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Self-assembly from 1 mM ethanolic solutions or 10-50 wt % solutions in hexadecane was performed, resulting in identical monolayer films. Previous studies indicate that self-assembly on Hg occurs on a millisecond time scale. The typical self-assembly time was 1 min, Self-assembly times between 10 s and. 5 min resulted in identical films.
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Self-assembly from 1 mM ethanolic solutions or 10-50 wt % solutions in hexadecane was performed, resulting in identical monolayer films. Previous studies indicate that self-assembly on Hg occurs on a millisecond time scale. The typical self-assembly time was 1 min, Self-assembly times between 10 s and. 5 min resulted in identical films.
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2 independent of the end-group and the length of the thiol/selenol. The obtained data are similar to the desorption results obtained for n-alkanethiols on gold electrodes (see Kakiuchi, T.; Usui, H Hobara, D.; Yamamoto, M. Langmuir 2002,18, 5231).
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The capacitance was measured at 1, 5, and. 10 V/s within the potential range of 0 to -0.7 V versus SSCE. Impedance spectroscopy measurements yielded identical (within the experimental error) capacitance values
-
The capacitance was measured at 1, 5, and. 10 V/s within the potential range of 0 to -0.7 V versus SSCE. Impedance spectroscopy measurements yielded identical (within the experimental error) capacitance values
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51
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app to zero overpotential
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app to zero overpotential
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75749112405
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o is used to avoid inaccurate subtraction of the capacitive background current.
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o is used to avoid inaccurate subtraction of the capacitive background current.
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