A new 3-D Gd-Cu heterometallic polymer [Gd2Cu3(bpy)2-(ip)6]·6H2O with a non-interpenetrated α-Po net

Chinese Science Bulletin

Volumn 54, Issue 23, 2009, Pages 4272-4276

  Jia, XiangLi ^a   Zhou, Jian ^a   Zhao, JunWei ^b   Li, ZhaoHui ^c   Zheng, ShouTian ^a   Yang, GuoYu ^a  

^a FUJIAN INSTITUTE OF RESEARCH ON THE STRUCTURE OF MATTER   (China)

^b HENAN UNIVERSITY   (China)

^c FUZHOU UNIVERSITY   (China)

Author keywords

Po network; Heterometallic polymer; Hydrothermal synthesis

Indexed keywords

EID: 74749087106     PISSN: 10016538     EISSN: 18619541     Source Type: Journal    
DOI: 10.1007/s11434-009-0549-9     Document Type: Article

References (30)

1. Xia J, Zhao B, Wang H S, et al. Two- and three-dimensional lanthanide complexes: Synthesis, crystal structures, and properties. Inorg Chem, 2007, 46: 3450-3458.
2. Cheng J W, Zheng S T, Yang G Y. Diversity of crystal structure with different lanthanide ions involving in situ oxidation-hydrolysis reaction. Dalton Trans, 2007, 36: 4059-4066.
3. Zhu W H, Wang Z M, Gao S. Two 3D porous lanthanide-fumarate-oxalate frameworks exhibiting framework dynamics and luminescent change upon reversible de- and rehydration. Inorg Chem, 2007, 46: 1337-1342.
4. Kitagawa S, Kitaura R, Noro S. Functional porous coordination polymers. Angew Chem Int Ed, 2004, 43: 2334-2375.
5. Liu G X, Zhu K, Chen H, et al. Two zinc(II) supramolecular isomers of square grid networks formed by two flexible ligands: Syntheses, structures and nonlinear optical properties. CrystEngComm, 2008, 10: 1527-1530.
6. Ren P, Shi W, Cheng P. Synthesis and characterization of three-dimensional 3d-3d and 3d-4f heterometallic coordination polymers with high thermal stability. Cryst Growth Des, 2008, 8: 1097-1099.
7. Gao H L, Yi L, Ding B, et al. First 3D Pr(III)-Ni(II)-Na(I) polymer and a 3D Pr(III) open network based on pyridine-2, 4, 6-tricarboxylic acid. Inorg Chem, 2006, 45: 481-483.
8. 3] (IN=isonicotinate): Employing 2D layers of lanthanide wheel clusters and 1D chains of copper halide clusters. Inorg Chem, 2007, 46: 5349-5353.
9. Murugesu M, Clérac R, Anson C E, et al. Structure and magnetic properties of a giant Cu44II aggregate which packs with a zeotypic superstructure. Inorg Chem, 2004, 43: 7269-7271.
10. Zheng N F, Bu X H, Lu H W, et al. Crystalline superlattices from single-sized quantum dots. J Am Chem Soc, 2005, 127: 11963-11965.
11. Zhao B, Cheng P, Dai Y, et al. A nanotubular 3D coordination polymer based on a 3d-4f heterometallic assembly. Angew Chem Int Ed, 2003, 42: 934-936.
12. Cheng J W, Zhang J, Yang G Y. Lanthanide-transition-metal sandwich framework comprising {Cu3} cluster pillars and layered networks of {Er36} wheels. Angew Chem Int Ed, 2006, 45: 73-77.
13. Cheng J W, Zheng S T, Yang G Y. Linking two distinct layered networks of nanosized {Ln18} and {Cu24} wheels through isonicotinate ligands. Chem-Eur J, 2008, 14: 88-97.
14. Zhang M B, Zhang J, Yang G Y. A 3D coordination framework based on linkages of nanosized hydroxo lanthanide clusters and copper centers by isonicotinate ligands. Angew Chem Int Ed, 2005, 44: 1385-1388.
15. -): A new pillared-layer approach to heterobimetallic 3d-4f 3D-network solids. Inorg Chem, 2007, 46: 10534-10538.
16. Cheng J W, Zheng S T, Yang G Y. Incorporating distinct metal clusters to construct diversity of 3D pillared-layer lanthanide-transition-metal frameworks. Inorg Chem, 2008, 47: 4930-4935.
17. Sheldrick G M. SHELXS97. Program for Crystal Structure Solution. Göttingen, Germany: University of Göttingen, 1997.
18. Sheldrick G M. SHELXL97. Program for Crystal Structure Refinement. Göttingen, Germany: University of Göttingen, 1997.
19. He F, Tong M L, Chen X M, et al. Synthesis, structures, and magnetic properties of heteronuclear Cu(II)-Ln(III) (Ln = La, Gd, or Tb) complexes. Inorg Chem, 2005, 44: 8285-8292.
20. Niu S Y, Jin J, Jin X X, et al. Synthesis, structure and characterization of Gd(III) dimer bridged by tetra benzoates. Solid State Sci, 2002, 4: 1103-1106.
21. Zhang M L, Li D S, Fu F, et al. A novel 4·82 CdII network constructed from helical motif: Incorporating alternate left- and right-hand helical water chains. Inorg Chem Comm, 2008, 11: 958-960.
22. Martin D P, Montney M R, Supkowski R M, et al. Cadmium glutarate coordination polymers containing hydrogen-bonding capable tethering organodiimines: From double interpenetration to supra-molecular cavities containing an unprecedented water tape morphology. Cryst Growth Des, 2008, 8: 3091-3097.
23. Zhao B, Cheng P, Chen X Y. Design and synthesis of 3d-4f metal-based zeolite-type materials with a 3D nanotubular structure encapsulated "water" pipe. J Am Chem Soc, 2004, 126: 3012-3013.
24. Li Y, Jiang L, Feng X L, et al. Anion dependent water clusters encapsulated inside a cryptand cavity. Cryst Growth Des, 2008, 8: 3689-3694.
25. Cheng J W, Zheng S T, Liu W, et al. An unusual eight-connected self-penetrating ilc net constructed by dinuclear lanthanide building units. CrystEngComm, 2008, 10: 765-769.
26. Mir M H, Kitagawa S, Vittal J J. Two- and three-fold interpenetrated metal-organic frameworks from one-pot crystallization. Inorg Chem, 2008, 47: 7728-7733.
27. Blatov V A, Carlucci L, Proserpio D M. Interpenetrating metal-organic and inorganic 3D networks: A computer-aided systematic investigation. part I. Analysis of the cambridge structural database. Cryst Eng Comm, 2004, 6: 377-395.
28. Wang X L, Cao Q, Wang E B, et al. Metal nuclearity modulated four-, six-, and eight-connected entangled frameworks based on mono-, bi-, and trimetallic cores as nodes. Chem Eur J, 2006, 12: 2680-2691.
29. Kesanli B, Cui Y, Smith M R, et al. Highly interpenetrated metal-organic frameworks for hydrogen storage. Angew Chem Int Ed, 2005, 44: 72-75.
30. Ye B H, Ding B B, Weng Y Q, et al. Multidimensional networks constructed with isomeric benzenedicarboxylates and 2, 2′-biimi-dazole based on mono-, bi-, and trinuclear units. Cryst Growth Des, 2005, 5: 801-806.