메뉴 건너뛰기




Volumn 75, Issue 1-4, 2004, Pages 55-75

Analysis of reaction kinetics, speciation and mechanism of gold leaching and thiosulfate oxidation by ammoniacal copper(II) solutions

Author keywords

Ammoniacal copper(II); Gold leaching; Kinetic models; Reaction mechanism; Thiosulfate

Indexed keywords

ADSORPTION; AMMONIA; COPPER COMPOUNDS; DIMERIZATION; LEACHING; MATHEMATICAL MODELS; OXIDATION; REACTION KINETICS; REDOX REACTIONS; SOLUTIONS;

EID: 7544220616     PISSN: 0304386X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.hydromet.2004.06.004     Document Type: Article
Times cited : (110)

References (46)
  • 2
    • 0035251503 scopus 로고    scopus 로고
    • Thiosulfate leaching of gold - A review
    • Aylmore, M.G., Muir, D.M., 2001. Thiosulfate leaching of gold - a review. Miner. Eng. 14, 135-174.
    • (2001) Miner. Eng. , vol.14 , pp. 135-174
    • Aylmore, M.G.1    Muir, D.M.2
  • 3
    • 1642279460 scopus 로고    scopus 로고
    • Towards an understanding of copper(I) speciation and reactivity in the copperammonia-thiosulfate lixiviant system
    • Young, C.A., Alfantazi, A.M., Anderson, C.G., Dreisinger, D.B., Harris, B., James, A. (Eds.), TMS, Warrendale
    • Black, J., Spiccia, L., McPhail, D.C., 2003. Towards an understanding of copper(I) speciation and reactivity in the copperammonia-thiosulfate lixiviant system. In: Young, C.A., Alfantazi, A.M., Anderson, C.G., Dreisinger, D.B., Harris, B., James, A. (Eds.), Hydrometallurgy 2003, Leaching and Solution Purification vol. 1. TMS, Warrendale, pp. 183-194.
    • (2003) Hydrometallurgy 2003, Leaching and Solution Purification , vol.1 , pp. 183-194
    • Black, J.1    Spiccia, L.2    McPhail, D.C.3
  • 4
    • 0034275968 scopus 로고    scopus 로고
    • Thiosulfate leaching kinetics of gold in the presence of copper and ammonia
    • Breuer, P.L., Jeffrey, M.I., 2000. Thiosulfate leaching kinetics of gold in the presence of copper and ammonia. Miner. Eng. 13, 1071-1081.
    • (2000) Miner. Eng. , vol.13 , pp. 1071-1081
    • Breuer, P.L.1    Jeffrey, M.I.2
  • 5
    • 0038515440 scopus 로고    scopus 로고
    • The reduction of copper(II) and the oxidation of thiosulfate and oxysulfur anions in gold leaching solutions
    • Breuer, P.L., Jeffrey, M.I., 2003a. The reduction of copper(II) and the oxidation of thiosulfate and oxysulfur anions in gold leaching solutions. Hydrometallurgy 70, 163-173.
    • (2003) Hydrometallurgy , vol.70 , pp. 163-173
    • Breuer, P.L.1    Jeffrey, M.I.2
  • 6
    • 1642357490 scopus 로고    scopus 로고
    • A review of the chemistry, electrochemistry and kinetics of the gold thiosulfate leaching process
    • Young, C.A., Alfantazi, A.M., Anderson, C.G., Dreisinger, D.B., Harris, B., James, A. (Eds.), TMS, Warrendale
    • Breuer, P.L., Jeffrey, M.I., 2003b. A review of the chemistry, electrochemistry and kinetics of the gold thiosulfate leaching process. In: Young, C.A., Alfantazi, A.M., Anderson, C.G., Dreisinger, D.B., Harris, B., James, A. (Eds.), Hydroraetallurgy 2003, Leaching and Solution Purification vol. 1. TMS, Warrendale, pp. 139-154.
