Bis(β-ketoamino)copper(II)/methylaluminoxane systems for homo- And copolymerizations of methyl acrylate and 1-hexene

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 48, Issue 5, 2010, Pages 1113-1121

  Gao, Haiyang ^a   Liu, Xiaofang ^a   Pei, Lixia ^b   Wu, Qing ^a  

^a SUN YAT SEN UNIVERSITY   (China)

^b SOUTH CHINA UNIVERSITY OF TECHNOLOGY   (China)

Author keywords

Copolymerizatlon; Monomers; Organometallic catalysts; Radical polymerization

Indexed keywords

1-HEXENE; ATACTIC; COPPER COMPLEXES; FINEMAN-ROSS METHOD; HEXENES; METHYL ACRYLATES; METHYLALUMINOXANE; ORGANOMETALLIC CATALYSTS; POLY(METHYL ACRYLATE); POLYMERIZATION MECHANISMS; RADICAL MECHANISM; RADICAL POLYMERIZATION; REACTIVITY RATIO;

ATOM TRANSFER RADICAL POLYMERIZATION; CATALYSIS; CATALYSTS; COPOLYMERIZATION; COPPER; MONOMERS; ORGANOMETALLICS;

COPPER COMPOUNDS;

EID: 76249090446     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.23867     Document Type: Article

References (50)

