203, 511-533 (1950).
8. Brady, J. F., and M. Vicic, " Normal stresses in colloidal dispersions.," J. Rheol. 0148-6055 39 (3), 545-566 (1995). 10.1122/1.550712
9. Brodnyan, J. G., and E. L. Kelley, " Viscosity of synthetic latex gels.," J. Colloid Sci. 0095-8522 19, 488-490 (1964). 10.1016/0095-8522(64) 90049-2
10. Brodnyan, J. G., and E. L. Kelley, " The effect of electrolyte content on synthetic latex flow behavior.," J. Colloid Sci. 0095-8522 20, 7-19 (1965). 10.1016/0095-8522(65)90088-7
11. Choi, G. N., and I. M. Krieger, " Rheological studies on sterically stabilized dispersions of uniform colloidal spheres: I. Sample preparation.," J. Colloid Interface Sci. 0021-9797 113, 94-100 (1986a). 10.1016/0021-9797(86)90209-2 (Pubitemid 16610292)
12. Choi, G. N., and I. M. Krieger, " Rheological studies on sterically stabilized model dispersions of uniform colloidal spheres: II. Steady-shear viscosity.," J. Colloid Interface Sci. 0021-9797 113, 101-113 (1986b). 10.1016/0021-9797(86)90210-9 (Pubitemid 16610293)
13. Chow, R. S., and K. Takamura, " Electrophoretic mobilities of bitumen and conventional crude-in-water emulsions using the laser Doppler apparatus in the presence of multivalent cations.," J. Colloid Interface Sci. 0021-9797 125, 212-225 (1988a). 10.1016/0021-9797(88)90070-7
14. Chow, R. S., and K. Takamura, " Effects of surface roughness (hairiness) of latex particles on their electrokinetic potentials.," J. Colloid Interface Sci. 0021-9797 125, 226-236 (1988b). 10.1016/0021-9797(88) 90071-9
15. Chu, F., J. Guilott, and A. Guyot, " Rheology of concentrated multi-sized poly(St/BA/MMA) latices.," Colloid Polym. Sci. 0303-402X 276, 305-312 (1998). 10.1007/s003960050244
16. Cox, R. G., and H. Brenner, " The rheology of a suspension of particles in a Newtonian fluid.," Chem. Eng. Sci. 0009-2509 26, 65-93 (1971). 10.1016/0009-2509(71)86082-7
17. Craciun, L., P. J. Carreau, M. -C. Heuzey, T. G. M. van de Ven, and M. Moan, " Rheological properties of concentrated latex suspensions of poly(styrene-butadiene).," Rheol. Acta 0035-4511 42, 410-420 (2003). 10.1007/s00397-003-0295-x (Pubitemid 37312416)
18. Crassous, J., M. Siebenbürger, M. Ballauff, M. Drechsler, D. Hajnal, O. Henrich, and M. Fuchs, " Shear stresses of colloidal dispersions at the glass transition in equilibrium and in flow.," J. Chem. Phys. 0021-9606 128, 204902 (2008). 10.1063/1.2921801 (Pubitemid 351770647)
19. Dames, B., B. R. Morrison, and N. Willenbacher, " An empirical model predicting the viscosity of highly concentrated, bimodal dispersions with colloidal interactions.," Rheol. Acta 0035-4511 40, 434-440 (2001). 10.1007/s003970100171 (Pubitemid 32901623)
20. Einstein, A., " Eine neue Bestimmung der Moleküldimensionen., " Ann. Phys. 0003-3804 324 (2), 289-306 (1906). 10.1002/andp.19063240204
21. Einstein, A., " Berichtigung zu meiner Arbeit: Eine neue Bestimmung der Moleküldimensionen.," Ann. Phys. 0003-3804 339 (3), 591-592 (1911). 10.1002/andp.19113390313
22. Gondret, P., and L. Petit, " Viscosity of bimodal suspensions.," J. Rheol. 0148-6055 41, 1261-1273 (1997). 10.1122/1.550850
23. Guyot, A., F. Chu, M. Schneider, C. Graillat, and T. F. McKenna, " High solid content latexes.," Prog. Polym. Sci. 0079-6700 27, 1573-1615 (2002). 10.1016/S0079-6700(02)00014-X (Pubitemid 34808608)
24. Hachisu, S., Y. Kobayashi, and A. Kose, " Phase separation in monodisperse latexes.," J. Colloid Interface Sci. 0021-9797 42, 342-348 (1973). 10.1016/0021-9797(73)90298-1
25. Hinch, E. J., and J. D. Sherwood, " The primary electroviscous effect in a suspension of spheres with thin double layers.," J. Fluid Mech. 0022-1120 132, 337-347 (1983). 10.1017/S0022112083001640
26. Hoy, K. L., " Effect of reaction pathway on emulsion polymer structure.," J. Coat. Technol. 0361-8773 51, 27-41 (1979).