    • (2003) Hydroraetallurgy 2003, Leaching and Solution Purification , vol.1 , pp. 139-154
    • Breuer, P.L.1    Jeffrey, M.I.2
  • 7
    • 1342264323 scopus 로고    scopus 로고
    • The effect of ionic strength and buffer choice on the decomposition of tetrathionate in alkaline solutions
    • Breuer, P.L., Jeffrey, M.I., 2003c. The effect of ionic strength and buffer choice on the decomposition of tetrathionate in alkaline solutions. Hydrometallurgy 72, 335-338.
    • (2003) Hydrometallurgy , vol.72 , pp. 335-338
    • Breuer, P.L.1    Jeffrey, M.I.2
  • 8
    • 37049125754 scopus 로고
    • Kinetics and mechanism of the oxidation of thiosulphate ions by copper(II) ions in aqueous ammonia solutions
    • Byerley, J.J., Fouda, S.A., Rempel, G.L., 1973a. Kinetics and mechanism of the oxidation of thiosulphate ions by copper(II) ions in aqueous ammonia solutions. J. Chem. Soc. Dalton Trans., 889-893.
    • (1973) J. Chem. Soc. Dalton Trans. , pp. 889-893
    • Byerley, J.J.1    Fouda, S.A.2    Rempel, G.L.3
  • 9
    • 0001534976 scopus 로고
    • The oxidation of thiosulfate in aqueous ammonia by copper(II) oxygen complexes
    • Byerley, J.J., Fouda, S.A., Rempel, G.L., 1973b. The oxidation of thiosulfate in aqueous ammonia by copper(II) oxygen complexes. Inorg. Nucl. Chem. Lett. 9, 879-883.
    • (1973) Inorg. Nucl. Chem. Lett. , vol.9 , pp. 879-883
    • Byerley, J.J.1    Fouda, S.A.2    Rempel, G.L.3
  • 10
    • 37049133855 scopus 로고
    • Activation of copper(II) amine complexes by molecular oxygen for the oxidation of thiosulfate ions
    • Byerley, J.J., Fouda, S.A., Rempel, G.L., 1975. Activation of copper(II) amine complexes by molecular oxygen for the oxidation of thiosulfate ions. J. Chem. Soc. Dalton Trans., 1329-1338.
    • (1975) J. Chem. Soc. Dalton Trans. , pp. 1329-1338
    • Byerley, J.J.1    Fouda, S.A.2    Rempel, G.L.3
  • 11
    • 0037366697 scopus 로고    scopus 로고
    • The impact of thiosulfate oxidation products on the oxidation of gold in ammonia thiosulfate solutions
    • Chu, C.K., Breuer, P.L., Jeffrey, M.I., 2003. The impact of thiosulfate oxidation products on the oxidation of gold in ammonia thiosulfate solutions. Miner. Eng. 16, 265-271.
    • (2003) Miner. Eng. , vol.16 , pp. 265-271
    • Chu, C.K.1    Breuer, P.L.2    Jeffrey, M.I.3
  • 12
    • 0036470617 scopus 로고    scopus 로고
    • Leaching behaviour of sulphides in ammoniacal thiosulphate systems
    • Feng, D., Van Deventer, J.S.J., 2002. Leaching behaviour of sulphides in ammoniacal thiosulphate systems. Hydrometallurgy 63, 189-200.
    • (2002) Hydrometallurgy , vol.63 , pp. 189-200
    • Feng, D.1    Van Deventer, J.S.J.2
  • 13
    • 0037380488 scopus 로고    scopus 로고
    • Leaching and recovery of gold using ammoniacal thiosulfate leach liquors (a review)
    • Grosse, A.C., Dicinoski, G.W., Shaw, M.J., Haddad, P.R., 2003. Leaching and recovery of gold using ammoniacal thiosulfate leach liquors (a review). Hydrometallurgy 69, 1-21.
    • (2003) Hydrometallurgy , vol.69 , pp. 1-21
    • Grosse, A.C.1    Dicinoski, G.W.2    Shaw, M.J.3    Haddad, P.R.4
  • 15
    • 0035284090 scopus 로고    scopus 로고
    • Kinetic aspects of gold and silver leaching in ammonia-thiosulfate solutions
    • Jeffrey, M.I., 2001. Kinetic aspects of gold and silver leaching in ammonia-thiosulfate solutions. Hydrometallurgy 60, 7-16.
