Low-temperature catalytic oxidation of aldehyde mixtures using wood fly ash: Kinetics, mechanism, and effect of ozone

Chemosphere

Volumn 78, Issue 9, 2010, Pages 1110-1115

  Kolar, Praveen ^a   Kastner, James R ^b  

^a North Carolina State University   (United States)

^b University of Georgia   (United States)

Author keywords

Catalyst; Low temperature; Odors; Rendering; VOCs

Indexed keywords

ACTIVATION ENERGY; AIR POLLUTION; BINARY MIXTURES; CARBON DIOXIDE; CATALYST ACTIVITY; CATALYSTS; FLY ASH; FREE RADICAL REACTIONS; METALS; ODORS; OXIDANTS; OXIDATION; OZONE; REACTION KINETICS; SCRUBBERS; TEMPERATURE; VOLATILE ORGANIC COMPOUNDS; WATER POLLUTION; WATER TREATMENT;

LOW TEMPERATURES; METAL OXIDE CATALYSTS; OXIDATION RATES; PARTICULATE MATTER; PLUG FLOW REACTOR; RENDERING; RENDERING FACILITY; TREATMENT TECHNOLOGIES;

CATALYTIC OXIDATION;

2 BUTANONE; 2 METHYLBUTANAL; ALDEHYDE DERIVATIVE; CARBON DIOXIDE; HEXANAL; ISOVALERALDEHYDE; METAL OXIDE; OXYGEN; OZONE; UNCLASSIFIED DRUG; VOLATILE ORGANIC COMPOUND;

ACTIVATION ENERGY; ALDEHYDE; ATMOSPHERIC POLLUTION; CATALYSIS; FLY ASH; LOW TEMPERATURE; ODOR; OXIDATION; OZONE; POLLUTANT REMOVAL; REACTION KINETICS; VOLATILE ORGANIC COMPOUND;

AIR POLLUTION; ANALYTIC METHOD; ARTICLE; CHEMICAL ANALYSIS; CHEMICAL REACTION KINETICS; CONCENTRATION (PARAMETERS); CONTROLLED STUDY; FLY ASH; LOW TEMPERATURE PROCEDURES; NONHUMAN; OXIDATION; PLUG FLOW REACTOR; SCRUBBER; WOOD ASH;

EID: 75449099053     PISSN: 00456535     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemosphere.2009.12.033     Document Type: Article

References (24)

1. 4. Appl. Catal. B-Environ. 16 (1998) 43-51
2. Baumann M.G.D., Lorenz L.F., Batterman S.A., and Zhang G.Z. Aldehyde emissions from particle board and medium density fiber board products. Forest Prod. J. 50 (2000) 75-82
3. Brewer M.S., Vega J.D., and Perkins E.G. Volatile compounds and sensory characteristics of frying fats. J. Food Lipids 6 (1999) 47-61
4. Demeyer J.C., Nkana V., and Verloo M.G. Characteristics of wood ash and influence on soil properties and nutrient uptake: an overview. Biores. Technol. 7 (2001) 287-295
5. Everaert K., and Baeyens J. Catalytic combustion of volatile organic compounds. J. Hazard. Mater. 109 (2004) 113-139
6. Fullana A., Barrachina A.A.C., and Sidhu S. Volatile aldehyde emissions from heated cooking oils. J. Sci. Food Agr. 84 (2004) 2015-2021
7. Gangwal S.K., Mullins M.E., Spivey J.J., Caffery P.R., and Tichenor B.A. Kinetics and selectivity of deep catalytic oxidation of n-heptane and benzene. Appl. Catal. 36 (1998) 231-247
8. Gervasini A., and Ragaini V. Catalytic technology assisted with ionization/ozonization phase for the abatement of volatile organic compounds. Catal. Today 60 (2000) 129-138
9. Haisman V., Stampachova P., Vcelak J., and Chvalovsky V. The oxidation of aldehydes to carboxylic acids and accompanying side reactions. Oxid. Commun. 4 (1983) 229-236
10. Kastner J.R., and Das K.C. Wet scrubber analysis of volatile organic compound removal in the rendering industry. J. Air Waste Manage. 52 (2002) 459-469
11. Kastner J.R., and Das K.C. Comparison of chemical wet scrubbers and biofiltration for VOC control using GC/MS. techniques and kinetic analysis. J. Chem. Technol. Biotechnol. 80 (2005) 1170-1179
12. Kastner J.R., Hue C., Das K.C., and McClendon R. Effect of pH and temperature on the kinetics of odor oxidation using chlorine dioxide. J. Air Waste Manage. 53 (2003) 1218-1224
13. Kastner J.R., Buquoi Q., Ganagavaram R., and Das K.C. Catalytic ozonation of gaseous reduced sulfur compounds using wood fly ash. Environ. Sci. Technol. 39 (2005) 1835-1842
14. Kastner J.R., Gangavaram R., Kolar P., Xu C., and Teja A. Catalytic ozonation kinetics of propanal using wood fly ash and metal nanoparticle impregnated carbon. Environ. Sci. Technol. 42 (2008) 556-562
15. Klose F., Scholz P., Kreisel G., Ondruschka B., Kneise R., and Knopf U. Catalysts from waste materials. Appl. Catal. B-Environ. 28 (2000) 209-221
16. Kolar P., Kastner J.R., and Miller J. Low temperature catalytic oxidation of aldehydes using wood fly ash and molecular oxygen. Appl. Catal. B-Environ. 76 (2007) 203-217
17. Larkin D. The role of catalysts in the air oxidation of aliphatic aldehydes. J. Org. Chem. 55 (1990) 1563-1568
18. Lehtinen C., and Brunow G. Factors affecting the selectivity of air oxidation of 2-ethylhexanal, an - branched aliphatic aldehyde. Org. Process Res. Dev. 4 (2000) 544-549
19. Liakopoulos C., Poulopoulos S., and Philippopoulos C. Kinetic studies of acetaldehyde oxidation over Pt/Rh and Pd monolithic catalysts in a spinning-basket flow reactor. Ind. Eng. Chem. Res. 40 (2001) 1476-1481
20. 3-aldehyde reactions. Int. J. Chem. Kinet. 14 (1982) 237-249
21. 2 xerogels under ambient, dark conditions. Langmuir 21 (2005) 2273-2280
22. Sheldon R.A., and Kochi J.K. Metal-Catalyzed Oxidations of Organic Compounds (1981), Academic Press, New York
23. 2 mixed oxide catalysts for complete oxidation of formaldehyde: Effect of preparation method and calcination temperature. Appl. Catal. B-Environ. 62 (2006) 265-273
24. Tsou J., Pinard L., Magnoux P., Figueiredo J.L., and Guisnet M. Catalytic oxidation of volatile organic compounds (VOCs): Oxidation of o-xylene over Pt/HBEA catalysts. Appl. Catal. B-Environ. (2003) 371-379