1. Boffa, L. S.; Novak, B. M. Chem Rev 2000, 100, 1479-1494.
2. Gibson, V. C.; Sptzmesser, S. K. Chem Rev 2003, 103, 283-316.
3. Berkefeld, A.; Mecking, S. Angew Chem Int Ed 2008, 47, 2538-2542.
4. Johnson, L. K.; Mecking, S.; Brookhart, M. J Am Chem Soc 1996, 118, 267-268.
5. Mecking, S.; Johnson, L. K.; Wang, L.; Brookhart, M. J Am Chem Soc 1998, 120, 888-899.
6. Wang, C.; Friedrich, S.; Younkin, T. R.; Li, R. T.; Grubbs, R. H.; Bansleben, D. A.; Day, M. W. Organometallics 1998, 17, 3149-3151.
7. Younkin, T. R.; Conner, E. F.; Henderson, J. I.; Friedrich, S. K.; Grubbs, R. H.; Bansleben, D. A. Science 2000, 287, 460-462.
8. Drent, E.; van Dijk, R.; van Ginkel, R.; van Oort, B.; Pugh, R. I. Chem Commun 2002, 744-745.
9. Li, X.-F.; Li, Y.-G.; Li, Y.-S.; Chen, Y.-X.; Hu, N.-H. Organometallics 2005, 24, 2502-2510.
10. Carlini, C.; De Luise, V.; Martinelli, M.; Raspolli Galletti, A. M.; Sbrana, G. J Polym Sci Part A: Polym Chem 2005, 44, 620-633.
11. Sen, A.; Borkar, S. J Organomet Chem 2007, 692, 3291-3299.
12. Wang, J.; Ye, Z.; Joly, H. Macromolecules 2007, 40, 6150-6163.
13. Chen, G.; Ma, X.; Guan, Z. J Am Chem Soc 2003, 125, 6697-6704.
14. Luo, S.; Jordan, R. F. J Am Chem Soc 2006, 128, 12072-12073.
15. Stibrany, R. T.; Schulz, D. N.; Kacker, S.; Patli, A. O. (Exxon). World Intellectual Property Organization Patent WO 99/30822, June 24, 1999.
16. Stibrany, R. T.; Schulz, D. N.; Kacker, S.; Patil, A. O. (Exxon). U.S. Patent 6,037,297, March 14, 2000.
17. Stibrany, R. T. (Exxon). U.S. Patent 6,180,788, January 30, 2001.
18. Stibrany, R. T.; Schulz, D. N.; Kacker, S.; Patil, A. O. (Exxon-Mobil). U.S. Patent 6,417,303, July 9, 2002.
19. Gibson, V. C.; Tomov, A.; Wass, D. F.; White, A. J Chem Soc, J. P. Dalton Trans 2002, 2261-2268.
20. Bushuev, M. B.; Krivopalov, V. P.; Semikolenova, N. V.; Peresypkina, E. V.; Virovets, A. V.; Sheludyakova, L. A.; Lavrenova, L. G.; Zakharov, V. A.; Larionov, S. V. Russ J Coord Chem 2006, 32, 208-213.
21. Larionov, S. V.; Savel'eva, Z. A.; Semikolenova, N. V.; Klevtsova, R. F.; Glinskaya, L. A.; Boguslavskii, E. G.; Ikorskii, V. N.; Zakharov, V. A.; Popov, S. A.; Tkachev, A. V. Russ J Coord Chem 2007, 33, 436-448.
22. Stibrany, R. T.; Schulz, N. D.; Kacker, S.; Patil, A. O.; Baugh, L. S.; Rucker, S. P.; Zushma, S.; Berluche, E.; Sissano, J. A. Macromolecules 2003, 36, 8584-8586.
23. Baugh, L. S.; Sissano, J. A.; Kacker, S.; Berluche, E.; Stibrany, R. T.; Schulz, D. N.; Rucker, S. P. J Polym Sci Part A: Polym Chem 2006, 44, 1817-1840.
24. Gallette, A. M. R.; Carlini, C.; Giaiacopi, S.; Martinelli, M.; Sbrana, G. J Polym Sci Part A: Polym Chem 2007, 45, 1134-1142.
25. Nagel, M.; Paxton, W. F.; Sen, A.; Zakharov, L.; Rheingold, A. L. Macromolecules 2004, 37, 9305-9307.
26. Olson, J. A.; Boyd, R.; Quail, J. W.; Foley, F. R. Organometallics 2008, 27, 5333-5338.
27. Lu, X.-Q.; Bao, F.; Kang, B.-S.; Wu, Q.; Liu, H.-Q.; Zhu, F.-M. J Organomet Chem 2006, 691, 821-828.
28. Carlini, C.; Giaiacopi, S.; Marchetti, F.; Pinzino, C.; Galletti, A. M. R.; Sbrana, G. Organometallics 2006, 25, 3659-3664.
29. Huang, Y.; Tang, G.; Jin, G.; Jin, G. Organometallics 2008, 27, 259-269.
30. Tang, G.; Lin, Y.; Jin, G. J Organomet Chem 2007, 692, 4106-4112.
31. Chen, F.; Tang, G.; Jin, G. J Organomet Chem 2007, 692, 3435-3442.
32. He, X.; Yao, Y.; Luo, X.; Zhang, J.; Liu, Y.; Zhang, L.; Wu, Q. Organometallics 2003, 22, 4952-4957.
33. 2 = 0.0844 ([I > 2σ(I)]), 0.0906 (all data). Crystallography data for the structures in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication numbers CCDC 735805. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
34. Knock, R.; Wilk, A.; Wannowius, K. J.; Reinen, D.; Elias, H. Inorg Chem 1990, 29, 3799-3805.
35. Stabnikov, P. A.; Zharkova, G. I.; Baidina, I. A.; Tkachev, S. V.; Krisyuk, V. V.; Igumenov I. K. Polyhedron 2007, 26, 4445-4450.
36. Matsuzaki, K.; Uryu, T.; Ishida, A. J Polym Sci A-1: Polym Chem 1967, 5, 2167-2177.
37. Kawamura, T.; Toshima, N.; Matsuzaki, K. Macromol Chem Phys 1995, 196, 3415-3424.
38. Liu, S.; Elyashiv, S.; Sen, A. J Am Chem Soc 2001, 123, 12738-12739.
39. Tian, G.; Novak, B. M. Macromolecules, 2001, 34, 7656-7663.
40. Inoue, Y.; Nishioka, A.; Chujo, R. Makromol Chem 1972, 156, 207-223.
41. Gao, H.-Y.; Chen, Y.; Zhu, F.-M.; Wu, Q. J Polym Sci Part A: Polym Chem 2006, 44, 5237-5246.
42. Chen, Y.; Sen, A. Macromelcules 2009, 42, 3591-3597.
43. Shibayama, K. Polym J 2003, 35, 711-713.
44. For radical polymerization with AIBN, r(MA) = 9.56 ± 0.06 and r(hexene) = 0.00 ± 0.02 determined by a NLLS method (see reference 42). For insertion/coordination polymerization with α-diimine Pd catalyst r(MA) ≈ 0, because this catalyst cannot homopolymerize acrylate (see reference 5).
45. Gridnev, A. A.; Ittel S. D. Chem Rev 2001, 101, 3611-3660.
46. Elia, C.; Elyashiv-Barad S.; Sen A. Organometallics 2002, 21, 4249-4256.
47. Albeniz, A. C.; Espinet, P.; Lopez-Fernandez, R. Organometallics 2003, 22, 4206-4212.
48. Albeniz, A. C.; Espinet, P.; Lopez-Fernandez, R. J Polym Sci Part A: Polym Chem 2006, 44, 5682-5691.
49. Lopez-Fernandez, R.; Carrera, N.; Albeniz, A. C.; Espinet, P. Organometallics 2009, 28, 4996-5001.
50. Kochi, J. K. Free Radicals; Wiley: New York, 1973; Vol.1, p 50.