Phenylmodification of Mn-containing mesoporous silica and catalytic oxidation of toluene

Journal of Chemical Technology and Biotechnology

Volumn 85, Issue 2, 2010, Pages 283-287

  Wang, Min ^a,b   Chen, Chen ^a   Zhang, Qiaohong ^a   Du, Zhongtian ^a   Zhang, Zhan ^a,b   Gao, Jin ^a   Xu, Jie ^a  

^a DALIAN INSTITUTE OF CHEMICAL PHYSICS   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

Dioxygen; Hexagonalmesoporous silica; Phenyl modification; Toluene oxidation

Indexed keywords

BENZOIC ACID; CATALYST SURFACES; CATALYTIC OXIDATION OF TOLUENE; DIOXYGEN; DIOXYGENS; FINE CHEMICALS; HEXAGONAL MESOPOROUS SILICA; HYDROPHOBIC CHARACTER; INDUSTRIAL TECHNOLOGY; MESOPOROUS SILICA; ONE STEP SYNTHESIS; ORGANIC MODIFICATION; OXIDIZED PRODUCTS; PHENYL GROUP; SOLVENT FREE CONDITIONS; TOLUENE OXIDATION; WATER DROPLETS;

CATALYSIS; CATALYST ACTIVITY; CATALYST SELECTIVITY; CONTACT ANGLE; HYDROCARBONS; HYDROPHOBICITY; INDUSTRIAL CHEMICALS; MANGANESE; MANGANESE COMPOUNDS; MANGANESE REMOVAL (WATER TREATMENT); MESOPOROUS MATERIALS; ORGANIC SOLVENTS; REACTION INTERMEDIATES; SILICA; TOLUENE;

CATALYTIC OXIDATION;

BENZOIC ACID; MANGANESE; OXYGEN; PHENYL GROUP; SILICON DIOXIDE; SOLVENT; TOLUENE; WATER;

ARTICLE; CATALYST; CHEMICAL ANALYSIS; CHEMICAL MODIFICATION; CONTACT ANGLE; IMMOBILIZATION; OXIDATION; REACTION ANALYSIS; REACTION TIME; SURFACE PROPERTY; SYNTHESIS;

EID: 75149168961     PISSN: 02682575     EISSN: 10974660     Source Type: Journal    
DOI: 10.1002/jctb.2304     Document Type: Article

References (29)