    • (2001) Hydrometallurgy , vol.60 , pp. 7-16
    • Jeffrey, M.I.1
  • 16
    • 0141570867 scopus 로고    scopus 로고
    • The importance of controlling oxygen addition during the thiosulfate leaching of gold ores
    • Jeffrey, M.I., Breuer, P.L., Chu, C.K., 2003. The importance of controlling oxygen addition during the thiosulfate leaching of gold ores. Int. J. Miner. Process. 72, 323-330.
    • (2003) Int. J. Miner. Process. , vol.72 , pp. 323-330
    • Jeffrey, M.I.1    Breuer, P.L.2    Chu, C.K.3
  • 17
    • 0003104090 scopus 로고
    • Electrochemistry and mechanism of leaching gold with ammoniacal thiosulphate
    • Sydney, 23-28 May. AusIMM, Melbourne
    • Jiang, T., Chen, J., Xu, S., 1993. Electrochemistry and mechanism of leaching gold with ammoniacal thiosulphate. Proc. 18th International Mineral Processing Congress, Sydney, 23-28 May. AusIMM, Melbourne, pp. 1141-1146.
    • (1993) Proc. 18th International Mineral Processing Congress , pp. 1141-1146
    • Jiang, T.1    Chen, J.2    Xu, S.3
  • 18
    • 0002686364 scopus 로고
    • A kinetic study of gold leaching with thiosulfate
    • Hiskey, J.B., Warren, G.W. (Eds.). AIME, Warrendale Chapter 7
    • Jiang, T., Chen, J., Xu, S., 1993. A kinetic study of gold leaching with thiosulfate. In: Hiskey, J.B., Warren, G.W. (Eds.), Hydrometallurgy, Fundamentals, Technology and Innovations. AIME, Warrendale, pp. 119-126. Chapter 7.
    • (1993) Hydrometallurgy, Fundamentals, Technology and Innovations , pp. 119-126
    • Jiang, T.1    Chen, J.2    Xu, S.3
  • 20
    • 1642279508 scopus 로고    scopus 로고
    • The importance of the Cu(II) catalyst in the thiosulfate leaching of gold
    • Young, C.A., Anderson, C.G., Dreisinger, D.B., Harris, B., James, A. (Eds.), TMS, Warrendale
    • Lam, A.E., Dreisinger, D.B., 2003. The importance of the Cu(II) catalyst in the thiosulfate leaching of gold. In: Young, C.A., Anderson, C.G., Dreisinger, D.B., Harris, B., James, A. (Eds.), Hydrometallurgy 2003, Leaching and Solution Purification vol. 1. TMS, Warrendale, pp. 195-211.
    • (2003) Hydrometallurgy 2003, Leaching and Solution Purification , vol.1 , pp. 195-211
    • Lam, A.E.1    Dreisinger, D.B.2
  • 21
    • 0003715646 scopus 로고    scopus 로고
    • Marcel Dekker, New York
    • Marcus, Y., 1997. Ion Properties. Marcel Dekker, New York.
    • (1997) Ion Properties
    • Marcus, Y.1
  • 22
    • 0036784236 scopus 로고    scopus 로고
    • The treatment of copper-gold ores by ammonium thiosulfate leaching
    • Molleman, E., Dreisinger, D., 2002. The treatment of copper-gold ores by ammonium thiosulfate leaching. Hydrometallurgy 66, 1-21.
    • (2002) Hydrometallurgy , vol.66 , pp. 1-21
    • Molleman, E.1    Dreisinger, D.2
  • 24
    • 0001711394 scopus 로고
    • Chemical behaviour of low valence sulfur compounds: V. Decomposition and oxidation of tetrathionate in aqueous ammonia solutions
    • Naito, K., Shieh, M.-C., Okabe, T., 1970. Chemical behaviour of low valence sulfur compounds: V. Decomposition and oxidation of tetrathionate in aqueous ammonia solutions. Bull. Chem. Soc. Jpn. 43 (5), 1372-1376.