27. Kallus, S., N. Willenbacher, D. Distler, T. Neidöfer, M. Wilhelm, and H. W. Spiess, " Characterization of polymer dispersions by Fourier transform rheology.," Rheol. Acta 0035-4511 40, 552-559 (2001). 10.1007/s003970100184 (Pubitemid 33105475)
28. Kim, S., and S. J. Karrila, Microhydrodynamics: Principles and Selected Applications (Butterworth-Heinemann, Boston, 1991), p. 206.
29. Krieger, I. M., " Rheology of monodisperse lattices.," Adv. Colloid Interface Sci. 0001-8686 3, 111-136 (1972). 10.1016/0001-8686(72)80001-0
30. Krieger, I. M., and T. J. Dougherty, " A mechanism for non-Newtonian flow in suspensions of rigid spheres.," Trans. Soc. Rheol. 0038-0032 3, 137-152 (1959). 10.1122/1.548848
31. Laun, H. M., " Rheological properties of aqueous polymer dispersions.," Angew. Makromol. Chem. 0003-3146 123/124, 335-359 (1984).
32. Laun, H. M., Rheological properties of polymer dispersions with respect to shear-induced particle structures, Progress and Trends in Rheology II. Supplement to Rheologica Acta., Proceedings of the Second Conference of European Rheologists, Prague, 1986, pp. 287-290.
33. Ming, Y., K. Takamura, H. T. Davis, and L. E. Scriven, " Microstructure evolution in latex coatings.," Tappi J. 0734-1415 78, 151-159 (1995).
34. Ohshima, H., " Primary electroviscous effect in a suspension of soft particles.," Langmuir 0743-7463 24 (13), 6453-6461 (2008). 10.1021/la800027m
35. Papir, Y. S., and I. M. Krieger, " Rheological studies on dispersions of uniform colloidal spheres: II. Dispersions in nonaqueous media.," J. Colloid Interface Sci. 0021-9797 34, 126-130 (1970). 10.1016/0021-9797(70)90265-1
36. Polymer Dispersions and Their Industrial Applications, edited by, D. Urban, and, K. Takamura, (Wiley-VCH, Weinheim, 2002). 10.1002/3527600582
37. Quemada, D., " Rheology of concentrated disperse systems and minimum energy dissipation principle.," Rheol. Acta 0035-4511 16, 82-94 (1977). 10.1007/BF01516932
38. Rubio-Hernández, F. J., A. I., Gómez-Merino, E. Ruiz-Reina, and C. Carnero-Ruiz, " The primary electroviscous effect of polystyrene latexes.," Colloids Surf., A 0927-7757 140, 295-298 (1998). 10.1016/S0927-7757(97)00286-0 (Pubitemid 28341723)
39. Russel, W. B., " The rheology of suspensions of charged rigid spheres.," J. Fluid Mech. 0022-1120 85, 209-232 (1978). 10.1017/S0022112078000609
40. Sakota, K., and T. Okaya, " Preparation and characterization of carboxylated isoprene/styrene copolymer latexes.," J. Appl. Polym. Sci. 0021-8995 20, 1735-1744 (1976). 10.1002/app.1976.070200702
41. Sheehan, J. G., K. Takamura, H. T. Davis, and L. E. Scriven, " Microstructure development in particulate coatings examined with high-resolution cryogenic scanning electron microscopy.," Tappi J. 0734-1415 76, 93-101 (1993).
42. Takamura, K., Polymer Colloids, Kirk-Othmer Encyclopedia of Chemical Technology (Wiley, New York, 2003).
43. Tomita, M., K. Takano, and T. G. M. van de Ven, " An optical method for studying the properties of ordered latices.," J. Colloid Interface Sci. 0021-9797 92, 367-382 (1983). 10.1016/0021-9797(83)90159-5
44. Tomita, M., and T. G. M. van de Ven, " Calculation of diffraction angles in ordered latices.," J. Colloid Interface Sci. 0021-9797 100, 112-115 (1984). 10.1016/0021-9797(84)90416-8
45. van de Ven, T. G. M., Colloidal Hydrodynamics (Academic, London, 1989).
46. van der Werff, J. C., and C. G. de Kruif, " Hard-sphere colloidal dispersions: The scaling of rheological properties with particle size, volume fraction and shear rate.," J. Rheol. 0148-6055 33, 421 (1989). 10.1122/1.550062
47. Wagner, N. J., and J. W. Bender, " The role of nanoscale forces in colloidal dispersion rheology.," MRS Bull. 0883-7694 29, 100-106 (2004).
48. Wang, Y. L., " Electroviscous effects of concentrated polystyrene latexes.," J. Colloid Interface Sci. 0021-9797 32, 633-641 (1970). 10.1016/0021-9797(70)90156-6
49. Woods, M. E., and I. M. Krieger, " Rheological studies on dispersions of uniform colloidal spheres. I. Aqueous dispersions in steady shear flow.," J. Colloid Interface Sci. 0021-9797 34, 91-99 (1970). 10.1016/0021-9797(70)90262-6
50. Zosel, A., W. Heckmann, G. Ley, and W. Mächtle, " Chemical heterogeneity in emulsion copolymers of carboxylic monomers.," Colloid Polym. Sci. 0303-402X 265, 113-125 (1987). 10.1007/BF01412754