Synthesis of oily core-hybrid shell nanocapsules through interfacial free radical copolymerization in miniemulsion: droplet formation and nucleation

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 48, Issue 3, 2010, Pages 593-603

  Cao, Z H ^a,b,c   Shan, G R ^a   Sheibat Othman, N ^c   Putaux, J L ^d   Bourgeat Lami, E ^b  

^a ZHEJIANG UNIVERSITY   (China)

^b UNIVERSITÉ LYON 1   (France)

^c UNIVERSITÉ LYON 1   (France)

^d CENTRE DE RECHERCHES SUR LES MACROMOLÉCULES VÉGÉTALES CERMAV CNRS   (France)

Author keywords

Cryo tem; Hybrid nanocapsules; Miniemulsion (co)polymerization; Morphology; Nucleation; TEM

Indexed keywords

DIMENSIONAL STABILITY; DROPS; FREE RADICALS; HIGH RESOLUTION TRANSMISSION ELECTRON MICROSCOPY; MORPHOLOGY; NANOCAPSULES; NANOPARTICLES; PHASE INTERFACES; PHASE SEPARATION; POLYMERIZATION; SHELLS (STRUCTURES); STYRENE; SURFACE ACTIVE AGENTS; TRANSMISSION ELECTRON MICROSCOPY;

CRYO-TEM; CRYOGENIC TRANSMISSION ELECTRON MICROSCOPY; FREE RADICAL COPOLYMERIZATION; HYBRID NANOCAPSULES; MINIEMULSIONS; ORGANIC/INORGANIC HYBRIDS; POLYMERIZATION INDUCED PHASE SEPARATIONS; SURFACTANT CONCENTRATIONS;

NUCLEATION;

EID: 75749096055     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.23809     Document Type: Article

References (55)