    • (1970) Bull. Chem. Soc. Jpn. , vol.43 , Issue.5 , pp. 1372-1376
    • Naito, K.1    Shieh, M.-C.2    Okabe, T.3
  • 25
    • 0002361982 scopus 로고    scopus 로고
    • Recovery of gold from thiosulfate solutions and pulps with ion-exchange resins
    • Young, E.D., Tidwell, L.G., Anderson, C.G. (Eds.). TMS, Warrendale
    • Nicol, M.J., O'Malley, G.P., 2001. Recovery of gold from thiosulfate solutions and pulps with ion-exchange resins. In: Young, E.D., Tidwell, L.G., Anderson, C.G. (Eds.), Cyanide: Social, Industrial and Economic Aspects. TMS, Warrendale, pp. 469-483.
    • (2001) Cyanide: Social, Industrial and Economic Aspects , pp. 469-483
    • Nicol, M.J.1    O'Malley, G.P.2
  • 26
    • 0036811234 scopus 로고    scopus 로고
    • Recovering gold from thiosulfate leach pulps via ion exchange
    • Nicol, M.J., O'Malley, G.P., 2002. Recovering gold from thiosulfate leach pulps via ion exchange. J. Met. 54, 44-47.
    • (2002) J. Met. , vol.54 , pp. 44-47
    • Nicol, M.J.1    O'Malley, G.P.2
  • 28
    • 2442603480 scopus 로고    scopus 로고
    • The ammine, thiosutfato, and mixed ammine/thiosulfato complexes of silver(I) and gold(I)
    • Perera, W.N., Senanayake, G., 2004. The ammine, thiosutfato, and mixed ammine/thiosulfato complexes of silver(I) and gold(I). Inorg. Chem. 43, 3048-3056.
    • (2004) Inorg. Chem. , vol.43 , pp. 3048-3056
    • Perera, W.N.1    Senanayake, G.2
  • 29
    • 0012721148 scopus 로고
    • Equilibria and kinetics of the fast interaction between copper(II) and thiosulphate ion in aqueous solutions
    • Rabai, G., Epstein, I.R., 1992. Equilibria and kinetics of the fast interaction between copper(II) and thiosulphate ion in aqueous solutions. Inorg. Chem. 31, 3239-3242.
    • (1992) Inorg. Chem. , vol.31 , pp. 3239-3242
    • Rabai, G.1    Epstein, I.R.2
  • 30
    • 0006486355 scopus 로고    scopus 로고
    • Are there realistic alternatives to cyanide as a lixiviant tor gold at the present time?
    • Young, E.D., Tidwell, L.G., Anderson, C.G. (Eds.). TMS, Warrendale
    • Ritchie, I.M., Nicol, M.J., Staunton, W.P., 2001. Are there realistic alternatives to cyanide as a lixiviant tor gold at the present time? In: Young, E.D., Tidwell, L.G., Anderson, C.G. (Eds.), Cyanide: Social, Industrial and Economic Aspects. TMS, Warrendale, pp. 427-440.
    • (2001) Cyanide: Social, Industrial and Economic Aspects , pp. 427-440
    • Ritchie, I.M.1    Nicol, M.J.2    Staunton, W.P.3
  • 31
    • 0020361041 scopus 로고
    • Kinetics of decomposition of tetrathionate, torithionate and thiosulpbate in alkaline media
    • Rolia, F., Chakrabarti, C.L., 1982. Kinetics of decomposition of tetrathionate, torithionate and thiosulpbate in alkaline media. Environ. Sci Technol. 16 (12), 852-857.
    • (1982) Environ. Sci Technol. , vol.16 , Issue.12 , pp. 852-857
    • Rolia, F.1    Chakrabarti, C.L.2
  • 32
    • 2442685802 scopus 로고    scopus 로고
    • Gold leaching in non-cyanide lixiviant systems: Critical issues on fundamentals and applications
    • and references therein
    • Senanayake, G., 2004a. Gold leaching in non-cyanide lixiviant systems: critical issues on fundamentals and applications. Miner. Eng. 17, 785-801. (and references therein).
