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Volumn 145, Issue , 2010, Pages 235-254

Designing instructable networks using synthetic replicators

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EID: 74849112547     PISSN: 13596640     EISSN: 13645498     Source Type: Journal    
DOI: 10.1039/b915061g     Document Type: Article
Times cited : (27)

References (82)
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    • For elegant examples and discussion of some autocatalytic organometallic reactions, see:
    • G. von Kiedrowski Bioorg. Chem. Front. 1993 3 113 146
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    • Von Kiedrowski, G.1
  • 68
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    • The bisubstrate reaction templates reported by Kelly and co-workers are prototypes for small molecule reciprocal replicators. In these systems, only one of the two complementary molecules is synthesized in a crosscatalytic reaction. For details, see:
    • D. G. Blackmond Tetrahedron: Asymmetry 2006 17 584 589
    • (2006) Tetrahedron: Asymmetry , vol.17 , pp. 584-589
    • Blackmond, D.G.1
  • 71
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    • The descriptors cis and trans identify the relative stereochemistry of the three protons located on the bicyclic fused ring structure formed in the cycloaddition reaction between the nitrone and the maleimide. In the cis cycloadduct, all three protons lie on the same face of the fused ring system. In the trans cycloadduct, the two protons originally located on the maleimide are located on the opposite face to the proton originating from the nitrone
    • E. Kassianidis D. Philp Angew. Chem., Int. Ed. 2006 45 6344 6348
    • (2006) Angew. Chem., Int. Ed. , vol.45 , pp. 6344-6348
    • Kassianidis, E.1    Philp, D.2
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    • a is arrived at by assuming there is no cooperativity in the binding process, i.e. the connection effective molarity is 1 M. Experimentally, in cases where we have been able to measure the connection EM directly, we have always observed values 0.8 M < EM < 5 M, therefore we believe that a value of 1 M is a reasonable estimate for the simulations For an analysis of the importance of autocatalytic processes in proposed primordial reactions, see:
    • R. J. Pieters I. Huc J. Rebek Jr. Angew. Chem., Int. Ed. Engl. 1994 33 1579 1581
    • (1994) Angew. Chem., Int. Ed. Engl. , vol.33 , pp. 1579-1581
    • Pieters, R.J.1    Huc, I.2    Rebek Jr., J.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.