1. Qiu, X.; Leporatti, S.; Donath, E.; Mohwald, H. Langmuir 2001, 17, 5375-5380.
2. He, J.; Yoneyama, Y.; Xu, B.; Nishiyama, N.; Tsubaki, N. Langmuir 2005, 21, 1699-1702.
3. Caruso, F.; Trau, D.; Mohwald, H.; Renneberg, R. Langmuir 2000, 16, 1485-1488.
4. Stockton, W. B.; Rubner, M. F. Macromolecules 1997, 30, 2717-2725.
5. Caruso, F.; Caruso, R. A.; Mohwald, H. Science 1998, 282, 1111-1114.
6. Gao, C. Y.; Leporatti, S.; Moya, S.; Donath, E.; Möhwald, H. Langmuir 2001, 17, 3491-3495.
7. Kida, T.; Mourl, M.; Akashi M. Angew Chem Int Ed 2006, 45, 7534-7536.
8. Such, G. K.; Tjipto, E.; Postma, A.; Johnston, A. P. R.; Caruso, F. Nano Lett 2007, 7, 1706-1710.
9. Huang, H.; Remsen, E. E.; Kowalewski, T.; Wooley, K. L. J Am Chem Soc 1999, 121, 3805-3806.
10. Liu, X. Y.; Jiang, M.; Yang, S. L.; Chen, M. Q.; Chen, D. Y.; Yang, C.; Wu, K. Angew Chem Int Ed 2002, 41, 2950-2953.
11. Jiang, P.; Bertone, J. F.; Colvin, V. L. Science 2001, 291, 453-457.
12. (a) The reader is invited to refer to the following articles and references therein for a literature review on hollow particles and capsules: Yow, H. N.; Routh, A. F. Soft Matter 2006, 2, 940-349;
13. (b) Bourgeat-Lami, E. In: Colloidal Polymers, Surfactant Series. Elaïssari, A., Ed.; Marcel Dekker: New York, 2003; Vol.115, Chapters, pp 189-224.
14. Sun, Q.; Deng, Y. J. Am Chem Soc 2005, 127, 8274-8275.
15. Wu, D.; Scott, C.; Ho, C.-C.; Co, C. C. Macromolecules 2006, 39, 5848-5853.
16. Underhill, R. S.; Jovanovic, A. V.; Carino, S. R.; Varshney, M.; Shah, D. O.; Dennis, D. M.; Morey, T. E.; Duran, R. S. Chem Mater 2002, 14, 4919-4925.
17. Jovanovic, A. V.; Underhill, R. S.; Bucholz, T. L.; Duran, R. S. Chem Mater 2005, 17, 3375-3383.
18. Torini, L.; Argillier, J.-F.; Zydowicz, N. Macromolecules 2005, 38, 3225-3236.
19. Crespy, D.; Stark, M.; Hoffmann-Richter, C.; Ziener, U.; Landfester, K. Macromolecules 2007, 40, 3122-3135.
20. Tiarks, F.; Landfester, K.; Antonietti, M. Langmuir 2001, 17, 908-918.
21. Luo, Y. W.; Zhou, X. D. J Polym Sci Part A: Polym Chem 2004, 42, 2145-2154.
22. Crespy, D.; Musyanovych, A.; Landfester, K. Colloid Polym Sci 2006, 284, 780-787.
23. Ni, K. F.; Shan, G. R.; Weng, Z. X. Macromolecules 2006, 39, 2529-2535.
24. Kim, Y.; Sudol, D.; Dimonie, V.; El-Aasser M. Key Eng Mater 2006, 306-306, 1091-1096.
25. Koh, H.-D.; Lee, J.-S. Macromol Rapid Commun 2007, 28, 315-321.
26. Chen, Y.; Liu, H.; Zhang, Z.; Wang, S. Eur Polym J 2007, 43, 2848-2855.
27. Lu, H.; Lin, Q.; Zhao, D.; Yao, T.; Zhang, K.; Zhang, J.; Yang, B. e-Polymer 2007, 50, 1-10.
28. Luo, Y. W.; Gu, H. Y. Polymer 2007, 48, 3262-3272.
29. van Zyl, A. J. P.; Bosch, R. F. P.; McLeary, J. B.; Sanderson, R. D.; Klumperman, B. Polymer 2005, 46, 3607-3615.
30. (a) Luo, Y. W.; Gu, H. Y. Macromol Rapid Commun 2006, 27, 21-25;
31. (b) Lu, F. J.; Luo, Y. W.; Li, B. G. Macromol Rapid Commun 2007, 28, 868-874.
32. Scott, C.; Wu, D.; Ho, C. C.; Co, C. C. J Am Chem Soc 2005, 127, 4160-4161.
33. (a) Cao, Z. H.; Cui, Q. M.; Shan, G. R. Acta Polym Sinica 2007, 12, 1116-1120;
34. (b) Cao, Z. H.; Shan, G. R. Chem J Chin Universities 2008, 29, 201-205.
35. Arshady, R.; Georges, M. H. Polym Eng Sci 1993, 33, 865-876.
36. (a) Tissot, I.; Novat, C.; Lefebvre, F.; Bourgeat-Lami, E. Macromolecules 2001, 34, 5737-5739;
37. (b) Tissot, I.; Reymond, J. P.; Lefebvre, F.; Bourgeat-Lami, E. Chem Mater 2002, 14, 1325-1331.
38. (a) Ni, K. F.; Shan, G. R.; Weng, Z. X.; Sheibat-Othman, N.; Fevotte, G.; Lefebvre, F.; Bourgeat-Lami, E. Macromolecules 2005, 38, 7321-7329;
39. (b) Ni, K. F.; Sheibat-Othman, N.; Shan, G. R.; Fevotte, G.; Bourgeat-Lami, E. Macromolecules 2005, 38, 9100-9109.
40. Cao, Z. H.; Bourgeat-Lami, E.; Sheibat-Othman, N.; Shan, G. R.; Fevotte, G. Macromolecules 2008, 41, 5166-5173.
41. Zhang, S. W.; Zhou, S. X.; Weng, Y. M.; Wu, L. M. Langmuir 2006, 22, 4674-4679.
42. Marcu, I.; Daniels, E. S.; Dimonie, V. L.; Hagiopol, C.; Roberts, J. E.; El-Aasser, M. S. Macromolecules 2003, 36, 328-332.
43. The z-average diameter is the mean diameter based on the intensity of scattered light.
44. Harris, J. R. Negative Staining and Cryoelectron Microscopy: The Thin Films Techniques; Bios Scientific Publishers: Oxford, U.K., 1997.
45. Lin, M.; Chu, F.; Guyot, A.; Putaux, J.-L.; Bourgeat-Lami, E. Polymer 2005, 46, 1331-1337.
46. Negrete-Herrera, N.; Putaux, J. L.; David, L.; Bourgeat-Lami, E. Macromolecules 2006, 39, 9177-9184.
47. Ostwald ripening involves the diffusive migration of individual dispersed molecules from smaller droplets which have a higher Laplace pressure to larger droplets of lower Laplace pressure.
48. Asua, J. M. Prog Polym Sci 2002, 27, 1283-1346.
49. Li, G.; Prasad, S.; Dhinojwala, A. Langmuir 2007, 23, 9929-9932.
50. Huibers, P. D. T.; Katritzky, A. R. J Chem Int Comput Sci 1998, 38, 283-292.
51. Huang, X.; Sudol, E. D.; Dimonie, V. L.; Anderson, C. D.; ElAasser, M. S. Macromolecules 2006, 39, 6944-6950.
52. Derjaguln, B. Kolloid-Z 1934, 69, 155-164.
53. Weiss, J.; Herrmann, N.; Mc Clements, D. J. Langmuir 1999, 15, 6652-6657.
54. Hyungchul, K.; Burgess D. J. J Colloid Interface Sci 2001, 241, 509-513.
55. Erdem, B.; Sully, Y.; Sudol, E. D.; Dimonie, V.; El-Aasser, M. S. Langmuir 2000, 16, 4890-4895.