    • (2004) Miner. Eng. , vol.17 , pp. 785-801
    • Senanayake, G.1
  • 34
    • 7544224234 scopus 로고    scopus 로고
    • Role of copper(II), carbonate and sulphite in gold leaching and thiosulphate degradation by oxygenated alkaline non-ammoniacal solutions
    • in press
    • Senanayake, G., 2004c. Role of copper(II), carbonate and sulphite in gold leaching and thiosulphate degradation by oxygenated alkaline non-ammoniacal solutions. Miner. Eng, (in press).
    • (2004) Miner. Eng.
    • Senanayake, G.1
  • 35
    • 1642402871 scopus 로고    scopus 로고
    • Chloride processing of metal sulfides: Review of fundamentals and applications
    • Young, C.A., Alfentazi, A.M., Anderson, C.G., Dreisinger, D.B., Harris, B., James, A. (Eds.). TMS, Warrendale
    • Senanayake, G., Mnir, D.M., 2003. Chloride processing of metal sulfides: review of fundamentals and applications. In: Young, C.A., Alfentazi, A.M., Anderson, C.G., Dreisinger, D.B., Harris, B., James, A. (Eds.), Hydrometallurgy 2003, Leaching and Solution Purification vol. 1. TMS, Warrendale, pp. 517-531.
    • (2003) Hydrometallurgy 2003, Leaching and Solution Purification , vol.1 , pp. 517-531
    • Senanayake, G.1    Mnir, D.M.2
  • 36
    • 1642263227 scopus 로고    scopus 로고
    • Thermodynamic studies of the gold(III)/(I)/(0) redox system in ammonia-thiosulphate solutions at 25°C
    • Young, C.A., Alfantazi, AM., Anderson, C.G., Dreisinger, D.B., Harris, B., James, A. (Eds.), TMS, Warrendale
    • Senanayake, G., Perera, W.N., Nicol. M.J., 2003. Thermodynamic studies of the gold(III)/(I)/(0) redox system in ammonia-thiosulphate solutions at 25°C. In: Young, C.A., Alfantazi, AM., Anderson, C.G., Dreisinger, D.B., Harris, B., James, A. (Eds.), Hydrometallurgy 2003, Leaching and Solution Purification vol. 1. TMS, Warrendale, pp. 155-168.
    • (2003) Hydrometallurgy 2003, Leaching and Solution Purification , vol.1 , pp. 155-168
    • Senanayake, G.1    Perera, W.N.2    Nicol, M.J.3
  • 38
    • 0037655061 scopus 로고    scopus 로고
    • The hydrolysis of gold(I) in aqueous solutions to 600°C and 1500 bar
    • and references therein
    • Stefansson, A., Seward, T.M., 2003. The hydrolysis of gold(I) in aqueous solutions to 600°C and 1500 bar. Geochim. Cosmochim. Acta 67, 1677-1688. (and references therein).
    • (2003) Geochim. Cosmochim. Acta , vol.67 , pp. 1677-1688
    • Stefansson, A.1    Seward, T.M.2
  • 39
    • 0002684915 scopus 로고    scopus 로고
    • Importance of solution chemistry of thiosolfate leaching of gold
    • AnsIMM, Melbourne
    • Wan, R.Y., 1997. Importance of solution chemistry of thiosolfate leaching of gold. World Gold'97. AnsIMM, Melbourne, pp. 159-162.
    • (1997) World Gold'97 , pp. 159-162
    • Wan, R.Y.1
  • 40
    • 1642372273 scopus 로고    scopus 로고
    • Using thiocyanate as lixiviant for gold recovery in acidic envinronment
    • Young, C.A., Alfantazi, A.M., Anderson, C.G., Dreisinger, D.B., Harris, B., James, A. (Eds.), TMS, Warrendale
    • Wan, R.Y., Brierley, J.A., Acar, S., LeVier. K.M., 2003. Using thiocyanate as lixiviant for gold recovery in acidic envinronment. In: Young, C.A., Alfantazi, A.M., Anderson, C.G., Dreisinger, D.B., Harris, B., James, A. (Eds.), Hydrometallurgy 2003, Leaching and Solution Purification vol. 1. TMS, Warrendale, pp. 105-121.