1. Recupero F and Punta C, Free radical functionalization of organic compounds catalyzed by N-hydroxyphthalimide. Chem Rev 107:3800-3842 (2007).
2. Punniyamurthy T, Velusamy S and Iqbal J, Recent advances in transition metal catalyzed oxidation of organic substrates with molecular oxygen. Chem Rev 105:2329-2363 (2005).
3. Sheldon RA and Arends I, Organocatalytic oxidations mediated by nitroxyl radicals. Adv Synth Catal 346:1051-1071 (2004).
4. Fokin AA and Schreiner PR, Metal-free, selective alkane functionalizations. Adv Synth Catal 345:1035-1052 (2003).
5. Gizli A, Aytimur G, Alpay E and Atalay S, Catalytic liquid-phase oxidation of toluene to benzoic acid. Chem Eng Technol 31:409-416 (2008).
6. Suresh AK, Sharma MM and Sridhar T, Engineering aspects of industrial liquid-phase air oxidation of hydrocarbons. Ind Eng Chem Res 39:3958-3997 (2000).
7. Partenheimer W, The complex synergy of water in themetal/bromide autoxidation of hydrocarbons caused by benzylic bromide formation. Adv Synth Catal 346:297-306 (2004).
8. Ishii Y, Sakaguchi S and Iwahama T, Innovation of hydrocarbon oxidation with molecular oxygen and related reactions. Adv Synth Catal 343:393-42 (2001).
9. Hermans I, Peeters J, Vereecken L and Jacobs PA, Mechanism of thermal toluene autoxidation. Chem Phys Chem 8:2678-2688 (2007).
10. Lu ZL, Lindner E and Mayer HA, Applications of sol-gel-processed interphase catalysts. Chem Rev 102:3543-3577 (2002).
11. Thomas JM, Raja R and Lewis DW, Single-site heterogeneous catalysts. Angew Chem Int Ed 44:6456-6482 (2005).
12. Huang G, Luo J, Deng CC, Guo YA, Zhao SK, Zhou H, et al, Catalytic oxidation of toluene with molecular oxygen over manganese tetraphenylporphyrin supported on chitosan. Appl Catal A 338:83-86 (2008).
13. Das BK and Clark JH, A novel immobilised cobalt(III) oxidation catalyst. Chem Commun 605-606 (2000).
14. Ilyas M and Sadiq M, Oxidation of toluene to benzoic acid catalyzed by platinum supported on zirconia in the liquid phase-solvent free conditions. Catal Lett 128:337-342 (2009).
15. Rao KTV, Rao PSN, Nagaraju R, Prasad PSS and Lingaiah N, Room temperature selective oxidation of toluene over vanadium substituted polyoxometalate catalysts. J Mol Catal A 303:84-89 (2009).
16. 3. J Chem Technol Biotechnol 82:620-625 (2007).
17. Raja R, Thomas JM and Dreyer V, Benign oxidants and single-site solid catalysts for the solvent-free selective oxidation of toluene. Catal Lett 110:179-183 (2006).
18. Li XQ, Xu J, Wang F, Gao J, Zhou LP and Yang GY, Direct oxidation of toluene to benzoic acid with molecular oxygen over manganese oxides. Catal Lett 108:137-140 (2006).
19. Wang F, Xu J, Li XQ, Gao J, Zhou LP and Ohnishi R, Liquid phase oxidation of toluene to benzaldehyde with molecular oxygen over copper-based heterogeneous catalysts. Adv Synth Catal 347:1987-1992 (2005).
20. Li XQ, Xu J, Zhou LP, Wang F, Gao J, Chen C, et al, Liquid-phase oxidation of toluene by molecular oxygen over copper manganese oxides. Catal Lett 110:149-154 (2006).
21. Chen C, Zhou LP, Zhang QH, Ma H, Miao H and Xu J, Design of bifunctionalized hexagonal mesoporous silicas for selective oxidation of cyclohexane. Nanotechnology 18:215603 (2007).
22. Chen C, Xu J, Zhang QH, Ma H, Miao H and Zhou LP, Direct synthesis of bifunctionalized hexagonal mesoporous silicas and its catalytic performance for aerobic oxidation of cyclohexane. J Phys Chem C 113:2855-2860 (2009).
23. Tanev PT and Pinnavaia TJ, A neutral templating route to mesoporous molecular-sieves. Science 267:865-867 (1995).
24. Pauly TR, Liu Y, Pinnavaia TJ, Billinge SJL and Rieker TP, Textural mesoporosity and the catalytic activity of mesoporous molecular sieves with wormhole framework structures. J Am Chem Soc 121:8835-8842 (1999).
25. Velu S, Shah N, Jyothi TM and Sivasanker S, Effect of manganese substitution on the physicochemical properties and catalytic toluene oxidation activities of Mg-Al layered double hydroxides. Micropor Mesopor Mater 33:61-75 (1999).
26. Ramanathan A, Archipov T, Maheswari R, Hanefeld U, Roduner E and Glaser R, Synthesis, characterization and catalytic properties of the novel manganese-containing amorphous mesoporous material MnTUD-1. J Phys Chem C 112:7468-7476 (2008).
27. Carrado KA, Xu LQ, Csencsits R and Muntean JV, Use of organo- and alkoxysilanes in the synthesis of grafted and pristine clays. Chem Mater 13:3766-3773 (2001).
28. Li XF, Gao HX, Jin GJ, Chen L, Ding L, Yang HY, et al, Characterization and catalytic performance of methyl-grafted Ti-HMS catalysts prepared by the CVD method. J Mol Struct 872:10-17 (2008).
29. Bastock TW, Clark JH, Martin K and Trenbirth BW, Mild, solvent-free oxidation of toluene and substituted toluenes to their benzoic acids using carboxylic acid-promoted heterogeneous catalysis. Green Chem 4:615-617 (2002).