    • (2003) Hydrometallurgy 2003, Leaching and Solution Purification , vol.1 , pp. 105-121
    • Wan, R.Y.1    Brierley, J.A.2    Acar, S.3    LeVier, K.M.4
  • 41
    • 0141459238 scopus 로고    scopus 로고
    • Solution chemistry fectors for gold thiosuifate heap leaching
    • Wan, R.Y., LeVier, K.M., 2003. Solution chemistry fectors for gold thiosuifate heap leaching. Int. J. Miner. Process. 72, 311-322.
    • (2003) Int. J. Miner. Process. , vol.72 , pp. 311-322
    • Wan, R.Y.1    LeVier, K.M.2
  • 42
    • 1642277852 scopus 로고    scopus 로고
    • A process for counter-acting the detrimental effect of tetrathionate on resin gold adsorption from thiosulfate leachates
    • Young, C.A., Alfantazi, A.M., Anderson, C.G., Dreisinger, D.H., Harris, B., James, A. (Eds.), TMS, Warrendale
    • West-Sells, P.G., Ji, J., Hackl, R.P., 2003. A process for counter-acting the detrimental effect of tetrathionate on resin gold adsorption from thiosulfate leachates. In: Young, C.A., Alfantazi, A.M., Anderson, C.G., Dreisinger, D.H., Harris, B., James, A. (Eds.), Hydrometallurgy 2003, Leaching and Solution Purification vol. 1. TMS, Warrendale, pp. 245-256.
    • (2003) Hydrometallurgy 2003, Leaching and Solution Purification , vol.1 , pp. 245-256
    • West-Sells, P.G.1    Ji, J.2    Hackl, R.P.3
  • 43
    • 0036784237 scopus 로고    scopus 로고
    • The kinetics for the decomposition of tetrathionate in alkaline solutions
    • Zhang, H.G., Dreisinger, D.B., 2002. The kinetics for the decomposition of tetrathionate in alkaline solutions. Hydrometallurgy 66 (1-3), 59-65.
    • (2002) Hydrometallurgy , vol.66 , Issue.1-3 , pp. 59-65
    • Zhang, H.G.1    Dreisinger, D.B.2
  • 44
    • 0141741740 scopus 로고    scopus 로고
    • An electrachemical study of the dissolution of gold in thiosulfate solutions: Part I. Alkaline solutions
    • Zhang, Z., Nicol, M.J., 2003. An electrachemical study of the dissolution of gold in thiosulfate solutions: Part I. Alkaline solutions. J. Appl. Electrochem. 33, 767-775.
    • (2003) J. Appl. Electrochem. , vol.33 , pp. 767-775
    • Zhang, Z.1    Nicol, M.J.2
  • 45
    • 4544385269 scopus 로고    scopus 로고
    • A study of the gold colloid dissolution kinetics in oxygenated ammoniacal thiosulfate solutions
    • in press
    • Zhang, X.M., Senanayake, G., Nicol, M.J., 2004. A study of the gold colloid dissolution kinetics in oxygenated ammoniacal thiosulfate solutions. Hydrometallurgy (in press).
    • (2004) Hydrometallurgy
    • Zhang, X.M.1    Senanayake, G.2    Nicol, M.J.3
  • 46
    • 0023828871 scopus 로고
    • Gold and silver extraction by ammoniacal thiosulphate leaching from a rhyolite ore
    • Zipperian, D., Raghavan, S., Wilson, J.P., 1988. Gold and silver extraction by ammoniacal thiosulphate leaching from a rhyolite ore. Hydroroetallurgy 19, 361-375.
    • (1988) Hydroroetallurgy , vol.19 , pp. 361-375
    • Zipperian, D.1    Raghavan, S.2    Wilson, J.P.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.